scholarly journals The treatment of copper–gold ores by ammonium thiosulfate leaching

2002 ◽  
Vol 66 (1-3) ◽  
pp. 1-21 ◽  
Author(s):  
Ellen Molleman ◽  
David Dreisinger
Metals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 1029
Author(s):  
Mooki Bae ◽  
Sookyung Kim ◽  
Jeongsoo Sohn ◽  
Donghyo Yang ◽  
Hyunju Lee

Ammonium thiosulfate is an alternative lixiviant for the hydrometallurgical treatment of sulfide gold ores. The present study is primarily focused on ammonium thiosulfate leaching of gold (Au) and silver (Ag) from the sulfide ore (Sunshin mine in Korea). The main chemical composition of the concentrate was Au (84 ppm), Ag (852 ppm), Fe (18.9%), Si (23.2%), and S (21.1%). The effects of various parameters on the process, such as leaching time (1–4 h), ammonium thiosulfate concentration (0.05–0.5 M), copper sulfate (CuSO4), concentration (0.05–0.25 M), solid to liquid ratio (0.2–0.5), and reaction temperature (40–60 °C) were systematically examined. Optimum Au leaching efficiency (>99%) was obtained under the following leaching conditions: 0.5 M ammonium thiosulfate with 0.05 M CuSO4 concentration, 0.2 S/L ratio at 60 °C for 2 h. The results indicate that the behavior of Ag was similar to that of Au. Almost complete dissolution of Ag occurred under following leaching conditions: 0.5 M ammonium thiosulfate with 0.05 M CuSO4 concentration at 60 °C for 4 h. This study would be useful in understanding the eco-friendly leaching systems of Au and Ag during the hydrometallurgical process of sulfide gold ore.


2019 ◽  
Vol 138 ◽  
pp. 168-177 ◽  
Author(s):  
Sanghee Jeon ◽  
Mayumi Ito ◽  
Carlito Baltazar Tabelin ◽  
Rongrit Pongsumrankul ◽  
Shinya Tanaka ◽  
...  

2018 ◽  
Vol 77 ◽  
pp. 195-202 ◽  
Author(s):  
Sanghee Jeon ◽  
Mayumi Ito ◽  
Carlito Baltazar Tabelin ◽  
Rongrit Pongsumrankul ◽  
Naho Kitajima ◽  
...  

Metals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 897 ◽  
Author(s):  
Diego Medina ◽  
Corby G. Anderson

Globally, copper, silver, and gold orebody grades have been dropping, and the mineralogy surrounding them has become more diversified and complex. The cyanidation process for gold production has remained dominant for over 130 years because of its selectivity and feasibility in the mining industry. For this reason, the industry has been adjusting its methods for the extraction of gold, by utilizing more efficient processes and technologies. Often, gold may be found in conjunction with copper and silver in ores and concentrates. Hence, the application of cyanide to these types of ores can present some difficulty, as the diversity of minerals found within these ores can cause the application of cyanidation to become more complicated. This paper outlines the practices, processes, and reagents proposed for the effective treatment of these ores. The primary purpose of this review paper is to present the hydrometallurgical processes that currently exist in the mining industry for the treatment of silver, copper, and gold ores, as well as concentrate treatments. In addition, this paper aims to present the most important challenges that the industry currently faces, so that future processes that are both more efficient and feasible may be established.


2021 ◽  
Vol 271 ◽  
pp. 04001
Author(s):  
Chen Yanbo ◽  
Qin Guanglin ◽  
Li Guangsheng ◽  
Zhu Xingfu ◽  
Yu Congquan ◽  
...  

The conventional cyanide leaching process is used to extract gold from a high copper gold concentrate. Because the copper associated minerals consume sodium cyanide in large quantities, the cost of the reagents is high and the economic benefit is not ideal. At the same time, a large number of cyanide tail slag are produced, which brings a series of environmental problems. In order to solve the environmental problems caused by excessive sodium cyanide consumption and cyanogen slag, the feasibility of leaching gold by thiosulfate in copper ammonia system was studied. The gold leaching rate of thiosulfate was increased to more than 90% by using the direct thiosulfate leaching process and pretreatment thiosulfate leaching process, which was close to the gold leaching index of sodium cyanide at the production site.


2018 ◽  
Vol 81 ◽  
pp. 148-156 ◽  
Author(s):  
Sanghee Jeon ◽  
Carlito Baltazar Tabelin ◽  
Hirotaka Takahashi ◽  
Ilhwan Park ◽  
Mayumi Ito ◽  
...  

2019 ◽  
Vol 97 (9) ◽  
pp. 651-658 ◽  
Author(s):  
Igor Povar ◽  
Stefano Ubaldini ◽  
Oxana Spinu ◽  
Tudor Lupascu

The paper presents a new thermodynamic approach to studying mixed ligand complex formation reactions in the multi-component two-phase system “cuprous oxide-ammoniacal copper (I) thiosulfate aqueous solution” under real conditions. The quintessence of the developed approach consists in the thermodynamic analysis of concurrent reactions in the heterogeneous system Cu(I) – NH3 – S2O32− – H2O on the basis of the introduced notion of generalized reaction equations. A detailed thermodynamic analysis in ammonium thiosulfate leaching systems has considered the formation of mixed ligand complex species Cu(OH)i(NH3)j(S2O3)k. The new feature is to focus on the chemical description of the overall process of complex formation consisting of a series of concurrent reactions, where the nature and ratio of the concentrations of chemical species, formed in such reactions, depend on the ratio of the concentrations of the metal Cu+ and ligands, temperature, and other thermodynamic parameters. On the basis of the selected thermodynamic data for involved species, the thermodynamic stability areas of solid phase and the repartition of soluble and insoluble chemical species towards the solution pH and a number of total reagent concentrations in heterogeneous mixtures have been investigated. The diagrams of heterogeneous and homogeneous chemical equilibria are used for the graphical representation of complex equilibria and distribution of soluble and insoluble species in examined systems. The used approach utilizes thermodynamic relationships coupled with original mass balance constraints, where the solid phases are explicitly expressed. The obtained results are useful for optimization of the overall scheme of thiosulfate leaching in gold hydrometallurgy to minimize reagent consumption and maximize gold extraction.


2005 ◽  
Vol 26 (3-4) ◽  
pp. 207-226 ◽  
Author(s):  
Ryan Mathur ◽  
Spencer Titley ◽  
Joaquin Ruiz ◽  
Stacie Gibbins ◽  
Kurt Friehauf

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