Geochemical evolution of a Devonian diaspore–crandallite–svanbergite-bearing weathering profile in the Middle Timan, Russia

1999 ◽  
Vol 66 (1-2) ◽  
pp. 353-361 ◽  
Author(s):  
Leonid E Mordberg
Author(s):  
S. G. Skublov ◽  
A. O. Krasotkina ◽  
A. B. Makeyev ◽  
O. L. Galankina ◽  
A. E. Melnik

Findings of the growth relationships between baddeleyite and zircon are rare, due to significant differences in the formation conditions of the minerals. A reaction replacement (partial to complete) of baddeleyite by zircon is possible during metamorphism accompanied by the interaction with high-Si fluids. The opposite situation, when zircon is replaced by baddeleyite, is extremely rare in the nature. Transformation of zircon from polymineral (compound) ore occurrence Ichetju (the Middle Timan) with the formation of microaggregates of baddeleyite, ratile and florencite has been found out. The size of the largest segregations of baddeleyite does not exceed 10 microns in diameter. Microaggregates are unevenly related to the rim of zircon with a thickness of 10 to 50 rfn, voids and cracks across the grain. Altered zircon rim (a mixture of newly formed minerals) is characterized by sharply increased composition of REE (especially LREE), Y, Nb, Ca, Ti. The composition of Th and U also increases. An overview of the experimental studies on the reaction between zircon and baddeleyite and single natural analogues allows to make a conclusion that the most likely mechanism of the transformation of zircon from ore occurrence Ichetju to baddeleyite (intergrowth with ratile and florencite) is due to the effect of interaction of primary zircon with high-temperature (higher than 500—600°C) alkaline fluids transporting HFSE (REE, Y, Nb, Ti). This is indirectly confirmed by the findings of zircon with anomalous high composition of Y and REE up to 100000 and 70000 ppm respectively.


2016 ◽  
Author(s):  
Alexander A. Conti ◽  
◽  
Elizabeth H. Gierlowski-Kordesch

The Mesozoic Hartford Basin, a fault-bounded half-graben in New England, is composed of four sedimentologic units displaying lacustrine, playa, and alluvial conditions separated by three tholeiitic basalt flows. Limited outcrop, however, has restricted analyses across the basin. The Jurassic East Berlin Formation, in particular, crops out only in the southern and northern extents of the basin, exposing the upper 100-118-m of deposits. As a result, a new core analysis across a 600-m-transect of East Berlin rocks has been completed in the central region of the basin, exposing the entire 195-m thickness of the formation for the first time. Cores expose eight 3-m-thick lacustrine mudrock units, the upper six of which are correlative to lake deposits identified in the southern and northern extents of the basin. Additionally, thin chicken-wire evaporites demarcate the lowermost, previously unexposed, lacustrine unit, 7-m beneath a 15-cm-thick tufa horizon. Thin playa deposits and thick sheetflood and Vertisol packages separate these lake sequences over 5-30-m of vertical distance.To supplement these sedimentologic data, and better understand lake geochemistry of the basin during East Berlin time, new biomarker analyses have been applied to each of the eight lacustrine mudrock units for the first time. Biomarker data are useful for determining the lake-basin type, a paleolake classification system derived by Bohacs, Carroll, and others to describe predictable physical and geochemical evolution within rift basins from fluvial facies to over-filled, balance-filled, and under-filled lacustrine facies; subsequently, balance-filled lacustrine facies grade to a terminal fluvial facies during changes in accommodation space through time. While fluvial facies envelope lake deposits within the Hartford Basin, identifying the lake types within the East Berlin has been problematic because of limited exposures. These new sedimentologic and biomarker analyses, however, suggest balance-filled lacustrine conditions at the base of the East Berlin that grade into under-filled conditions upsection. These new biomarker data finally provide definitive evidence for changing lake types during East Berlin time.


2020 ◽  
Author(s):  
Hunter M. Manlove ◽  
◽  
Jay L. Banner ◽  
Lakin K. Beal ◽  
Darrel M. Tremaine ◽  
...  

2021 ◽  
Vol 14 (3) ◽  
Author(s):  
Rajan Girija Rejith ◽  
Mayappan Sundararajan ◽  
Balu Gowtham ◽  
Ayyappan Balasubramanian ◽  
Joseph Francis Lawrence

Island Arc ◽  
2002 ◽  
Vol 11 (4) ◽  
pp. 255-273 ◽  
Author(s):  
PETER D. CLIFT ◽  
ROBYN HANNIGAN ◽  
JERZY BLUSZTAJN ◽  
AMY E. DRAUT

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