4D volcanic geology of Hachijo-jima islet, Izu-Bonin arc

This study provides geological, geochemical, and chronological insight into the evolution of the Hachijo-jima volcanoes of the Izu Bonin arc. The regional Ata-Torihama tephra (Ata-Th; 0.24 Ma) and Kikai-Tozurahara tephra (K-Tz; 0.095 Ma) from Kyushu are intercalated within the voluminous proximal volcanic products. Our study combines detailed geologic mapping, tephrochronology, U-Pb zircon dating, and published drill core data from NEDO (1993) to evaluate the time transgressive 3-dimensional (thus 4-dimensional) structure of the dissected Mihara-yama volcano, the older of the two volcanoes on Hachijo-jima. The volcanic succession comprises terrestrial volcanic basement, marine volcaniclastic rocks, and terrestrial tuff intercalated with tholeiitic basalt and the regional calc-alkaline tephra layers. The un-dissected Hachijo-Fuji stratovolcano (tholeiitic basalt) overlies marine volcaniclastics abutting the northwestern paleo sea cliffs of Mihara-yama. Newly-described folding and normal faulting of the marine and overlying terrestrial volcaniclastic rocks suggests NW-SE shortening that may be associated with the collision of the Izu-Bonin arc with the Honshu arc. The proto Hachijo-jima volcano emerged above the sea > 0.24 Ma, and this date can be applied as a molecular biological calibration date for organisms on this island.

Experimental settling, floatation and compaction of plagioclase in basaltic melt and a revision of melt density

Centrifuge-assisted piston cylinder experiments were conducted on plagioclase in basaltic melt at 1140–1250 °C, 0.42–0.84 GPa and mostly 1000 g. One set of experiments assesses the settling velocity of a dilute plagioclase suspension; a second sinks or floats plagioclase in a MORB-type melt exploring conditions of neutral buoyancy; and a third set examines floatation of plagioclase from an evolved lunar magma ocean composition. A compaction rate for plagioclase cumulates is established. The experiments demonstrate that neutral density of plagioclase An74 in a MOR-type tholeiitic basalt occurs at 0.59 ± 0.04 GPa (1200 °C), contrasting predictions by present models on melt density which yield a density inversion pressure at 0.10–0.15 GPa. In nature, the level of neutral buoyancy depends on melt composition; nevertheless, for the onset of plagioclase crystallization in dry tholeiitic basalts, our result is robust. As the molar volume of plagioclase is well known, the experimentally determined pressure of neutral buoyancy indicates a correction of -1.6% to previous density models for silicate melts. It follows that for (tholeiitic) layered mafic intrusions, plagioclase is negatively buoyant for early, relatively primitive, parent melts. In contrast, the extreme Fe enrichment of a fractionating lunar magma ocean leads to melt densities that let anorthite always float. Compaction φ/φ0 of experimental plagioclase cumulates is quantified to φ/φ0 = − 0.0582 log (Δρ·h·a·t) + 1.284, where φ0 is the porosity after settling (67 ± 2%), h the cumulate pile height, a acceleration and φ porosity as a function of time t. Gravitational-driven compaction in tens of m-thick plagioclase cumulate in basaltic magmas reaches down to ~ 40% porosity within hundreds of years, a timescales competing with characteristic cooling times of cumulate layers of mafic intrusions. To achieve plagioclase modes > 80% due to compaction, an additional overload of ~ 100 m (layers) of mafic minerals would be required. Compaction of a lunar anorthosite crust of 35 km to 20% porosity (i.e. ~ 90% plagioclase after crystallization of the interstitial melt) would require 30 kyrs.

A Multidisciplinary Investigation Into the Eruptive Style, Processes, and Duration of a Cascades Back-Arc Tholeiitic Basalt: A Case Study of the Brushy Butte Flow Field, Northern California, United States

The Cascades back-arc in northern California is dominated by monogenetic tholeiitic basalts that erupted throughout the Pleistocene. Elucidating their eruptive history and processes is important for understanding potential future eruptions here. We focus on the well-exposed monogenetic volcano that emplaced the Brushy Butte flow field, which constructed a ∼150 m tall edifice, has flow lobes up to >10 km long, and in total covers ∼150 km2 with an eruptive volume of 3.5 km3. We use a multidisciplinary approach of field mapping, petrography, geochemistry, paleomagnetism, geochronology, and lidar imagery to unravel the eruptive history and processes that emplaced this flow field. Tholeiitic basalts in northern California have diverse surface morphology and vegetation cover but similar petrographic appearances, which makes them hard to distinguish in the field. Geochemistry and paleomagnetism offer an independent means of distinguishing tholeiitic basalts. Brushy Butte flow field lavas are similar in major-oxide and trace-element abundances but differ from adjacent tholeiitic basalts. This is also apparent in remanent magnetic directions. Additionally, paleomagnetism indicates that the flow field was emplaced during a geologically brief time interval (10–20 years), which 36Cl cosmogenic dating puts at 35.7 ± 1.7 ka. Lidar imagery shows that these flows erupted from at least 28 vents encompassing multiple scoria cones, spatter cones, and craters. Flows can be grouped into four pulses using stratigraphic position and volume. Pulse 1 is the most voluminous, comprising eight eruptions and ∼2.3 km3. Each subsequent pulse started rapidly but decayed quickly, and each successive pulse erupted less lava (i.e., 2.3 km3 for pulse 1, 0.6 km3 for pulse 2, 0.3 km3 for pulse 3, and 0.2 km3 for pulse 4). Many of these flows host well-established lava channels and levees (with channel breakouts) that lead to lava fans, with some flows hosting lava ponds. Similar flow features from tholeiitic eruptions elsewhere demonstrate that these morphologies generally occur over weeks, months, or longer (e.g., Puʻu ʻŌʻō eruption at K–llauea, Hawaiʻi). This multidisciplinary study shows the range of eruptive styles and durations of a Cascades back-arc eruption and illustrates how potential future tholeiitic eruptive activity in the western United States might progress.

Zircon survival in shallow asthenosphere and deep lithosphere

Zircon (ZrSiO4) is the most frequently used geochronometer of terrestrial and extraterrestrial processes. To shed light on question of zircon survival in the Earth's shallow asthenosphere, high-temperature experiments of zircon dissolution in natural mid-ocean ridge basaltic (MORB) and synthetic haplobasaltic melts have been performed at temperatures of 1250–1300 °C and pressures from 0.1 MPa to 0.7 GPa. Zirconium measurements were made in situ by electron probe microanalyses (EPMA) at high current. Taking into account secondary fluorescence effects in zircon-glass pairs during EPMA, a zirconium diffusion coefficient of 2.87E-08 cm2/s was determined at 1300 °C and 0.5 GPa. When applied to the question of zircon survival in asthenospheric melts of tholeiitic basalt composition, the data are used to infer that typical 100 mm zircon crystals dissolve rapidly (~10 h) and congruently upon reaction with basaltic melt at pressures of 0.2–0.7 GPa. We observed incongruent (to crystal ZrO2 and SiO2 in melt) dissolution of zircon in natural mid-ocean ridge the basaltic melt at low pressures <0.2 GPa and in the haplobasaltic melt at 0.7 GPa pressure. Our experimental data raise questions about the origin of zircon crystals in mafic and ultramafic rocks, in particular, in shallow oceanic asthenosphere and deep lithosphere, as well as the meaning of the zircon-based ages estimated from these minerals. The origin of zircon in shallow (ultra-) mafic chambers is likely related to the crystallization of intercumulus liquid. Large zircon megacrysts in kimberlites, peridotites, alkali basalts, and carbonatite magmas suggest fast transport and short interaction durations between zircon and melt. The origin of zircon megacrysts is likely related to metasomatic addition of Zr into the mantle as an episode of mantle melting should eliminate them on geologically short timescales.

The eruptive history, magmatic evolution, and influence of glacial ice at long-lived Akutan volcano, eastern Aleutian Islands, Alaska, USA

New 40Ar/39Ar and whole-rock geochemical data are used to develop a detailed eruptive chronology for Akutan volcano, Akutan Island, Alaska, USA, in the eastern Aleutian island arc. Akutan Island (166°W, 54.1°N) is the site of long-lived volcanism and the entire island comprises volcanic rocks as old as 3.3 Ma. Our current study is on the 225 km2 western half of the island, where our results show that the focus of volcanism has shifted over the last ∼700 k.y., and that on occasion, multiple volcanic centers have been active over the same period, including within the Holocene. Incremental heating experiments resulted in 56 40Ar/39Ar plateau ages and span 2.3 Ma to 9.2 ka. Eruptive products of all units are primarily tholeiitic and medium-K, and range from basalt to dacite. Rare calc-alkaline lavas show evidence suggesting their formation via mixing of mafic and evolved magmas, not via crystallization-derived differentiation through the calc-alkaline trend. Earliest lavas are broadly dispersed and are almost exclusively mafic with high and variable La/Yb ratios that are likely the result of low degrees of partial mantle melting. Holocene lavas all fall along a single tholeiitic, basalt-to-dacite evolutionary trend and have among the lowest La/Yb ratios, which favors higher degrees of mantle melting and is consistent with the increased magma flux during this time. A suite of xenoliths, spanning a wide range of compositions, are found in the deposits of the 1.6 ka caldera-forming eruption. They are interpreted to represent completely crystallized liquids or the crystal residuum from tholeiitic fractional crystallization of the active Akutan magma system. The new geochronologic and geochemical data are used along with existing geodetic and seismic interpretations from the island to develop a conceptual model of the active Akutan magma system. Collectively, these data are consistent with hot, dry magmas that are likely stored at 5−10 km depth prior to eruption. The prolonged eruptive activity at Akutan has also allowed us to evaluate patterns in lava-ice interactions through time as our new data and observations suggest that the influence of glaciation on eruptive activity, and possible magma composition, is more pronounced at Akutan than has been observed for other well-studied Aleutian volcanoes to the west.

Lithogeochemistry of the Mid-Ocean Ridge Basalts near the Fossil Ridge of the Southwest Sub-Basin, South China Sea

Mid-ocean ridge basalts (MORB) in the South China Sea (SCS) record deep crust-mantle processes during seafloor spreading. We conducted a petrological and geochemical study on the MORBs obtained from the southwest sub-basin of the SCS at site U1433 and U1434 of the International Ocean Discovery Program (IODP) Expedition 349. Results show that MORBs at IODP site U1433 and U1434 are unaffected by seawater alteration, and all U1433 and the bulk of U1434 rocks belong to the sub-alkaline low-potassium tholeiitic basalt series. Samples collected from site U1433 and U1434 are enriched mid-ocean ridge basalts (E-MORBs), and the U1434 basalts are more enriched in incompatible elements than the U1433 samples. The SCS MORBs have mainly undergone the fractional crystallization of olivine, accompanied by the relatively weak fractional crystallization of plagioclase and clinopyroxene during magma evolution. The magma of both sites might be mainly produced by the high-degree partial melting of spinel peridotite at low pressures. The degree of partial melting at site U1434 was lower than at U1433, ascribed to the relatively lower spreading rate. The magmatic source of the southwest sub-basin basalts may be contaminated by lower continental crust and contributed by recycled oceanic crust component during the opening of the SCS.

A Fractional Crystallization Link between Komatiites, Basalts, and Dunites of the Palaeoproterozoic Winnipegosis Komatiite Belt, Manitoba, Canada

The rock type most commonly associated with komatiite throughout Earth’s history is tholeiitic basalt. Despite this well-known association, the link between komatiite and basalt formation is still debated. Two models have been suggested: that tholeiitic basalts represent the products of extensive fractional crystallization of komatiite, or that basalts are formed by lower degrees of mantle melting than komatiites in the cooler portions of a zoned plume. We present major and trace element data for tholeiitic basalts (∼7·5 wt% MgO) and dunites (46–48 wt% MgO) from the Palaeoproterozoic Winnipegosis Komatiite Belt (WKB), which, along with previous data for WKB komatiites (17–26 wt% MgO), are utilized to explore the potential links between komatiite and basalt via crystallization processes. The dunites are interpreted as olivine + chromite cumulates that were pervasively serpentinized during metamorphism. Their major and immobile trace element relationships indicate that the accumulating olivine was highly magnesian (Mg# = 0·91–0·92), and that small amounts (4–7 wt% on average) of intercumulus melt were trapped during their formation. These high inferred olivine Mg# values suggest that the dunites are derived from crystallization of komatiite. The tholeiitic basalts have undergone greenschist-facies metamorphism and have typical geochemical characteristics for Palaeoproterozoic basalts, with the exception of high FeO contents. Their REE patterns are similar to Winnipegosis komatiites, although absolute concentrations are higher by a factor of ∼2·5. The ability of thermodynamic modelling with MELTS software to reproduce komatiite liquid lines of descent (LLD) is evaluated by comparison with the crystallization sequence and mineral compositions observed for Winnipegosis komatiites. With minor caveats, MELTS is able to successfully reproduce the LLD. This modelling is extended to higher pressures to simulate crystallization of komatiitic melt in an upper crustal magma chamber. All major and rare earth element characteristics of the tholeiitic basalts can be reproduced by ∼60 % crystallization of a Winnipegosis komatiite-like parental melt at pressures of ∼1·5–2·5 kbar at oxygen fugacities between QFM − 1 and QFM + 1, where QFM is the quartz–fayalite–magnetite buffer. Winnipegosis basalts have low Mg# values that are not in equilibrium with mantle peridotite. They therefore cannot represent primary mantle melts derived from cooler mantle than the komatiites, and require fractional crystallization processes in their formation. Furthermore, their trace element characteristics indicate a depth of melting indistinguishable from that of the Winnipegosis komatiites, and derivation from an identical depleted mantle source. All geochemical and geological evidence is therefore consistent with their derivation from a komatiitic melt, and the presence of a large komatiite-derived dunite body in the WKB provides evidence of extensive fractionation of komatiite in the upper crust. The observed uniform basalt compositions are interpreted as the result of a density minimum in the evolving komatiitic melt at temperatures between clinopyroxene and plagioclase saturation, with efficient extraction of melt from a mixture containing ∼60 % crystals. We conclude that the WKB basalts formed by fractional crystallization of a komatiitic parental melt, and suggest that this model may be more broadly applicable to other localities where komatiites and associated basalts show similar geochemical or isotopic characteristics.