Formation of azopyridine/phthalocyaninatoiron complexes on the air-water interface and electrical properties of their Langmuir-Blodgett films

1997 ◽  
Vol 86 (1-3) ◽  
pp. 1899-1900 ◽  
Author(s):  
M. Rikukawa ◽  
K. Sanui ◽  
N. Ogata
2000 ◽  
Vol 19 (2) ◽  
pp. 117-125 ◽  
Author(s):  
Wieslaw I Gruszecki ◽  
Bogumil Zelent ◽  
Heidar-Ali Tajmir-Riahi ◽  
Gongming Wang ◽  
Toufik Taleb ◽  
...  

2008 ◽  
Vol 1144 ◽  
Author(s):  
Yoko Tatewaki ◽  
Junko Takizawa ◽  
Tatsuya Hatanaka ◽  
Mutsumi Kimura ◽  
Hirofusa Shirai

ABSTRACTWe found that novel amphiphilic tetrathiafulvalene (TTF; 1) organized into supramolecular assemblies by the addition of electron acceptor 2,3,5,6-tetrafluoro-7,7'f,8,8'f-tetracyano-p-quinodimethane (F4TCNQ) at the air-water interface. The assemblies on the air-water interface can be transferred onto the surface of mica and the morphologies of transferred films were investigated by AFM. The morphology of Langmuir-Blodgett films strongly depended on the ratio between 1 and F4TCNQ. Film of 1:1 mixture of 1 and F4TCNQ formed nanoscopic wires having an average dimension of 5.0 (height) × 70 (width) × 3000 (length) nm. On the other hand, the film of 2:1 mixture of 1 and F4TCNQ showed the mixed domains of wires and flat monolayers. Thus, the completely charge-transferred complex (1+)(F4TCNQ-) formed one-dimensional nanowires having a micrometer length. Room temperature electrical conductivities of cast film for 1:1 and 2:1 mixed layers of 1 and F4TCNQ were 2.4 × 10−4 and 8.0 × 10−5 S cm−1, respectively.


Langmuir ◽  
2000 ◽  
Vol 16 (3) ◽  
pp. 1196-1204 ◽  
Author(s):  
Amélia M. Gonçalves da Silva ◽  
Maria Isabel Viseu ◽  
Anantha Malathi ◽  
Patrícia Antunes ◽  
Sílvia M. B. Costa

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