Flow-injection spectrophotometric determination of periodate and iodate by their reaction with pyrogallol red in acidic media

Author(s):  
Ali A Ensafi ◽  
M.Arab Chamjangali
2009 ◽  
Vol 2009 ◽  
pp. 1-8 ◽  
Author(s):  
Helena Puzanowska-Tarasiewicz ◽  
Joanna Karpińska ◽  
Ludmiła Kuźmicka

The presented review is devoted to analytical applications of reactions of Fe(III) and with 2,10-disubstituted phenothiazines (PT). It was found that iron(III) and hexacyanoferrate(III) ions in acidic media easily oxidized PT with the formation of colored oxidation products. This property has been exploited for spectrophotometric determination of iron(III) ions and phenothiazines. Some flow-injection procedures of the determination of PT based on the oxidation reaction by means of the above-mentioned oxidants have been proposed. In the presented review, the application of 2,10-disubstituted phenothiazines as indicators in complexometric titration of iron(III) as well as procedures of PT determination based on generation of ternary compound in the system Fe(III)-- PT was also described.


2003 ◽  
Vol 142 (4) ◽  
pp. 231-235 ◽  
Author(s):  
Tom�s P�rez-Ruiz ◽  
Carmen Mart�nez-Lozano ◽  
Virginia Tom�s ◽  
Antonio Sanz ◽  
Raquel Garre

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