Characterisation and theoretical investigation of the electronic properties and second-order nonlinearity of some three dentate salicylaldiminato Schiff base ligands

Author(s):  
M. Jalali-Heravi ◽  
A.A. Khandar ◽  
I. Sheikshoaie
Inorganics ◽  
2020 ◽  
Vol 8 (4) ◽  
pp. 25 ◽  
Author(s):  
Paola Matozzo ◽  
Alessia Colombo ◽  
Claudia Dragonetti ◽  
Stefania Righetto ◽  
Dominique Roberto ◽  
...  

Whereas there is an increasing amount of reports on the second-order nonlinear optical (NLO) and luminescence properties of tetradentate [N2O2] Schiff base–zinc complexes, the study of zinc complexes having two bidentate [NO] Schiff-base ligands is relatively unexplored from an NLO point of view. This work puts in evidence that the known chiral bis{2-[(R)-(+)-1-phenylethyliminomethyl]phenolato-N,O}zinc(II) complex is a fascinating multifunctional molecular inorganic–organic hybrid material characterized by interesting second-order NLO and luminescent properties in solution. The emissive properties of the organic 2-(R)-(+)-1-phenylethyliminomethyl]phenol proligand are greatly enhanced upon coordination to the inorganic Zn(II) center.


RSC Advances ◽  
2019 ◽  
Vol 9 (60) ◽  
pp. 34710-34719 ◽  
Author(s):  
Kousik Ghosh ◽  
Sayantan Sil ◽  
Partha Pratim Ray ◽  
Joaquín Ortega-Castro ◽  
Antonio Frontera ◽  
...  

The opto-electronic properties of a cobalt(iii)–sodium complex have been studied with the help of both experimental and theoretical investigation. The complex has also been used to fabricate an effective photosensitive Schottky device.


Polyhedron ◽  
2014 ◽  
Vol 73 ◽  
pp. 139-145 ◽  
Author(s):  
Subrata Naiya ◽  
Sanjib Giri ◽  
Saptarshi Biswas ◽  
Michael G.B. Drew ◽  
Ashutosh Ghosh

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