scholarly journals Photosensitive Schottky barrier diode behavior of a semiconducting Co(iii)–Na complex with a compartmental Schiff base ligand

RSC Advances ◽  
2019 ◽  
Vol 9 (60) ◽  
pp. 34710-34719 ◽  
Author(s):  
Kousik Ghosh ◽  
Sayantan Sil ◽  
Partha Pratim Ray ◽  
Joaquín Ortega-Castro ◽  
Antonio Frontera ◽  
...  
Keyword(s):  
Schiff Base ◽  
Electronic Properties ◽  
Schottky Barrier ◽  
Theoretical Investigation ◽  
Schiff Base Ligand ◽  
Schottky Barrier Diode ◽  
Sodium Complex ◽  
Diode Behavior ◽  
Schottky Device

The opto-electronic properties of a cobalt(iii)–sodium complex have been studied with the help of both experimental and theoretical investigation. The complex has also been used to fabricate an effective photosensitive Schottky device.

Tetra- and poly-nuclear Cd(ii) complexes of an N3O4 Schiff base ligand: crystal structures, electrical conductivity and photoswitching properties

2020 ◽  
Vol 44 (34) ◽  
pp. 14733-14743 ◽  
Author(s):  
Tanmoy Kumar Ghosh ◽  
Sumanta Jana ◽  
Subrata Jana ◽  
Ashutosh Ghosh
Keyword(s):  
Electrical Conductivity ◽  
Schiff Base ◽  
Schottky Barrier ◽  
Crystal Structures ◽  
Schiff Base Ligand ◽  
Schottky Barrier Diode ◽  
Polymeric Complex

A tetranuclear and a polymeric Cd(ii) complex have been synthesized and characterized. The polymeric complex based device behaves as a Schottky barrier diode and exhibits a photoswitching property.

The development of a promising photosensitive Schottky barrier diode using a novel Cd(ii) based coordination polymer

2017 ◽  
Vol 46 (39) ◽  
pp. 13531-13543 ◽  
Author(s):  
Pravat Ghorai ◽  
Arka Dey ◽  
Paula Brandão ◽  
Joaquín Ortega-Castro ◽  
Antonio Bauza ◽  
...  
Keyword(s):  
Schiff Base ◽  
Coordination Polymer ◽  
Schottky Barrier ◽  
Schiff Base Ligand ◽  
Schottky Barrier Diode ◽  
Polymer Complex

A novel 1D Cd(ii) based coordination polymer (complex 1) has been synthesized involving an 8-aminoquinoline based Schiff base ligand and cyanate ion, which exhibits interesting photosensitive Schottky barrier diode behaviour.

Cyclometalated Pt(ii) complexes with a bidentate Schiff-base ligand displaying unexpected cis/trans isomerism: synthesis, structures and electronic properties

2017 ◽  
Vol 46 (37) ◽  
pp. 12500-12506 ◽  
Author(s):  
A. Poma ◽  
A. Forni ◽  
C. Baldoli ◽  
P. R. Mussini ◽  
A. Bossi
Keyword(s):  
Schiff Base ◽  
Electronic Properties ◽  
Computational Methods ◽  
Schiff Base Ligand ◽  
X Ray Diffraction ◽  
X Ray ◽  
Bidentate Schiff Base Ligand

Unexpected cis/trans isomerism in a bis-cyclometalated Pt(ii) complex is investigated by NMR, X-ray diffraction, optical, electrochemical and computational methods and rationalized.

A tetranuclear nickel/lead complex with a salen type Schiff base: synthesis, structure and exploration of photosensitive Schottky barrier diode behaviour

2019 ◽  
Vol 43 (13) ◽  
pp. 5020-5031 ◽  
Author(s):  
Sourav Roy ◽  
Arka Dey ◽  
Michael G. B. Drew ◽  
Partha Pratim Ray ◽  
Shouvik Chattopadhyay
Keyword(s):  
Schiff Base ◽  
Charge Transfer ◽  
Schottky Barrier ◽  
Schottky Diode ◽  
Schottky Barrier Diode ◽  
Kinetics Of ◽  
Lead Complex ◽  
Nickel Lead

A tetranuclear nickel(ii)/lead(ii) complex has been synthesized and characterized. The complex based device behaves as a Schottky diode. The charge transfer kinetics of the complex is enhanced after light soaking.

Steric Trapping of the High Spin State in FeIII Quinolylsalicylaldimine Complexes

2014 ◽  
Vol 67 (11) ◽  
pp. 1574 ◽  
Author(s):  
Darunee Sertphon ◽  
David J. Harding ◽  
Phimphaka Harding ◽  
Keith S. Murray ◽  
Boujemaa Moubaraki ◽  
...  
Keyword(s):  
Schiff Base ◽  
Electronic Properties ◽  
High Spin ◽  
Spin State ◽  
Schiff Base Ligand ◽  
Room Temperature ◽  
Spin Crossover ◽  
High Spin State ◽  
Electrochemical Studies ◽  
Magnetic Studies

A new sterically bulky Schiff base ligand, N-(8-quinolyl)-5-tert-butylsalicylaldimine (Hqsal-5-tBu) has been prepared and a series of FeIII complexes, [Fe(qsal-5-tBu)2]Y (Y = Cl 1, ClO4 2, NO3 3, BF4 4) utilising this ligand are reported and fully characterised. UV-vis spectroscopic and electrochemical studies indicate that 1–4 are high spin (HS) in solution at room temperature and further suggest that the tBu group only slightly alters the electronic properties of 1–4 compared with related [Fe(qsal-5-X)2]+ systems. The structures of [Fe(qsal-5-tBu)2]Cl·4MeOH·H2O 1, [Fe(qsal-5-tBu)2]ClO4·MeOH 2, and [Fe(qsal-5-tBu)2]NO3 3 determined at 100 K reveal HS FeIII centres in all cases. Four-fold parallel aryl embraces and π–π interactions serve to link the cations forming 2D sheets mirroring the motifs found in other [Fe(qsal-5-X)2]+ complexes. Despite this the tBu group causes strong distortions at the Fe centre which as magnetic studies reveal prevent spin crossover trapping 1–4 in the HS state.

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