Influence of Foam Adjuvants on Activity of Selected Herbicides

Weed Science ◽  
1974 ◽  
Vol 22 (4) ◽  
pp. 384-388 ◽  
Author(s):  
H. G. Mccall ◽  
C. J. Scifres ◽  
M. G. Merkle
Keyword(s):  
Acetic Acid ◽  
Residual Life ◽  
Diesel Oil ◽  
Prosopis Juliflora ◽  
Acid Uptake ◽  
Quercus Virginiana ◽  
Foam Generation ◽  
Live Oak ◽  
Anisic Acid ◽  
Oil Water

Three blended foam adjuvants increased 2,4,5-T [(2,4,5-trichlorophenoxy)acetic acid] uptake from aqueous solutions by detached live oak (Quercus virginianaMill.) leaves as compared to uptake from water alone. There were no differences in honey mesquite [Prosopis juliflora(Swartz.) D.C. var.glandulosa(Torr.) Cockerell] control with 2,4,5-T or 1:1 combinations of 2,4,5-T with picloram (4-amino-3,5,6-trichloropicolinic acid) or with dicamba (3,6-dichloro-o-anisic acid) at 0.56 kg/ha whether applied in water + 0.5% (v/v) foam adjuvant or in a diesel oil: water (1:4, v/v) emulsion. Residual life of picloram in native forages was not extended by foam carrier as compared to water, water and surfactant, and diesel oil:water emulsion as carrier. Foam generation from adjuvants with expansion ratios (ER) of two to four was less susceptible to alteration from addition of commercially-formulated herbicides than was an adjuvant with an ER of seven. Foam adjuvant ER's increased in a curvilinear fashion as water temperature was increased from 5 to 50 C.

Control of Woody Plants with Herbicide Mixtures

Weed Science ◽  
1973 ◽  
Vol 21 (5) ◽  
pp. 423-426 ◽  
Author(s):  
R. E. Meyer ◽  
R. W. Bovey
Keyword(s):  
Acetic Acid ◽  
Woody Plants ◽  
Prosopis Juliflora ◽  
Acacia Farnesiana ◽  
Quercus Virginiana ◽  
Live Oak ◽  
Anisic Acid ◽  
Herbicide Mixtures ◽  
Dichlorophenoxy Acetic Acid ◽  
Honey Mesquite

Honey mesquite [Prosopis juliflora(Swartz) DC. var.glandulosa(Torr.) Cockerell], huisache [Acacia farnesiana(L.) Willd.], Macartney rose (Rosa bracteataWendl.), live oak (Quercus virginianaMill.), and whitebrush (Aloysia lycioidesCham.) were sprayed with herbicides alone and in mixtures. Mixtures of picloram (4-amino-3,5,6-trichloropicolinic acid) + dicamba (3,6-dichloro-o-anisic acid) at 0.56 + 0.56 and 1.12 + 1.12 kg/ha were most effective for killing honey mesquite in July. Picloram or picloram + dicamba were more effective for defoliating huisache than 2,4,5-T [(2,4,5-trichlorophenoxy)acetic acid], dicamba, or other mixtures of herbicides. On Macartney rose picloram as the salt or ester was most effective, but some mixtures of picloram plus either 2,4-D [(2,4-dichlorophenoxy)acetic acid] or 2,4,5-T were as effective as picloram alone. On live oak, the most effective treatments generally contained at least 1.12 kg/ha of picloram either alone or in mixtures with dicamba or 2,4,5-T. Picloram alone killed as many or more whitebrush plants than MCPA [[(4-chloro-o-tolyl)oxy]acetic acid], dicamba, 2,4,5-T, 2,4-D, or mixtures.

Triclopyr for Control of Honey Mesquite (Prosopis julifloravar.glandulosa)

Weed Science ◽  
1983 ◽  
Vol 31 (5) ◽  
pp. 681-685 ◽  
Author(s):  
Pete W. Jacoby ◽  
Cecil H. Meadors
Keyword(s):  
Acetic Acid ◽  
Diesel Oil ◽  
Prosopis Juliflora ◽  
Anisic Acid ◽  
Oil Water ◽  
Honey Mesquite

Triclopyr {[(3,5,6-trichloro-2-pyridinyl)oxy] acetic acid} was aerially applied at four locations in Texas to determine effectiveness of the amine and ester formulations for the control of honey mesquite [Prosopis juliflora(Swartz) DC. var.glandulosa(Torr.) Cockerell # PRCJG]. The ester formulation was superior to the amine in most trials. Honey mesquite control with triclopyr amine was comparable to that with 2,4,5-T [(2,4,5-trichlorophenoxy)acetic acid] while control with triclopyr ester was similar to that attained with a 1:1 mixture of 2,4, 5-T and picloram (4-amino-3,5,6-trichloropicolinic acid). Honey mesquite control obtained with a 1:1 mixture of 2,4,5-T and dicamba (3,6-dichloro-o-anisic acid) was intermediate between that with the 2,4,5-T and picloram mixture and that with 2,4,5-T alone. Efficacy of triclopyr increased as rates were increased from 0.3 to 0.6 kg ae/ha and from 0.6 to 1.1 kg/ha. Triclopyr formulations were effective when applied in either water or diesel oil/water emulsions. Honey mesquite control from triclopyr in combination with picloram was generally comparable to that from the mixture of picloram and 2,4,5-T.

Evaluation of Polymerized Herbicides for Brush Control

Weed Science ◽  
1972 ◽  
Vol 20 (4) ◽  
pp. 332-335 ◽  
Author(s):  
R. W. Bovey ◽  
R. E. Meyer ◽  
R. D. Baker ◽  
J. R. Baur
Keyword(s):  
Acetic Acid ◽  
Picolinic Acid ◽  
Acacia Farnesiana ◽  
Quercus Virginiana ◽  
Live Oak ◽  
Anisic Acid ◽  
Ilex Vomitoria ◽  
Brush Control ◽  
Ulmus Alata ◽  
Dichlorophenoxy Acetic Acid

Polymerized and conventional (2,4-dichlorophenoxy)-acetic acid (2,4-D), (2,4,5-trichlorophenoxy)acetic acid (2,4,5-T), 3,6-dichloro-o-anisic acid (dicamba), and 4-amino-3,5,6-trichloro-picolinic acid (picloram) were applied alone and in certain combinations to several brush species. Generally there were no significant differences in effectiveness between conventional and polymerized herbicides on honey mesquite(Prosopis juliflora(Swartz) DC. var.glandulosa(Torr.) Cockrell), huisache(Acacia farnesianaL. Willd.), Macartney rose(Rosa bracteataWendl.), live oak(Quercus virginianaMill.), whitebrush(Aloysia lycioidesCham.), and winged elm(Ulmus alataMichx.). Conventional granular picloram was more effective on yaupon(Ilex vomitoriaAit.) than polymerized formulations.

Absorption of 2,4,5-T Applied in Various Carriers to Honey Mesquite

Weed Science ◽  
1973 ◽  
Vol 21 (2) ◽  
pp. 94-96 ◽  
Author(s):  
C. J. Scifres ◽  
J. R. Baur ◽  
R. W. Bovey
Keyword(s):  
Acetic Acid ◽  
Diesel Oil ◽  
Prosopis Juliflora ◽  
Butyl Ether ◽  
Paraffin Oil ◽  
Oil Water ◽  
Honey Mesquite

Absorption of the butyl ether esters of (2,4,5-trichlorophenoxy)-acetic acid (2,4,5-T) by honey mesquite [Prosopis juliflora (Swartz) DC. var. glandulosa (Torr.) Cockerell] foliage was more rapid when 0.56 kg/ha was applied in 15 L/ha paraffin oil than when diesel oil, water, or emulsions of the oils in water were used as carriers. However, carrier had little effect on 2,4,5-T translocation to stems or roots. The percentage of greenhouse-grown honey mesquite plants killed was reduced when 2,4,5-T was applied in diesel oil as compared to other carriers studied.

Comparison of Salt and Ester Formulations of Picloram

Weed Science ◽  
1970 ◽  
Vol 18 (4) ◽  
pp. 447-451 ◽  
Author(s):  
R. W. Bovey ◽  
M. L. Ketchersid ◽  
M. G. Merkle
Keyword(s):  
Potassium Salt ◽  
Uv Light ◽  
Diesel Oil ◽  
Acacia Farnesiana ◽  
Quercus Virginiana ◽  
Live Oak ◽  
Petri Dishes ◽  
The Difference ◽  
Extensive Degradation ◽  
Ulmus Alata

Under Texas conditions, the potassium salt of 4-amino-3,5,6-trichloropicolinic acid (picloram) usually was more effective than the isooctyl ester formulation for control of live oak (Quercus virginianaMill.), yaupon(Ilex vomitoriaAit.), winged elm(Ulmus alataMichx.), huisache (Acacia farnesiana(L.) Willd.), and honey mesquite(Prosopis juliflora(Swartz) DC. var.glandulosa(Torr.) Cockerell). Possible reasons for the difference in effectiveness of picloram formulations were studied in the laboratory. Extensive degradation of the ester of picloram (96%) occurred in open Petri dishes after 72 hr exposure to ultraviolet (uv) light, compared to a loss of 26% for the salt of picloram. Forty-five percent of the isooctyl ester of picloram was lost at high temperatures (60 C), whereas only 2% of the potassium salt of picloram was lost after 1 week at 60 C from open Petri dishes in a dark oven. Application of the ester to soils reduced thermal and ultraviolet light degradation losses compared to losses from open Petri dishes. Loss of the ester was greater when applied in diesel oil to Petri dishes than in either water or paraffin oil. The salt of picloram leached most after 12.5 cm simulated rainfall in soil columns to the 17.5 to 30-cm level (907 μg), followed by the acid (360 μg), and last the isooctyl ester (0 μg). However, considerable acid (161 μg) was recovered at the 32.5 to 45-cm depth from the isooctyl ester treatment exposed to wet soils for 3 days, indicating hydrolysis of the ester to acid.

Hexazinone and Other Herbicides on Texas Woody Plants

Weed Science ◽  
1980 ◽  
Vol 28 (3) ◽  
pp. 358-362 ◽  
Author(s):  
R. E. Meyer ◽  
R. W. Bovey
Keyword(s):  
Woody Plants ◽  
Prosopis Juliflora ◽  
Gleditsia Triacanthos ◽  
Acacia Farnesiana ◽  
Quercus Virginiana ◽  
Live Oak ◽  
Post Oak ◽  
Ilex Vomitoria ◽  
Quercus Stellata ◽  
Honey Mesquite

Hexazinone [3-cyclohexyl-6-(dimethylamino)-1-methyl-1,3,5-triazine-2,4(1H,3H)-dione] was applied to honeylocust (Gleditsia triacanthosL.), honey mesquite [Prosopis juliflora(Swartz) DC. var.glandulosa(Torr.) Cockerell], huisache [Acacia farnesiana(L.) Willd.], live oak (Quercus virginianaMill.), Macartney rose (Rosa bracteataWendl.), post oak (Quercus stellataWangenh.), saw greenbrier (Smilax bona-noxL.), whitebrush (Aloysia lycioidesCham.), and yaupon (Ilex vomitoriaAit.). Bromacil (5-bromo-3-sec-butyl-6-methyluracil) and tebuthiuron {N-[5-(1,1-dimethylethyl)-1,3,4-thiadiazol-2-yl]-N,N′-dimethylurea} were used for comparison in some experiments. Hexazinone was required at the following rates to kill at least 75% of the following species: 1.1 kg/ha for live oak, 2.2 kg/ha for post oak, 4.5 kg/ha for huisache (at Bryan, Texas) and whitebrush, and 9 kg/ha for honeylocust. Hexazinone was ineffective at 9 kg/ha for control of honey mesquite, huisache (at Washington, Texas), Macartney rose, saw greenbrier, and yaupon. Tebuthiuron at 1.1 kg/ha killed 80% of the live oak, and as a subsurface spray at 4.5 kg/ha, killed huisache (at Washington, Texas). Bromacil was effective on huisache at 9 kg/ha.

Control of Honey Mesquite (Prosopis julifloravar.glandulosa) with 3,6-Dichloropicolinic Acid

Weed Science ◽  
1981 ◽  
Vol 29 (4) ◽  
pp. 376-378 ◽  
Author(s):  
P. W. Jacoby ◽  
C. H. Meadors ◽  
M. A. Foster
Keyword(s):  
Acetic Acid ◽  
Prosopis Juliflora ◽  
Absolute Increase ◽  
Anisic Acid ◽  
Honey Mesquite

The herbicide 3,6-dichloropicolinic acid was more effective than 2,4,5-T [(2,4,5-trichlorophenoxy)acetic acid] or equal-ratio combinations of 2,4,5-T with picloram (4-amino-3,5,6-trichloropicolinic acid) or dicamba (3,6-dichloro-o-anisic acid) when aerially applied as broadcast sprays for control of honey mesquite [Prosopis juliflora(Swartz) DC. var.glandulosa(Torr.) Cockerell]. Applied at 0.56 kg/ha, 3,6-dichloropicolinic acid controlled 60 and 68% of the honey mesquite at two locations; whereas, the mixture of 2,4,5-T and picloram controlled only 21 and 30% of the honey mesquite at the same rate of application. The herbicide 3,6-dichloropicolinic acid was equally effective when applied alone or in 1:1 mixtures with 2,4,5-T, picloram, or triclopyr {[(3,5,6-trichloro-2-pyridinyl)oxy] acetic acid} at equivalent rates. Applying 3,6-dichloropicolinic acid at 1.12 kg/ha resulted in an absolute increase in mortality of 26% over the 0.56-kg/ha rate.

A Carrier for Some Water-Soluble Herbicides

Weed Science ◽  
1971 ◽  
Vol 19 (1) ◽  
pp. 102-106 ◽  
Author(s):  
Samuel J. Shellhorn ◽  
Herbert M. Hull
Keyword(s):  
Acetic Acid ◽  
Dimethyl Sulfoxide ◽  
Prosopis Juliflora ◽  
Water Soluble ◽  
Anisic Acid ◽  
Velvet Mesquite

A mixture of dimethyl sulfoxide (DMSO), glycerol, phytobland oil, and water (50:25:15:10, v/v) proved to be outstandingly effective as a carrier for water-soluble formulations of 4-amino-3,5,6-trichloropicolinic acid (picloram), (2,4,5-trichlorophenoxy)acetic acid (2,4,5-T), and mixtures thereof. The carrier was selected after numerous experiments in which these and other adjuvants, used individually, gave at least some degree of herbicidal enhancement on velvet mesquite seedlings [Prosopis juliflora var. velutina (Woot.) Sarg.]. Maximum synergism between the carrier complex and herbicide occurred with the triethylamine salt of 2,4,5-T; relatively little influence on the butoxyethanol ester was observed. Picloram and 3,6-dichloro-o-anisic acid (dicamba) were intermediate in activity between the two phenoxy formulations.

Absorption and Penetration of Picloram and 2,4,5-T into Detached Live Oak Leaves

Weed Science ◽  
1971 ◽  
Vol 19 (2) ◽  
pp. 138-141 ◽  
Author(s):  
J. R. Baur ◽  
R. W. Bovey ◽  
R. D. Baker ◽  
Imogene Riley
Keyword(s):  
Acetic Acid ◽  
Aqueous Solutions ◽  
Quercus Virginiana ◽  
Live Oak ◽  
Herbicide Concentration ◽  
Oak Leaves

Detached live oak (Quercus virginianaMill.) leaves were immersed in aqueous solutions of 4-amino-3,5,6-trichloropicolinic acid (picloram) or (2,4,5-trichlorophenoxy)acetic acid (2,4,5-T) for periods up to 4 hr. Herbicide concentration ranged from 10−3to 10−6M; solutions were adjusted to either pH 4, 6, 7, or 8. Absorption of picloram in the presence of equimolar concentrations of 2,4,5-T exceeded that noted for picloram alone. The presence of picloram in the treating solutions had no effect on absorption of 2,4,5-T. This technique allows evaluation of absorption and penetration characteristics of mixtures of herbicides, solvents, and adjuvants.

Herbicide Combinations for Woody Plant Control

Weed Science ◽  
1968 ◽  
Vol 16 (3) ◽  
pp. 332-335 ◽  
Author(s):  
R. W. Bovey ◽  
F. S. Davis ◽  
H. L. Morton
Keyword(s):  
Plant Species ◽  
Woody Plant ◽  
Prosopis Juliflora ◽  
Antagonistic Effect ◽  
Acacia Farnesiana ◽  
Quercus Virginiana ◽  
Live Oak ◽  
Ilex Vomitoria ◽  
Plant Control ◽  
Honey Mesquite

We studied 4-amino-3,5,6-trichloropicolinic acid (picloram) alone and in combination with 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) or 1,1′-dimethyl-4,4′-bipyridinium salt (paraquat) for control of several greenhouse, nursery, and natural-grown, woody plant species. Picloram:paraquat combinations improved the control of some species such as yaupon (Ilex vomitoria Ait.) as compared to picloram alone at equal rates; but it had an antagonistic effect on huisache (Acacia farnesiana (L.) Willd.) and honey mesquite (Prosopis juliflora (Swartz) DC. var. glandulosa (Torr.) Cockerell). Evaluation of picloram: 2,4,5-T combinations suggested that 2,4,5-T sometimes could be added in equal amounts to picloram to increase control or reduce picloram rates proportionately on huisache, honey mesquite and live oak (Quercus virginiana Mill.).

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