Early Silica Diagenesis in Volcanic and Sedimentary Rocks: Devitrification and Replacement Phenomena
Although silica is a primary component of flints, cherts, volcanic glasses, and siliceous deep sea oozes, mobilization pathways and modes of reprecipitation of this element during early diagenesis of volcanic and sedimentary rocks remains an elusive geologic problem. As a result, the source and mode of deposition of vast Tertiary silica deposits of the Atlantic and Gulf Coastal Plain and offshore deep sea deposits is currently a topic of sharp debate. Both volcanic and biogenous sources of silica have been variously postulated as ultimate or immediate silica sources for a broad range of fine-grained silica-rich rocks including claystones, “opal claystones,” “buhrstones,” “pseudobuhrstones,” cristobalitic cherts, and silicified chalks and limestones. Current scanning electron microscope/electron microprobe investigations of incipient stages of diagenesis in geologically young biogenous sediments, volcanic glasses, and silica-replaced carbonate rocks, however, do allow silica pathways to be traced and silica sources to be ascertained.