Intrinsic absorption profile and radiative cooling rate of a PAH cation revealed by action spectroscopy in the cryogenic electrostatic storage ring DESIREE
2019 ◽
Vol 15
(S350)
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pp. 127-131
Keyword(s):
Hot Band
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AbstractThe multi-photon photodissociation (MPD) action spectrum of the coronene cation $$({{\rm{C}}_{24}}{\rm{H}}_{12}^ + )$$ has been measured as a function of storage time up to 60 s in the cryogenic electrostatic storage ring DESIREE. These measurements reveal not only the intrinsic absorption profile of isolated coronene cations, but also the rate at which hot-band absorptions are quenched by radiative cooling. The cooling rate is interpreted using a Simple Harmonic Cascade model of infrared vibrational emission.
2011 ◽
Vol 82
(6)
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pp. 065112
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2012 ◽
Vol 388
(14)
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pp. 142013
2014 ◽
Vol 488
(10)
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pp. 102011