Intrinsic absorption profile and radiative cooling rate of a PAH cation revealed by action spectroscopy in the cryogenic electrostatic storage ring DESIREE

2019 ◽  
Vol 15 (S350) ◽  
pp. 127-131
Author(s):  
Mark H. Stockett ◽  
Mikael Björkhage ◽  
Henrik Cederquist ◽  
Henning T. Schmidt ◽  
Zettergren Henning

AbstractThe multi-photon photodissociation (MPD) action spectrum of the coronene cation $$({{\rm{C}}_{24}}{\rm{H}}_{12}^ + )$$ has been measured as a function of storage time up to 60 s in the cryogenic electrostatic storage ring DESIREE. These measurements reveal not only the intrinsic absorption profile of isolated coronene cations, but also the rate at which hot-band absorptions are quenched by radiative cooling. The cooling rate is interpreted using a Simple Harmonic Cascade model of infrared vibrational emission.

2019 ◽  
Vol 217 ◽  
pp. 126-137 ◽  
Author(s):  
Mark H. Stockett ◽  
Mikael Björkhage ◽  
Henrik Cederquist ◽  
Henning T. Schmidt ◽  
Henning Zettergren

The intrinsic absorption profile and radiative cooling rate of coronene cations are reported.


2013 ◽  
Vol 110 (6) ◽  
Author(s):  
S. Martin ◽  
J. Bernard ◽  
R. Brédy ◽  
B. Concina ◽  
C. Joblin ◽  
...  

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Vol 82 (6) ◽  
pp. 065112 ◽  
Author(s):  
R. D. Thomas ◽  
H. T. Schmidt ◽  
G. Andler ◽  
M. Björkhage ◽  
M. Blom ◽  
...  

2011 ◽  
Author(s):  
A. A. Almuqhim ◽  
S. M. Alshammari ◽  
M. O. A. El Ghazaly ◽  
A. I. Papash ◽  
C. P. Welsch ◽  
...  

2012 ◽  
Vol 388 (14) ◽  
pp. 142013
Author(s):  
T J Reddish ◽  
M R Sullivan ◽  
P Hammond ◽  
P A Thorn ◽  
G Arora

2017 ◽  
Vol 875 ◽  
pp. 032035
Author(s):  
M. Saito ◽  
T. Tanabe ◽  
M. Lintuluoto ◽  
E. B. Starikov ◽  
K. Noda ◽  
...  

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