Polaragraphic Determination of Ferrous and Ferric Ion in Refractory Minerals

1956 ◽  
Vol 28 (1) ◽  
pp. 97-98 ◽  
Author(s):  
G. S. Bien ◽  
E. D. Goldberg

1985 ◽  
Vol 49 (350) ◽  
pp. 101-102 ◽  
Author(s):  
R. D. Gillard
Keyword(s):  

AbstractHey's observation of reduction of ferric ion bound to 1,10-phenanthroline in water is explained in terms of the analogy between quaternization of the ligand and its coordination by iron(III).



1965 ◽  
Vol 11 (6) ◽  
pp. 624-627 ◽  
Author(s):  
Walton H Marsh ◽  
Benjamin Fingerhut ◽  
Henry Miller

Abstract Automated and manual direct methods for the determination of urea in blood or serum are described. These methods determine urea by the colored product formed when urea, in relatively weak acid solution, reacts with diacetyl monoxime in the presence of thiosemicarbazide and ferric ion. Results are compared with those obtained by urease conversion of urea to ammonia and measurement of the ammonia by nesslerization.



1932 ◽  
Vol 5 (3) ◽  
pp. 356-359
Author(s):  
F. Kirchhof

Abstract The determination of small quantities of copper in fabrics and in rubberized materials can be simplified by destruction with concentrated nitric acid, which accelerates the ignition to the final ash. At the same time, this method avoids the usual danger of volatilization of copper as chloride as a result of the presence of chlorine from white factice or from cold vulcanization. Likewise, precipitation of the copper as sulfide can be avoided by repeating the precipitation of the extract from the ash, which contains predominantly aluminum and iron, with ammonia. In this second precipitation, only around 1 to 2 per cent of the total quantity of copper is retained in the precipitate and filter, and this quantity may in most cases be neglected. The ordinary colorimetric method used in the past for the detection of copper as complex cuprammonium ion can be made about ten times as sensitive by making use of the reaction: Cu+ + + 2I− → CuI + I. This is, however, applicable only in the complete absence of the ferric ion and of nitric acid in the test solution. The sensitivity can be increased still more by the addition of starch. Another advantage of the determination of copper by measurement of the equivalent quantity of iodine lies in the fact that, if necessary, only one-tenth as much sample need be used, but in this case as in all such determinations, the copper must be distributed uniformly throughout the material to be analyzed.





1964 ◽  
Vol 13 (6) ◽  
pp. 544-547 ◽  
Author(s):  
Masakichi NISHIMURA ◽  
Makoto SAITO ◽  
Yasumitsu UZUMASA


1968 ◽  
Vol 40 (3) ◽  
pp. 603-605 ◽  
Author(s):  
Toru. Yoshioka ◽  
Yoichi. Goshi ◽  
Hiroko. Kohno


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