Gas Chromatographic Head Space Techniques for the Quantitative Determination of Volatile Components in Multicomponent Aqueous Solutions.

1964 ◽  
Vol 36 (1) ◽  
pp. 77-82 ◽  
Author(s):  
R. E. Kepner ◽  
Henk. Maarse ◽  
Jacobus. Strating
Keyword(s):  
Aqueous Solutions ◽  
Quantitative Determination ◽  
Volatile Components ◽  
Head Space

scholarly journals Recovery of Hg(0) from the Aqueous Hg(I/II) Present in Analyte Solution after Quantitative Determination of Iron

2013 ◽  
Vol 2013 ◽  
pp. 1-3
Author(s):  
Suman K. Giri ◽  
Nigamananda Das
Keyword(s):  
Aqueous Solutions ◽  
Quantitative Determination ◽  
Simple Method ◽  
Stoichiometric Amount ◽  
Analyte Solution

An easy and feasible approach to recover HgCl2, used in quantitative determination of iron values, as Hg(0) was described. Both Hg(I) and Hg(II), present in the solution after quantitative determination of iron, was completely reduced to Hg(0) by the addition of aluminium chips in more slightly excess than the stoichiometric amount. The purity of recovered Hg(0) was verified by comparing the value of density with pure mercury. This simple method may be useful to remove the mercury from other waste aqueous solutions before their discharge into the environment.

Gas Chromatographic Determination of Residual Hexane in Modified Hop Extract

1972 ◽  
Vol 55 (6) ◽  
pp. 1226-1227
Author(s):  
Mark A Litchman ◽  
Lewis A Turano ◽  
Ronald P Upton
Keyword(s):  
Liquid Chromatography ◽  
Quantitative Determination ◽  
Chromatographic Determination ◽  
Methanol Solution ◽  
Chromatographic Column ◽  
Gas Liquid Chromatography ◽  
Porapak Q ◽  
Residual Hexane ◽  
Head Space

Abstract A method is described for the quantitative determination of hexane in modified hop extract by head-space gas-liquid chromatography. A sample of extract is weighed into a serum vial and water-methanol solution is added. The vial is sealed tightly and heated 1 hr in a 70°C bath. A sample of the head-space gas over the solution is injected onto a Porapak Q gas chromatographic column for determination. Recovery of 2–29 ppm hexane added to potassium isohumulone was 95.5–114.8%. The method may be applicable to other hop extracts.

Quantitative Determination of Cadmium in Water-Soluble Color Additives by Atomic Absorption Spectroscopy

1972 ◽  
Vol 55 (5) ◽  
pp. 1145-1149
Author(s):  
Lueangier Moten
Keyword(s):  
Aqueous Solutions ◽  
Quantitative Determination ◽  
Atomic Absorption ◽  
Absorption Spectroscopy ◽  
Atomic Absorption Spectroscopy ◽  
Quantitative Method ◽  
Water Soluble ◽  
Low Levels ◽  
Absorption Measurements

Abstract A quantitative method is presented for the determination of cadmium at low levels (5–20 ppm) in water-soluble color additives by atomic absorption spectroscopy. Absorption measurements were made on aqueous solutions of typical color additives to which known amounts of cadmium had been added. The method requires no pretreatment of sample and should be applicable to all water-soluble color additives.

Methods for quantitative determination of ethylene in aqueous solutions for biological studies.

1981 ◽  
Vol 4 (4) ◽  
pp. 271-274
Author(s):  
P. K. Bassi ◽  
K. C. Eastwell ◽  
T. Akalehiywot ◽  
Mary S. Spencer
Keyword(s):  
Aqueous Solutions ◽  
Quantitative Determination ◽  
Biological Studies

scholarly journals Development and Validation of Method for the Quantitative Determination of Zinc in its Chelate Complexes Using Energy Dispersive X-ray Fluorescence Spectroscopy

2021 ◽  
Vol 10 (4) ◽  
pp. 154-161
Author(s):  
А. V. Marukhlenko ◽  
Т. V. Maksimova ◽  
Т. V. Pleteneva ◽  
М. A. Morozova
Keyword(s):  
Fluorescence Spectroscopy ◽  
Aqueous Solutions ◽  
Quantitative Determination ◽  
Zinc Sulfate ◽  
Zinc Content ◽  
Chelate Complex ◽  
Molar Ratio ◽  
X Ray ◽  
Validation Parameters

Introduction. The production, standardization and quality control process of various dietary supplements containing chelated zinc requires validated quantitative assessment methods. In this work, we propose an X-ray fluorescence spectroscopy (XRF) technique for determining the zinc content in the composition of coordination compounds using the example of a synthesized chelate complex with methionine.Aim. To synthesize Zn(Met)2 chelate complex, to develop and validate a method for its quantitative analysis using the XRF method.Materials and methods. The synthesized zinc chelate complex was investigated by IR spectroscopy. The XRF method was used to develop a method for quantifying the zinc content in the synthesized complex. We used dry mixtures of zinc sulfate monohydrate and L-methionine (Met) in a molar ratio of Zn to Met – 1 : 1, 1 : 2, 1 : 4, 1 : 8 and 1 : 16 and also aqueous solutions of zinc sulfate and L-methionine in a molar ratio of Zn to Met 1 : 2 with Zn concentrations from 0.5 to 100 mmol/l as calibration standards. Complexometric titration was used as an arbitration method for the quantitative determination of zinc content in the samples under study.Results and discussion. The IR spectrum of chelate complex confirmed the presence of a donor-acceptor bond between Zn2+ and the nitrogen atom of amino group in methionine. The titration results showed chelate compounds have a composition corresponding to the stoichiometric formula Zn(Met)2. XRF analysis of dry standard mixed samples demonstrated the presence of matrix effect, that makes impossible an accurate assessment of zinc content in the chelate compound. According to the XRF spectra of aqueous solutions containing zinc sulfate and methionine in a ratio of 1 : 2 at a zinc concentration of 0.5; 1; 2; 3; 4; 5; 10; 25; 50 and 100 mmol/L, a calibration graph was constructed – the dependence of the fluorescence signal intensity for the Kα line of zinc on the concentration of zinc in the solution (r = 0.9996). The method was evaluated by the following validation parameters: specificity, linearity, correctness, precision, and analytical range. The specificity of the validated method was proven in the presence of copper, iron, and silver.Conclusion. The developed method make it possible to determine with sufficient precision and correctness the content of Zn2+ in its aqueous solutions of inorganic and organic nature by the XRF method in the concentration range from 3 to 100 mmol/l without the influence of the matrix.

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