Time-resolved phosphorimetry as a method of simultaneous analysis of two-component mixtures

1967 ◽  
Vol 39 (4) ◽  
pp. 500-503 ◽  
Author(s):  
P. A. St. John ◽  
James D. Winefordner

1999 ◽  
Vol 19 (1-4) ◽  
pp. 271-274 ◽  
Author(s):  
S. E. J. Bell ◽  
J. H. Rice ◽  
J. J. McGarvey ◽  
R. E. Hester ◽  
J. N. Moore ◽  
...  

Time-resolved resonance Raman (TR3) and absorbance difference studies of the excited states of Cu(TPP) (TPP=5,10,15,20-tetraphenylporphyrin) have been carried out with < 10 ps times resolution in THF and pyridine solvents. In THF the distinctive transient Raman bands in the ν2 and ν4 regions, previously observed with ns laser pulses, grow in the first 55 ps before decaying in 100's of ps. The ∆A spectra also show biphasic decay. This behaviour is associated with attack by solvent on the 4-coordinate excited state to form the longer lived species observed in TR3 experiments.In pyridine two component decay is also observed but it is the shorter-lived species which gives the transient Raman bands seen previously with ns laser excitation. This state is different from that seen in THF. At 5 ps delay ν4 is broader than in the ground state and, more importantly, there is a significant shift in the two pyridine bands at ca. 1000 cm-1. This implies a significant involvement of the pyridine-based orbitals in the excited state.



2009 ◽  
Vol 102 (17) ◽  
Author(s):  
R. P. Saichu ◽  
I. Mahns ◽  
A. Goos ◽  
S. Binder ◽  
P. May ◽  
...  


2021 ◽  
Author(s):  
Qi Wu ◽  
Peiling Dai ◽  
Yun Wang ◽  
Jin Zhang ◽  
Meng Li ◽  
...  

Simultaneous analysis of luminescence signals of multiple probes can improve the accuracy and efficiency of biosensing and bioimaging. Analysis of multiple signals at different wavelengths usually suffers from spectral overlap,...



1989 ◽  
Vol 93 (8) ◽  
pp. 3244-3250 ◽  
Author(s):  
Hongwen Luo ◽  
Noel Boens ◽  
Mark Van der Auweraer ◽  
Frans C. De Schryver ◽  
Angelos Malliaris


2000 ◽  
Vol 16 (7) ◽  
pp. 765-769 ◽  
Author(s):  
Kazuyuki WATANABE ◽  
Miwa ODA ◽  
Hidetoshi ARAKAWA ◽  
Masako MAEDA


2020 ◽  
Vol 65 (3) ◽  
pp. 196
Author(s):  
O. M. Navozenko ◽  
V. M. Yashchuk ◽  
Yu. P. Piryatinski ◽  
D. Gudeiko ◽  
A. P. Naumenko ◽  
...  

The absorption and luminescence of new boron-containing dyes in two-component films of Alq3 (matrix)-dye(impurity) (obtained by the method of thermal vacuum deposition) are studied. The comparison of the spectra of absorption, fluorescence, and fluorescence excitation of a dyes in one-component solutions and double-component films shows the existence of the effective electronic excitation energy transfer (EEET) from the matrix to dye molecules. Time-resolved spectra of two-component films also manifest strong EEET in these systems. For the estimation of the average exciton spreading length in Alq3 films, the diffusion model of the motion of singlet excitons is used. The diffusion coefficient is evaluated using time-resolved spectroscopy. The optimum concentrations of dyes in a light-emitting layer of OLED are evaluated based on experimental data and the used model of EEET.



2016 ◽  
Vol 55 (3) ◽  
pp. 471-484 ◽  
Author(s):  
Janina Kabatc ◽  
Katarzyna Kostrzewska ◽  
Katarzyna Jurek ◽  
Martyna Kozak ◽  
Alicja Balcerak ◽  
...  


2005 ◽  
Vol 28 (14) ◽  
pp. 2179-2194 ◽  
Author(s):  
Erdal Dinç ◽  
Özgür Üstündağ ◽  
Abdil Özdemir ◽  
Dumitru Baleanu


Langmuir ◽  
1989 ◽  
Vol 5 (4) ◽  
pp. 948-953 ◽  
Author(s):  
Steven Reekmans ◽  
Noel Boens ◽  
Mark Van der Auweraer ◽  
Hongwen Luo ◽  
Frans C. De Schryver


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