Physical significance of transfer activity coefficients for single ions

Orest. Popovych

doi:10.1021/ac60349a006

Propriétés de solvation des solutions concentrées en acide phosphorique

Canadian Journal of Chemistry ◽

10.1139/v86-098 ◽

1986 ◽

Vol 64 (3) ◽

pp. 608-614 ◽

Cited By ~ 9

Author(s):

C. Louis ◽

J. Bessière

Keyword(s):

Activity Coefficients ◽

Acid Solutions ◽

Reduction Reactions ◽

Basic Properties ◽

Transfer Activity ◽

Oxidation Reduction ◽

Normal Potential ◽

Oxygen Atoms

Solvation properties of ions inH2O–H3PO4 media (1–14 M) are characterized with their solvation transfer activity coefficients f. These are calculated from normal potential or solubility values, and indicate an increasing solvation for anions and decreasing solvation for cations in concentrated acid solutions. For each species, the range depends on its number of charges, on the existence of oxygen atoms in its structure, and on its basic properties. The consequences of variation of solvation on oxidation–reduction reactions and solubility properties are studied.

Relationship between transfer activity coefficients, S1 S2, of cryptate 2.2.2 complexes and their stability constant in various solvents

Proceedings of the National Academy of Sciences ◽

10.1073/pnas.77.9.5040 ◽

1980 ◽

Vol 77 (9) ◽

pp. 5040-5042 ◽

Cited By ~ 12

Author(s):

I. M. Kolthoff ◽

M. K. Chantooni

Keyword(s):

Stability Constant ◽

Activity Coefficients ◽

Transfer Activity

Transfer activity coefficients of crown ethers and their alkali metal ion complexes between water and polar nonaqueous solvents

BUNSEKI KAGAKU ◽

10.2116/bunsekikagaku.52.89 ◽

2003 ◽

Vol 52 (2) ◽

pp. 89-105 ◽

Cited By ~ 6

Author(s):

Shoichi KATSUTA ◽

Yasuyuki TAKEDA

Keyword(s):

Alkali Metal ◽

Crown Ethers ◽

Activity Coefficients ◽

Metal Ion ◽

Nonaqueous Solvents ◽

Metal Ion Complexes ◽

Alkali Metal Ion ◽

Transfer Activity

Solubility products and transfer activity coefficients of potassium picrate, potassium tetraphenylborate, and tetraphenylphosphonium picrate in methanol-water mixtures at 25.degree.C

Journal of Chemical & Engineering Data ◽

10.1021/je60082a025 ◽

1979 ◽

Vol 24 (3) ◽

pp. 215-218 ◽

Cited By ~ 6

Author(s):

Pat J. LaBrocca ◽

Rebecca Phillips ◽

Sidney S. Goldberg ◽

Orest Popovych

Keyword(s):

Activity Coefficients ◽

Transfer Activity ◽

Solubility Products ◽

Potassium Picrate

Relation between stability constants of metal ion cryptates in two solvents and the transfer activity coefficients of the metal ions

Journal of Solution Chemistry ◽

10.1007/bf00646725 ◽

1985 ◽

Vol 14 (1) ◽

pp. 1-12 ◽

Cited By ~ 24

Author(s):

Miran K. Chantooni ◽

Izaak M. Kolthoff

Keyword(s):

Metal Ions ◽

Stability Constants ◽

Activity Coefficients ◽

Metal Ion ◽

Transfer Activity

Transfer activity coefficients between some dipolar aprotic solvents and alcohols of salts composed of various anions and potassium complexed with Bis(4,4'(5')-t-butylbenzo)-18-crown-6

Australian Journal of Chemistry ◽

10.1071/ch9831753 ◽

1983 ◽

Vol 36 (9) ◽

pp. 1753 ◽

Cited By ~ 13

Author(s):

Jr MK Chantooni ◽

IM Kolthoff ◽

G Roland

Keyword(s):

Dimethyl Sulfoxide ◽

Stability Constants ◽

Propylene Carbonate ◽

Activity Coefficients ◽

Isopropyl Alcohol ◽

The Other ◽

Aprotic Solvents ◽

Transfer Activity ◽

Dipolar Aprotic Solvents

Stability constants, Kf(LK+) and Kf(LKX) = [LKX]/[L][KX] at 25� in the dipolar aprotic solvents acetone (Me2CO), acetonitrile (MeCN), propylene carbonate (pc), N,N-dimethylformamide (HCONMe2), dimethyl sulfoxide (Me2SO), as well as in the alcohols, methanol (MeOH), isopropyl alcohol (Pr1OH), and butan -1-ol (BuOH) have been determined, L being bis(4,4'(5')-t-buty1benzo)-18- crown-6 (di(BuBo)-18-cr-6). This crown is considerably more lipophylic than is dibenzo-18-crown-6. Values of Kf(LKX) have been found from values of Kf(LK+), KA(KX) and KA(LKX). Transfer activity coefficients, Me2COγS, have been calculated (based on the Parker proposal that γ(Ph4As+) = γ(BPh4-) between acetone and the various solvents used of K+, Br-, ClO4-, P1- (picrate), LK+, KX, and LKX. It is found that K+ is more strongly solvated in Me2CO than in the other aprotic solvents of low donicity. The reverse is true between Me2CO and HCONMe2 or Me2SO (even after correcting for the Born effect).

ChemInform Abstract: TRANSFER ACTIVITY COEFFICIENTS OF ORTHO-SUBSTITUTED AND NON-ORTHO-SUBSTITUTED BENZOATES BETWEEN WATER, METHANOL, AND POLAR APROTIC SOLVENTS

Chemischer Informationsdienst ◽

10.1002/chin.197424104 ◽

1974 ◽

Vol 5 (24) ◽

pp. no-no

Author(s):

M. K. JUN. CHANTOONI ◽

I. M. KOLTHOFF

Keyword(s):

Activity Coefficients ◽

Aprotic Solvents ◽

Transfer Activity

Stabilities in Water and Transfer Activity Coefficients between Nonaqueous Solvents and Water of 1 : 1 Complexes of 15,15-Dimethyl-16-crown-5 with Metal Ions

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.74.311 ◽

2001 ◽

Vol 74 (2) ◽

pp. 311-315 ◽

Cited By ~ 2

Author(s):

Shoichi Katsuta ◽

Takako Motoyama ◽

Yasuyuki Takeda ◽

Mikio Ouchi

Keyword(s):

Metal Ions ◽

Activity Coefficients ◽

Nonaqueous Solvents ◽

Transfer Activity

Stabilities and Transfer Activity Coefficients from Water to Polar Nonaqueous Solvents of Benzo-15-Crown-5- and 15-Crown-5-Alkali Metal Ion Complexes

Journal of Coordination Chemistry ◽

10.1080/00958970211903 ◽

2002 ◽

Vol 55 (4) ◽

pp. 459-468 ◽

Cited By ~ 10

Author(s):

Yasuyuki Takeda ◽

Munehiro Tanaka ◽

Hiroaki Yamada ◽

Shoichi Katsuta

Keyword(s):

Alkali Metal ◽

Activity Coefficients ◽

Metal Ion ◽

Nonaqueous Solvents ◽

Metal Ion Complexes ◽

Alkali Metal Ion ◽

Transfer Activity

Solubility products and transfer activity coefficients of rubidium and cesium tetraphenylborates and tetraphenylarsonium picrate in methanol-water mixtures at 25.degree.C

Journal of Chemical & Engineering Data ◽

10.1021/je00033a009 ◽

1983 ◽

Vol 28 (3) ◽

pp. 316-318 ◽

Cited By ~ 4

Author(s):

Anna Berne ◽

Barbara Wajsbrot ◽

Phillip D. Klahr ◽

Orest Popovych

Keyword(s):

Activity Coefficients ◽

Transfer Activity ◽

Solubility Products