Ion-selective electrode determination of complex formation constants in submicromolar silver nitrate solution

1975 ◽  
Vol 47 (13) ◽  
pp. 2310-2313 ◽  
Author(s):  
Arthur L. Cummings ◽  
Keith P. Anderson
Keyword(s):  
Complex Formation ◽  
Silver Nitrate ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Formation Constants ◽  
Ion Selective Electrode ◽  
Selective Electrode ◽  
Complex Formation Constants

Comparison of calcium complexation of some carboxylic acids derived from D­glucose and D-fructose

1995 ◽  
Vol 73 (8) ◽  
pp. 1338-1347 ◽  
Author(s):  
Hélène Bazin ◽  
Gérard Descotes ◽  
Alain Bouchu ◽  
Michelle Petit-Ramel
Keyword(s):  
Molecular Structure ◽  
Complex Formation ◽  
Carboxylic Acids ◽  
Formation Constants ◽  
Ion Selective Electrode ◽  
Selective Electrode ◽  
Complex Formation Constants ◽  
Calcium Complexation ◽  
C Nmr

The aim of this work was to compare calcium sequestering behaviour of 11 carboxylic acids derived from carbohydrates, and to study the influence of molecular structure on the calcium complexation. For this purpose, various carboxylic acids derived from methyl D-glucopyranoside, methyl D-fructopyranoside, and methyl D-fructofuranoside were synthesized and studied using an ion selective electrode to determine calcium complex formation constants. Complexation sites of carbohydrate skeletons were determined using 13C NMR. Keywords: Ca(II) complexation, carboxylic acids, fructofuranosides, fructopyranosides, glucopyranosides.

Modified Method for the Determination of Mycotoxins in Cocoa Beans

1973 ◽  
Vol 56 (4) ◽  
pp. 1028-1030 ◽  
Author(s):  
Peter M Scott
Keyword(s):  
Silver Nitrate ◽  
Ochratoxin A ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Solvent Mixture ◽  
Cocoa Beans ◽  
Extraction Solvent ◽  
Modified Method

Abstract Method 26.026–26.030 was modified for the analysis of cocoa beans for aflatoxins by inclusion of 3% silver nitrate solution in the extraction solvent mixture. Recoveries of aflatoxins and ochratoxin A added at levels of 5–45 and 20–300 μg/kg, respectively, were satisfactory.

129. The Chlorine Content of Milk as an Indication of Mastitis

1936 ◽  
Vol 7 (1) ◽  
pp. 47-54 ◽  
Author(s):  
J. W. Blood ◽  
A. Rowlands
Keyword(s):  
Silver Nitrate ◽  
Rapid Method ◽  
Nitrate Solution ◽  
Silver Nitrate Solution ◽  
Chlorine Content ◽  
Careful Examination ◽  
Simple Test ◽  
End Point ◽  
Direct Titration

1. The importance of a rapid and simple test for the diagnosis of mastitis in cows is a question which has attracted considerable attention on the part of many workers. One such test based on the determination of chlorine in milk by a rapid method has been advocated recently by Rosell.2. The authors of this paper have made a careful examination of this method and compared the results obtained on samples of milk with those given by other methods known to yield reliable and reasonably accurate results.3. The direct titration of chlorine in milk with silver nitrate solution, without the removal of proteins, invariably gives high results, and, moreover, a satisfactory end-point is difficult to obtain.

Volumetric determination of cobalt in Co-Sm-Fe alloys using a silver ion selective electrode in aqueous dimethylformamide and in water

1979 ◽  
Vol 44 (6) ◽  
pp. 1742-1746 ◽  
Author(s):  
Adam Košturiak ◽  
Dagmar Kalavská
Keyword(s):  
Aqueous Solution ◽  
Silver Nitrate ◽  
Silver Ion ◽  
Ion Selective Electrode ◽  
Selective Electrode ◽  
Back Titration ◽  
Volumetric Determination ◽  
Excess Sodium ◽  
Fe Alloys

A procedure is suggested for direct volumetric determination of cobalt with a sodium diethyldithiocarbaminate titrant solution in the medium of 80% dimethylformamide, using indication with a silver ion selective electrode. The procedure was applied to the cobalt determination in Co-Sm-Fe alloys. The method was adapted for the determination of cobalt in aqueous solution by back titration of excess sodium diethyldithiocarbaminate with a silver nitrate titrant solution or with generated Ag(I), using the same indication or biamperometric indication.

The Volumetric Determination of Free Sulfur

1933 ◽  
Vol 6 (3) ◽  
pp. 412-413 ◽  
Author(s):  
A. Castiglioni
Keyword(s):  
Silver Nitrate ◽  
Nitrate Solution ◽  
Potassium Cyanide ◽  
Silver Nitrate Solution ◽  
Potassium Thiocyanate ◽  
Acetone Extract ◽  
Red Color ◽  
Volumetric Determination ◽  
Free Sulfur

Abstract In order to determine free sulfur in substances like rubber and antimony sulfide, extraction is carried out with a solvent, preferably acetone. After separation from the solvent, the extracted sulfur is converted into the sulfate and weighed as barium sulfate. With the object of making this determination, easier and simpler, it occurred to the author to determine the sulfur in the acetone extract volumetrically, instead of gravimetrically, by utilizing the observed fact that potassium thiocyanate is formed when the acetone extract is boiled with potassium cyanide. Experimental investigation of this subject showed that in the presence of an excess of potassium cyanide, conversion of the sulfur into potassium thiocyanate is quantitative, so that after evaporation of the solvent a mixture of potassium cyanide and potassium thiocyanate remains behind. To determine the potassium thiocyanate in the aqueous solution of these two salts, the method of Schulek (cf. Z. anal. Chem., 65, 433 (1924–25)) was used, which is based on the decomposition of potassium cyanide by formaldehyde. Instead, however, of adding an excess of titrated silver nitrate solution, as recommended by Schulek, and then determining the excess silver by the Volhard method, the titration was carried out directly with the silver nitrate solution, using iron nitrate as indicator, until the blood-red color of ferric thiocyanate had disappeared. In the following table are given the results of determinations by this procedure.

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