Host Polytypism and Structural Modulation in Two-Dimensional Fe(NCS)2-Based Metal–Organic Frameworks: Can Spin-Crossover Transitions Be Predicted?

2019 ◽  
Vol 20 (1) ◽  
pp. 422-433
Author(s):  
Noelia De La Pinta ◽  
Paul Benjamin Klar ◽  
Tomasz Breczewski ◽  
Gotzon Madariaga
Keyword(s):  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
Metal Organic ◽  
Structural Modulation

Nanoporosity, Inclusion Chemistry, and Spin Crossover in Orthogonally Interlocked Two-Dimensional Metal-Organic Frameworks

2015 ◽  
Vol 21 (34) ◽  
pp. 12112-12120 ◽  
Author(s):  
Tania Romero-Morcillo ◽  
Noelia De la Pinta ◽  
Lorena M. Callejo ◽  
Lucía Piñeiro-López ◽  
M. Carmen Muñoz ◽  
...  
Keyword(s):  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
Metal Organic ◽  
Inclusion Chemistry

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

A small molecular, a big scissoring effect: sodium dodecyl sulfate working on two-dimensional metal organic frameworks

CrystEngComm ◽  
2021 ◽  
Author(s):  
Qing Luo ◽  
Zhen Ding ◽  
Huamin Sun ◽  
Zhen Cheng ◽  
Naien SHI ◽  
...  
Keyword(s):  
Sodium Dodecyl Sulfate ◽  
Active Sites ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Sodium Dodecyl ◽  
Advanced Materials ◽  
Controlled Synthesis ◽  
Two Dimensional ◽  
Dodecyl Sulfate ◽  
Metal Organic

Ultrathin two-dimensional (2D) metal-organic framework (MOF) nanosheets are prosperous advanced materials due to their particularly thin thickness and exposed active sites. The difficulty in the controlled synthesis of 2D MOF...

Metal-Organic Framework Transistors for Dopamine Sensing

2021 ◽  
Author(s):  
Jiajun Song ◽  
Jianzhong Zheng ◽  
Anneng Yang ◽  
Hong Liu ◽  
Zeyu Zhao ◽  
...  
Keyword(s):  
Charge Transport ◽  
Transport Properties ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
High Porosity ◽  
Two Dimensional ◽  
Metal Organic ◽  
Organic Framework

Two-dimensional (2D) conductive metal-organic frameworks (MOFs) can not only inherit the high porosity and tailorability of traditional MOFs but also exhibit unique charge transport properties, offering promising opportunities for applications...

Spin-Crossover Behavior in Cyanide-Bridged Iron(II)−Copper(I) Bimetallic 1−3D Metal−Organic Frameworks

2009 ◽  
Vol 48 (8) ◽  
pp. 3371-3381 ◽  
Author(s):  
Gloria Agustí ◽  
M. Carmen Muñoz ◽  
Ana B. Gaspar ◽  
José A. Real
Keyword(s):  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crossover Behavior ◽  
Metal Organic
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