scholarly journals Atmosphere-Induced Transient Structural Transformations of Pd–Cu and Pt–Cu Alloy Nanocrystals

Author(s):  
Lea Pasquale ◽  
Sharif Najafishirtari ◽  
Rosaria Brescia ◽  
Alice Scarpellini ◽  
Cansunur Demirci ◽  
...  
2017 ◽  
Vol 97 ◽  
pp. 115-121 ◽  
Author(s):  
Wenjuan Zhu ◽  
Chao Wang ◽  
Xiaojian Li ◽  
Malik Saddam Khan ◽  
Xu Sun ◽  
...  

NANO ◽  
2019 ◽  
Vol 14 (06) ◽  
pp. 1950069
Author(s):  
Yunong Zhou ◽  
Chao Hu ◽  
Weidong Zhang ◽  
Hong Chen ◽  
Gang Yu

The ability to control the shape, structure and faceting characteristics of bimetallic alloy nanocrystals (NCs) has been vital for designing a catalyst with excellent activity and durability in fuel cells. However, it has remained a significant challenge to synthesize platinum–copper (Pt–Cu) alloy NCs with controlled structure and exposed facets. Herein, Pt–Cu alloy NCs with different shapes, structures and facets were synthesized via a one-step direct chemical co-reduction method employing various glucose concentrations. The results showed that the prepared Pt–Cu alloy NCs exhibited very interesting facet-dependent electrocatalytic properties for ethylene glycol oxidation. In comparison with other prepared Pt–Cu alloy NCs and commercial Pt/C, Pt–Cu alloy NPs with (111)-dominant facets showed higher electrocatalytic activity and durability for ethylene glycol oxidation. Alloy NPs showing prominent electrocatalytic performance were attributed to the predominant (111) facets on NP surfaces serving as catalytic active sites, in addition to added Cu providing unique electronic and synergistic effects. The present work highlighted that these NPs with (111)-dominant facets were indeed promising candidates as electrocatalysts with excellent activity and superior durability.


2015 ◽  
Vol 60 (11) ◽  
pp. 1002-1008 ◽  
Author(s):  
Yanyan Jia ◽  
Zhenming Cao ◽  
Qiaoli Chen ◽  
Yaqi Jiang ◽  
Zhaoxiong Xie ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (23) ◽  
pp. 18153-18158 ◽  
Author(s):  
Yanyan Jia ◽  
Jingyun Su ◽  
Zhibin Chen ◽  
Kai Tan ◽  
Qiaoli Chen ◽  
...  

Octahedral Pt–Cu alloy nanocrystals with tunable composition from PtCu to PtCu3 was successfully synthesized via UPD-like process.


Small ◽  
2013 ◽  
Vol 9 (18) ◽  
pp. 3063-3069 ◽  
Author(s):  
Zhicheng Zhang ◽  
Yong Yang ◽  
Farhat Nosheen ◽  
Pengpeng Wang ◽  
Jingchao Zhang ◽  
...  

2015 ◽  
Vol 31 (1) ◽  
pp. 91-96 ◽  
Author(s):  
Alexandr M. Glezer ◽  
Nadezhda A. Shurygina ◽  
Elena N. Blinova ◽  
Inga E. Permyakova ◽  
Sergey A. Firstov

ChemNanoMat ◽  
2018 ◽  
Vol 4 (9) ◽  
pp. 909-913 ◽  
Author(s):  
Jing Yang ◽  
Manman Su ◽  
Yanxi Zhao ◽  
Jinlin Li ◽  
Mei Li ◽  
...  

Author(s):  
Shrikant P. Bhat

deformation behavior of Al-Cu alloys aged to contain θ ' has been the subject of many investigations (e.g., Ref. 1-5). Since θ ' is strong and hard, dislocations bypass θ ' plates (Orowan mechanism) at low strains. However, at high strains the partially coherent θ ' plates are probably sheared, although the mechanism is complex, depending on the form of deformation. Particularly, the cyclic straining of the bulk alloy is known to produce gross bends and twists of θ '. However, no detailed investigation of the deformation of θ ' has yet been reported; moreover, Calabrese and Laird interpreted the deformation of θ ' as largely being elastic.During an investigation of high temperature cyclic deformation, the detailed electron-microscopic observation revealed that, under reversed straining conditions, θ ' particles are severely distorted--bent and twisted depending on the local matrix constraint. A typical electronmicrograph, showing the twist is shown in Fig. 1. In order to establish whether the deformation is elastic or plastic, a sample from a specimen cycled at room temperature was heated inside the microscope and the results are presented in a series of micrographs (Fig. 2a-e).


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