Rheological Properties of Water-in-Brazilian Crude Oil Emulsions: Effect of Water Content, Salinity, and pH

2018 ◽  
Vol 32 (8) ◽  
pp. 8880-8890 ◽  
Author(s):  
Cesar B. Z. de Oliveira ◽  
W. J. Souza ◽  
C. F. Santana ◽  
C. C. Santana ◽  
C. Dariva ◽  
...  
Author(s):  
Abed Saad ◽  
Nour Abdurahman ◽  
Rosli Mohd Yunus

: In this study, the Sany-glass test was used to evaluate the performance of a new surfactant prepared from corn oil as a demulsifier for crude oil emulsions. Central composite design (CCD), based on the response surface methodology (RSM), was used to investigate the effect of four variables, including demulsifier dosage, water content, temperature, and pH, on the efficiency of water removal from the emulsion. As well, analysis of variance was applied to examine the precision of the CCD mathematical model. The results indicate that demulsifier dose and emulsion pH are two significant parameters determining demulsification. The maximum separation efficiency of 96% was attained at an alkaline pH and with 3500 ppm demulsifier. According to the RSM analysis, the optimal values for the input variables are 40% water content, 3500 ppm demulsifier, 60 °C, and pH 8.


2007 ◽  
Vol 21 (2) ◽  
pp. 1014-1018 ◽  
Author(s):  
Naoya Shigemoto ◽  
Rashid S. Al-Maamari ◽  
Baba Y. Jibril ◽  
Akihiko Hirayama ◽  
Mark Sueyoshi

2015 ◽  
Vol 32 (2) ◽  
pp. 455-464 ◽  
Author(s):  
W. J. Souza ◽  
K. M. C. Santos ◽  
A. A. Cruz ◽  
E. Franceschi ◽  
C. Dariva ◽  
...  

2013 ◽  
Vol 10 (4) ◽  
pp. 506-509 ◽  
Author(s):  
Wu-Jun Jin ◽  
Kun Zhao ◽  
Chen Yang ◽  
Chang-Hong Xu ◽  
Hao Ni ◽  
...  

Author(s):  
Zhanna Nadirova ◽  
Oleksandr Ivakhnenko ◽  
Manap Zhantasov ◽  
Gulmira Bimbetova ◽  
Kazim Nadirov

Reducing the water content of crude oil is a necessary step in preparing oil for transportation and processing. This task is complicated by the presence of stable water-in-oil emulsions. The most widely used approach to oil demulsification is exploring chemical demulsifiers. However, the high cost and impossibility of regenerating the latter require the search for new ways to destroy water-oil emulsions. One of the promising areas is the use of ultrasound. This paper presents the results of studies on the ultrasonic treatment of four samples of emulsions with different water content (8.74; 15; 25 and 30 vol.%) based on oil from the Kumkol oilfield (Kazakhstan). Samples of emulsions were subjected to ultrasonic action at a frequency of 40 kHz for 5-60 min at a temperature of 70±1°C, followed by settling for 40 min at the indicated temperature. The influence of the initial water content in the emulsion, the acoustic intensity, as well as the duration of ultrasonic treatment on the dewatering ratio was investigated. It was found that the residual water content in the oil was 5.04- 7.82 vol.%. Ultrasonic treatment of crude oil from the Kumkol oilfield can be used for preliminary dewatering, to subsequently reduce the consumption of chemical demulsifiers.


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