Synthesis of Secondary Amines from One-Pot Reductive Amination with Formic Acid as the Hydrogen Donor over an Acid-Resistant Cobalt Catalyst

2017 ◽  
Vol 56 (44) ◽  
pp. 12556-12565 ◽  
Author(s):  
Liang Jiang ◽  
Peng Zhou ◽  
Zehui Zhang ◽  
Shiwei Jin ◽  
Quan Chi
Keyword(s):  
Formic Acid ◽  
Cobalt Catalyst ◽  
Reductive Amination ◽  
Hydrogen Donor ◽  
Secondary Amines ◽  
One Pot

One-pot reductive amination of aldehydes with nitroarenes using formic acid as the hydrogen donor and mesoporous graphitic carbon nitride supported AgPd alloy nanoparticles as the heterogeneous catalyst

2018 ◽  
Vol 42 (12) ◽  
pp. 10000-10006 ◽  
Author(s):  
Seda Ergen ◽  
Bilal Nişancı ◽  
Önder Metin
Keyword(s):  
Formic Acid ◽  
Heterogeneous Catalyst ◽  
Carbon Nitride ◽  
Reductive Amination ◽  
Graphitic Carbon ◽  
Hydrogen Donor ◽  
Graphitic Carbon Nitride ◽  
Secondary Amines ◽  
Alloy Nanoparticles ◽  
One Pot

A facile one-pot protocol has been developed for the synthesis of secondary amines via a tandem reductive amination of aldehydes with nitroaromatics.

One-pot reductive amination of carbonyl compounds with nitro compounds with CO/H2O as the hydrogen donor over non-noble cobalt catalyst

2017 ◽  
Vol 352 ◽  
pp. 264-273 ◽  
Author(s):  
Peng Zhou ◽  
Changlin Yu ◽  
Liang Jiang ◽  
Kangle Lv ◽  
Zehui Zhang
Keyword(s):  
Carbonyl Compounds ◽  
Cobalt Catalyst ◽  
Reductive Amination ◽  
Nitro Compounds ◽  
Hydrogen Donor ◽  
One Pot

scholarly journals Correction: One-pot reductive amination of aldehydes with nitroarenes using formic acid as the hydrogen donor and mesoporous graphitic carbon nitride supported AgPd alloy nanoparticles as the heterogeneous catalyst

2021 ◽  
Author(s):  
Seda Ergen ◽  
Bilal Nişancı ◽  
Önder Metin
Keyword(s):  
Formic Acid ◽  
Heterogeneous Catalyst ◽  
Carbon Nitride ◽  
Reductive Amination ◽  
Graphitic Carbon ◽  
Hydrogen Donor ◽  
Graphitic Carbon Nitride ◽  
Alloy Nanoparticles ◽  
One Pot

Correction for ‘One-pot reductive amination of aldehydes with nitroarenes using formic acid as the hydrogen donor and mesoporous graphitic carbon nitride supported AgPd alloy nanoparticles as the heterogeneous catalyst’ by Seda Ergen et al., New J. Chem., 2018, 42, 10000–10006, DOI: 10.1039/C8NJ01569D

Cobalt encapsulated in N‑doped graphene sheet for one-pot reductive amination to synthesize secondary amines

2021 ◽  
Vol 505 ◽  
pp. 111504
Author(s):  
Lin Liu ◽  
Wenxiu Li ◽  
Ran Qi ◽  
Qingqing Zhu ◽  
Jing Li ◽  
...  
Keyword(s):  
Graphene Sheet ◽  
Reductive Amination ◽  
Secondary Amines ◽  
One Pot ◽  
Doped Graphene

scholarly journals Facile Synthesis of COF-Supported Reduced Pd-Based Catalyst for One-Pot Reductive Amination of Aldehydes

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 287
Author(s):  
Jianguo Liu ◽  
Mingyue Zhang ◽  
Longlong Ma
Keyword(s):  
Heterogeneous Catalysts ◽  
Reductive Amination ◽  
Secondary Amines ◽  
Metallic State ◽  
One Pot ◽  
Effective Synthesis ◽  
Pharmaceutical Industries ◽  
The One ◽  
Heterocyclic Aldehydes ◽  
Supported Pd

Dibenzylamine motifs are an important class of crucial organic compounds and are widely used in fine chemical and pharmaceutical industries. The development of the efficient, economical, and environmentally friendly synthesis of amines using transition metal-based heterogeneous catalysts remains both desirable and challenging. Herein, we prepared the covalent organic framework (COF)-supported heterogeneous reduced COF-supported Pd-based catalyst and used it for the one-pot reductive amination of aldehydes. There are both Pd metallic state and oxidated Pdσ+ in the catalysts. Furthermore, in the presence of the reduced COF-supported Pd-based catalyst, many aromatic, aliphatic, and heterocyclic aldehydes with various functional groups substituted were converted to their corresponding amines products in good to excellent selectivity (up to 91%) under mild reaction conditions (70 °C, 2 h, NH3, 20 bar H2). This work expands the covalent organic frameworks for the material family and its support catalyst, opening up new catalytic applications in the economical, practical, and effective synthesis of secondary amines.

Practical One-Pot Synthesis of Secondary Amines by Zinc-Catalyzed Reductive Amination

2010 ◽  
Vol 141 (1) ◽  
pp. 55-61 ◽  
Author(s):  
Stephan Enthaler
Keyword(s):  
Reductive Amination ◽  
Secondary Amines ◽  
One Pot ◽  
One Pot Synthesis

Direct reductive amination of aldehydes using lithium-arene(cat.) as reducing system. A simple one-pot procedure for the synthesis of secondary amines

2012 ◽  
Vol 53 (25) ◽  
pp. 3156-3160 ◽  
Author(s):  
Fabiana Nador ◽  
Yanina Moglie ◽  
Andrés Ciolino ◽  
Adriana Pierini ◽  
Viviana Dorn ◽  
...  
Keyword(s):  
Reductive Amination ◽  
Secondary Amines ◽  
One Pot ◽  
System A

Intermetallic Ni2Si/SiCN as a highly efficient catalyst for the one-pot tandem synthesis of imines and secondary amines

2020 ◽  
Vol 7 (1) ◽  
pp. 82-90 ◽  
Author(s):  
Xiao Chen ◽  
Shuhua Han ◽  
Dongdong Yin ◽  
Changhai Liang
Keyword(s):  
High Activity ◽  
Aromatic Amine ◽  
Reductive Amination ◽  
High Selectivity ◽  
Secondary Amines ◽  
One Pot ◽  
Efficient Catalyst ◽  
Highly Efficient ◽  
The One ◽  
Tandem Synthesis

For the one-pot reductive amination of benzaldehyde with nitrobenzene, intermetallic Ni2Si/SiCN from the decomposition of a nickel-modified polysilazane precursor exhibited high activity (>99%) and high selectivity (92% to aromatic amine).

One-pot, chemoselective synthesis of secondary amines from aryl nitriles using a PdPt–Fe3O4 nanoparticle catalyst

2020 ◽  
Vol 10 (13) ◽  
pp. 4201-4209
Author(s):  
Jin Hee Cho ◽  
Sangmoon Byun ◽  
Ahra Cho ◽  
B. Moon Kim
Keyword(s):  
Reductive Amination ◽  
Secondary Amines ◽  
Fe3o4 Nanoparticle ◽  
Catalytic Method ◽  
One Pot ◽  
Chemoselective Synthesis ◽  
Aryl Nitriles ◽  
The One ◽  
Nanoparticle Catalyst

We have developed a new catalytic method for the one-pot, cascade synthesis of unsymmetrical secondary amines via the reductive amination of aryl nitriles with nitroalkanes using a PdPt–Fe3O4 nanoparticle (NP) catalyst.

ChemInform Abstract: Direct Reductive Amination of Aldehydes Using Lithium-Arene (cat.) as Reducing System: A Simple One-Pot Procedure for the Synthesis of Secondary Amines.

ChemInform ◽  
2012 ◽  
Vol 43 (40) ◽  
pp. no-no
Author(s):  
Fabiana Nador ◽  
Yanina Moglie ◽  
Andres Ciolino ◽  
Adriana Pierini ◽  
Viviana Dorn ◽  
...  
Keyword(s):  
Reductive Amination ◽  
Secondary Amines ◽  
One Pot ◽  
System A
Sign in / Sign up

Export Citation Format

Share Document