Controllable Preparation and Catalytic Performance of Magnetic Fe3O4@CeO2-Polysulfone Nanocomposites with Core–Shell Structure

2018 ◽  
Vol 57 (44) ◽  
pp. 15039-15045 ◽  
Author(s):  
Juan Wei ◽  
Hongbao Yao ◽  
Yujun Wang ◽  
Guangsheng Luo
2014 ◽  
Vol 953-954 ◽  
pp. 1297-1302
Author(s):  
Guang Ying Wang ◽  
Li Fang ◽  
Fei Fei Li ◽  
Surin Saipanya

A core-shell structure RuRh@Pt/C nanoparticles was prepared by using a two-step reduction method under ultrasonic promotion. The catalytic performance was tested in methanol electrooxidation. X-ray diffraction (XRD), scanning electron microscope (SEM) combined with cyclic voltammetry (CV) were used to characterize the obtained catalyst. The results showed that there was no alloy formed between the core RuRh and the shell Pt. The electrocatalytic activity of RuRh@Pt/C varied with the Ru/Rh ratio in the bimetallic core, among which the catalyst with the Ru/Rh ratio 1:2 and the Pt-shell thickness of 1.5 ([email protected]/C) showed the highest catalytic activity for methanol. With this catalyst, the current density of the oxidation peak for methanol electro-oxidation reached 2.3 times as that of Pt1.5/C while the corresponding peak potential shifted 60 mV negatively in comparing to that of Pt1.5/C. In addition, the catalyst with the core-shell structure of RuRh@Pt/C possessed much higher CO-tolerance for methanol electro-oxidation, indicating its promising application in low temperature fuel cell.


RSC Advances ◽  
2021 ◽  
Vol 11 (60) ◽  
pp. 37708-37712
Author(s):  
Wenyan Li ◽  
Xinying Lin ◽  
Jing Long ◽  
Bo Zheng ◽  
Zhaorui Pan ◽  
...  

Mesoporous core–shell structure Ag@SiO2 nanospheres are constructed to prevent Ag nanoparticles from aggregation during the hydrogenation reaction.


Nanoscale ◽  
2020 ◽  
Vol 12 (30) ◽  
pp. 16366-16380 ◽  
Author(s):  
Xiaosheng Huang ◽  
Fang Dong ◽  
Guodong Zhang ◽  
Zhicheng Tang

Tungsten anchoring Cu3(VO4)2@CeO2 nanorods with a core–shell structure exhibited satisfactory NH3-SCR catalytic performance.


2018 ◽  
Vol 33 (2) ◽  
pp. e4708 ◽  
Author(s):  
Mingliang Ma ◽  
Yuying Yang ◽  
Dili Liao ◽  
Ping Lyu ◽  
Jinwei Zhang ◽  
...  

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