scholarly journals Iron(III)–Oxo Cluster Chemistry with Dimethylarsinate Ligands: Structures, Magnetic Properties, and Computational Studies

2020 ◽  
Vol 59 (24) ◽  
pp. 18090-18101
Author(s):  
Kenneth Hong Kit Lee ◽  
Juan E. Peralta ◽  
Khalil A. Abboud ◽  
George Christou
Keyword(s):  
Magnetic Properties ◽  
Computational Studies ◽  
Cluster Chemistry

Synthesis, structure, computational studies and magnetic properties of a ten-coordinate gadolinium(III) complex

1997 ◽  
Vol 258 (2) ◽  
pp. 127-130 ◽  
Author(s):  
Michael T. Benson ◽  
Thomas R. Cundari ◽  
Leah C. Saunders ◽  
Shaun O. Sommerer
Keyword(s):  
Magnetic Properties ◽  
Computational Studies

In search of 3d/4f-metal single-molecule magnets: Nickel(II)/lanthanide(III) coordination clusters

2013 ◽  
Vol 85 (2) ◽  
pp. 315-327 ◽  
Author(s):  
Christina D. Polyzou ◽  
Constantinos G. Efthymiou ◽  
Albert Escuer ◽  
Luís Cunha-Silva ◽  
Constantina Papatriantafyllopoulou ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Metal Complexes ◽  
Single Molecule ◽  
Metal Cluster ◽  
Single Molecule Magnets ◽  
One Pot ◽  
Cluster Chemistry ◽  
Depth Analysis ◽  
Synthetic Utility

The importance of 3d/4f-metal cluster chemistry is outlined, and the employment of 2-pyridyl ketone- and 2-pyridyl oxime-based ligands for the preparation of low-nuclearity NiII/LnIII complexes (Ln = lanthanide) is reviewed. The synthetic utility of the “metal complexes as ligands” and “one-pot” approaches is critically discussed. The small nuclearity of the products permits the in-depth analysis of their magnetic properties.

Computational Studies on the Mo-Doped Gold Nanoclusters Au n Mo(n = 1–10): Structures, Stabilities and Magnetic Properties

2015 ◽  
Vol 27 (3) ◽  
pp. 993-1004 ◽  
Author(s):  
Jia Cao ◽  
Qi Li ◽  
Zhi Xiang Wang ◽  
Lou Jun Gao ◽  
Feng Fu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Gold Nanoclusters ◽  
Computational Studies

Polyalcohol ligand in CuII and FeIII cluster chemistry: Synthesis, structures and magnetic properties of {Cu12} and {Fe8} aggregates

2011 ◽  
Vol 375 (1) ◽  
pp. 187-192 ◽  
Author(s):  
Po-Heng Lin ◽  
Sarah Eastman ◽  
Aman Bhatti ◽  
Melanie Brulotte ◽  
Tara J. Burchell ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Cluster Chemistry

Solution behavior and magnetic properties of a novel nonanuclear copper(ii) cluster

2018 ◽  
Vol 42 (22) ◽  
pp. 17884-17888 ◽  
Author(s):  
Bao-Qian Ji ◽  
Marko Jagodič ◽  
Hui-Yan Ma ◽  
Hai-Feng Su ◽  
Yun-Wu Li ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Solution Behavior ◽  
Cluster Chemistry ◽  
Esi Ms ◽  
Assembly Mechanism ◽  
First Time ◽  
Solution Behaviour

A {Cu9} nanocluster was constructed from a new multidentate pyrazole–alcohol ligand and various small sterically-hindering anions. The ESI-MS was for the first time applied to Cu cluster chemistry to detect the solution behaviour and possible assembly mechanism of the {Cu9} cluster. The cluster also exhibited antiferromagnetic behaviour.

AEM analysis of crystallization in Ti-based amorphous alloys

1983 ◽  
Vol 41 ◽  
pp. 270-271
Author(s):  
A.R. Pelton ◽  
A.F. Marshall ◽  
Y.S. Lee
Keyword(s):  
Magnetic Properties ◽  
Amorphous Alloys ◽  
Amorphous Materials ◽  
Isothermal Annealing ◽  
Amorphous Matrix ◽  
Nucleation And Growth ◽  
Current Interest ◽  
Amorphous Films ◽  
Electrical And Magnetic Properties

Amorphous materials are of current interest due to their desirable mechanical, electrical and magnetic properties. Furthermore, crystallizing amorphous alloys provides an avenue for discerning sequential and competitive phases thus allowing access to otherwise inaccessible crystalline structures. Previous studies have shown the benefits of using AEM to determine crystal structures and compositions of partially crystallized alloys. The present paper will discuss the AEM characterization of crystallized Cu-Ti and Ni-Ti amorphous films.Cu60Ti40: The amorphous alloy Cu60Ti40, when continuously heated, forms a simple intermediate, macrocrystalline phase which then transforms to the ordered, equilibrium Cu3Ti2 phase. However, contrary to what one would expect from kinetic considerations, isothermal annealing below the isochronal crystallization temperature results in direct nucleation and growth of Cu3Ti2 from the amorphous matrix.

Microstructure in soft magnetic E3 (S1, Al) (Sendust) alloys

1988 ◽  
Vol 46 ◽  
pp. 770-771
Author(s):  
June D. Kim
Keyword(s):  
Electron Microscopy ◽  
Magnetic Properties ◽  
Ternary Phase Diagram ◽  
Vertical Tube ◽  
Vacuum Induction Melting ◽  
Induction Melting ◽  
Soft Magnetic ◽  
Quenching Temperature ◽  
Thin Foils ◽  
Vertical Tube Furnace

Iron-base alloys containing 8-11 wt.% Si, 4-8 wt.% Al, known as “Sendust” alloys, show excellent soft magnetic properties. These magnetic properties are strongly dependent on heat treatment conditions, especially on the quenching temperature following annealing. But little has been known about the microstructure and the Fe-Si-Al ternary phase diagram has not been established. In the present investigation, transmission electron microscopy (TEM) has been used to study the microstructure in a Sendust alloy as a function of temperature.An Fe-9.34 wt.% Si-5.34 wt.% Al (approximately Fe3Si0.6Al0.4) alloy was prepared by vacuum induction melting, and homogenized at 1,200°C for 5 hrs. Specimens were heat-treated in a vertical tube furnace in air, and the temperature was controlled to an accuracy of ±2°C. Thin foils for TEM observation were prepared by jet polishing using a mixture of perchloric acid 15% and acetic acid 85% at 10V and ∼13°C. Electron microscopy was performed using a Philips EM 301 microscope.

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