Bridging Polyoxometalate-Based Mn4 Cubane Clusters with Inorganic Phosphates: Structural Transformation and Magnetic Properties

2020 ◽  
Vol 60 (1) ◽  
pp. 219-224
Author(s):  
Zhiwei Liu ◽  
Qing Chang ◽  
Weijie Wu ◽  
Weiye Yin ◽  
Yongle Chu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Structural Transformation ◽  
Inorganic Phosphates ◽  
Cubane Clusters

Effect of La/Cr codoping on structural transformation, leakage, dielectric and magnetic properties of BiFeO3 ceramics

2017 ◽  
Vol 52 (12) ◽  
pp. 7118-7129 ◽  
Author(s):  
Fangting Lin ◽  
Qiqi Yu ◽  
Linyan Deng ◽  
Zhengjian Zhang ◽  
Xiaoyong He ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Structural Transformation

Holmium induced structural transformation and improved dielectric and magnetic properties in Bi0.80La0.20FeO3 multiferroics

2019 ◽  
Vol 487 ◽  
pp. 165337 ◽  
Author(s):  
Jogender Singh ◽  
Ashish Agarwal ◽  
Sujata Sanghi ◽  
Tanvi Bhasin ◽  
Manisha Yadav ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Structural Transformation

scholarly journals Modification of Structure and Magnetic Properties in Coordination Assemblies Based on [Cu(cyclam)]2+ and [W(CN)8]3−

Crystals ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 45 ◽  
Author(s):  
Aleksandra Pacanowska ◽  
Mateusz Reczyński ◽  
Beata Nowicka
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Structural Transformation ◽  
Water Solution ◽  
Building Blocks ◽  
Alcohol Solution ◽  
Slow Diffusion ◽  
Crystal Structural ◽  
Water Alcohol

The 1D {[CuII(cyclam)]3[WV(CN)8]2.5H2O}n (1·5H2O) (cyclam = 1,4,8,11-tetraazacyclotetradecane) coordination polymer of ladder topology can be obtained in water-alcohol solution from [Cu(cyclam)]2+ and [W(CN)8]3− building blocks. Upon dehydration, 1·5H2O undergoes a single-crystal-to-single-crystal structural transformation to the anhydrous {[CuII(cyclam)]3[WV(CN)8]2}n (1) form, which retains the same topology, but is characterized by shorter Cu-W distances and significantly more bent CN-bridges. The deformation of the coordination skeleton is reflected in magnetic properties: the predominant intra-chain interactions change from ferromagnetic in 1·5H2O to antiferromagnetic in 1. The reaction between the same building blocks in water solution under slow diffusion conditions leads to the formation of a 0D {[CuII(cyclam)(H2O)]2[CuII(cyclam)][WV(CN)8]2}.3H2O pentanuclear assembly (2·3H2O).

scholarly journals Effect of Coordination Geometry on Magnetic Properties in a Series of Cobalt(II) Complexes and Structural Transformation in Mother Liquor

2020 ◽  
Vol 59 (10) ◽  
pp. 7067-7081 ◽  
Author(s):  
Subrata Ghosh ◽  
Sujit Kamilya ◽  
Mayurika Das ◽  
Sakshi Mehta ◽  
Marie-Emmanuelle Boulon ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Structural Transformation ◽  
Mother Liquor ◽  
Coordination Geometry

Syntheses, structures, and magnetic properties of two unique Cu(ii)-based coordination polymers involving a crystal-to-crystal structural transformation from a 1D chain to a 3D network

2017 ◽  
Vol 46 (48) ◽  
pp. 17025-17031 ◽  
Author(s):  
Xu-Feng Yang ◽  
Min Liu ◽  
Hai-Bin Zhu ◽  
Cheng Hang ◽  
Yue Zhao
Keyword(s):  
Magnetic Properties ◽  
Structural Transformation ◽  
Coordination Polymers ◽  
Network Structure ◽  
Chain Structure ◽  
3D Network ◽  
1D Chain ◽  
Crystal Structural

Promoted by the DMF solvent, the 1D chain structure of 1 can be irreversibly transformed into the 3D sod network structure of 2 in a crystal-to-crystal fashion, which is accompanied by a drastic magnetic change.

Solvent-induced single-crystal-to-single-crystal transformation and tunable magnetic properties of 1D azido-Cu(ii) chains with a carboxylate bridge

2019 ◽  
Vol 48 (30) ◽  
pp. 11268-11277 ◽  
Author(s):  
Xiangyu Liu ◽  
Xiufang Ma ◽  
Jinhui Yang ◽  
Shuchang Luo ◽  
Zheng Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Solvent Effect ◽  
Structural Transformation ◽  
Coordination Polymers ◽  
Crystal Transformation ◽  
Carboxylate Bridge ◽  
Copper Coordination

The solvent effect leads to structural transformation and tunable magnetism of chain-like azido-copper coordination polymers.

Sign in / Sign up

Export Citation Format

Share Document