Luminescent Two-Dimensional Metal–Organic Framework Nanosheets with Large π-Conjugated System: Design, Synthesis, and Detection of Anti-Inflammatory Drugs and Pesticides

Author(s):  
Cai-Xia Yu ◽  
Wen Jiang ◽  
Ke-Zhong Wang ◽  
Ai-Ping Liang ◽  
Jian-Guo Song ◽  
...  
2020 ◽  
Vol 1136 ◽  
pp. 157-167
Author(s):  
Gabriela Peña-Velasco ◽  
Laura Hinojosa-Reyes ◽  
Maricela Escamilla-Coronado ◽  
Gemma Turnes-Palomino ◽  
Carlos Palomino-Cabello ◽  
...  

2019 ◽  
Vol 58 (5) ◽  
pp. 3145-3155 ◽  
Author(s):  
Tong Yan ◽  
Jie Zhou ◽  
Rong-Rong Zhu ◽  
Yan-Ru Zhao ◽  
Zhe Xue ◽  
...  

2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.


2017 ◽  
Vol 139 (24) ◽  
pp. 8312-8319 ◽  
Author(s):  
Ming Xu ◽  
Shuai Yuan ◽  
Xin-Yu Chen ◽  
Yu-Jie Chang ◽  
Gregory Day ◽  
...  

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