Metal–Ligand Cooperativity Promoting Sulfur Atom Transfer in Ferrous Complexes and Isolation of a Sulfurmethylenephosphorane Adduct

2018 ◽  
Vol 57 (18) ◽  
pp. 11552-11559 ◽  
Author(s):  
Dieter Sorsche ◽  
Matthias E. Miehlich ◽  
Eva M. Zolnhofer ◽  
Patrick J. Carroll ◽  
Karsten Meyer ◽  
...  
Keyword(s):  
Sulfur Atom ◽  
Atom Transfer ◽  
Metal Ligand

scholarly journals K2S2O8-Promoted Aryl Thioamides Synthesis from Aryl Aldehydes Using Thiourea as the Sulfur Source

Molecules ◽  
2018 ◽  
Vol 23 (9) ◽  
pp. 2225 ◽  
Author(s):  
Yongjun Bian ◽  
Xingyu Qu ◽  
Yongqiang Chen ◽  
Jun Li ◽  
Leng Liu
Keyword(s):  
Transition Metal ◽  
Functional Groups ◽  
Sulfur Atom ◽  
Coupling Reaction ◽  
Sulfur Source ◽  
Atom Transfer ◽  
Free Condition ◽  
Metal Free ◽  
Aryl Aldehydes ◽  
Three Component Coupling

Thiourea as a sulfur atom transfer reagent was applied for the synthesis of aryl thioamides through a three-component coupling reaction with aryl aldehydes and N,N-dimethylformamide (DMF) or N,N-dimethylacetamide (DMAC). The reaction could tolerate various functional groups and gave moderate to good yields of desired products under the transition-metal-free condition.

Computational Study of Sulfur Atom-Transfer Reactions from Thiiranes to ER3(E = As, P; R = CH3, Ph)

2005 ◽  
Vol 44 (23) ◽  
pp. 8426-8432 ◽  
Author(s):  
Abdellatif Ibdah ◽  
James H. Espenson ◽  
William S. Jenks
Keyword(s):  
Sulfur Atom ◽  
Computational Study ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Atom Transfer Reactions
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