Flexible Metal–Organic Frameworks for Light-Switchable CO2 Sorption Using an Auxiliary Ligand Strategy

2019 ◽  
Vol 58 (15) ◽  
pp. 9766-9772 ◽  
Author(s):  
Debobroto Sensharma ◽  
Nianyong Zhu ◽  
Swetanshu Tandon ◽  
Sebastien Vaesen ◽  
Graeme W. Watson ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Auxiliary Ligand ◽  
Co2 Sorption ◽  
Metal Organic ◽  
Flexible Metal

Methane storage in flexible metal–organic frameworks with intrinsic thermal management

Nature ◽  
2015 ◽  
Vol 527 (7578) ◽  
pp. 357-361 ◽  
Author(s):  
Jarad A. Mason ◽  
Julia Oktawiec ◽  
Mercedes K. Taylor ◽  
Matthew R. Hudson ◽  
Julien Rodriguez ◽  
...  
Keyword(s):  
Thermal Management ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic ◽  
Flexible Metal

Intermediate states approach for adsorption studies in flexible metal–organic frameworks

2019 ◽  
Vol 21 (6) ◽  
pp. 3294-3303 ◽  
Author(s):  
Justyna Rogacka ◽  
Filip Formalik ◽  
Azahara L. Triguero ◽  
Lucyna Firlej ◽  
Bogdan Kuchta ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
P Adsorption ◽  
Adsorption Studies ◽  
Intermediate States ◽  
Metal Organic ◽  
Flexible Metal

Adsorption studies in flexible metal–organic frameworks are challenging and time-consuming.

scholarly journals Temperature dependence of adsorption hysteresis in flexible metal organic frameworks

2020 ◽  
Vol 3 (1) ◽  
Author(s):  
Shamsur Rahman ◽  
Arash Arami-Niya ◽  
Xiaoxian Yang ◽  
Gongkui Xiao ◽  
Gang (Kevin) Li ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Capillary Condensation ◽  
Metal Organic Frameworks ◽  
Sorption Isotherms ◽  
Separation Performance ◽  
Process Simulations ◽  
Metal Organic ◽  
Flexible Metal ◽  
Pressure Swing ◽  
External Stimuli

Abstract“Breathing” and “gating” are striking phenomena exhibited by flexible metal-organic frameworks (MOFs) in which their pore structures transform upon external stimuli. These effects are often associated with eminent steps and hysteresis in sorption isotherms. Despite significant mechanistic studies, the accurate description of stepped isotherms and hysteresis remains a barrier to the promised applications of flexible MOFs in molecular sieving, storage and sensing. Here, we investigate the temperature dependence of structural transformations in three flexible MOFs and present a new isotherm model to consistently analyse the transition pressures and step widths. The transition pressure reduces exponentially with decreasing temperature as does the degree of hysteresis (c.f. capillary condensation). The MOF structural transition enthalpies range from +6 to +31 kJ·mol−1 revealing that the adsorption-triggered transition is entropically driven. Pressure swing adsorption process simulations based on flexible MOFs that utilise the model reveal how isotherm hysteresis can affect separation performance.

scholarly journals Amino Acid Residues Determine the Response of Flexible Metal–Organic Frameworks to Guests

2020 ◽  
Vol 142 (35) ◽  
pp. 14903-14913 ◽  
Author(s):  
Yong Yan ◽  
Elliot J. Carrington ◽  
Rémi Pétuya ◽  
George F. S. Whitehead ◽  
Ajay Verma ◽  
...  
Keyword(s):  
Amino Acid ◽  
Metal Organic Frameworks ◽  
Amino Acid Residues ◽  
Metal Organic ◽  
Flexible Metal

Elucidation of flexible metal-organic frameworks: Research progresses and recent developments

2019 ◽  
Vol 389 ◽  
pp. 161-188 ◽  
Author(s):  
Jae Hwa Lee ◽  
Sungeun Jeoung ◽  
Yongchul G. Chung ◽  
Hoi Ri Moon
Keyword(s):  
Metal Organic Frameworks ◽  
Recent Developments ◽  
Metal Organic ◽  
Flexible Metal

Enantioselective Inclusion of Alcohols by Solvent-Controlled Assembled Flexible Metal–Organic Frameworks

2014 ◽  
Vol 53 (10) ◽  
pp. 4794-4796 ◽  
Author(s):  
Lang Lin ◽  
Rongmin Yu ◽  
Xiao-Yuan Wu ◽  
Wen-Bin Yang ◽  
Jian Zhang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Flexible Metal

Flexible metal–organic frameworks as superior cathodes for rechargeable sodium-ion batteries

2015 ◽  
Vol 3 (32) ◽  
pp. 16590-16597 ◽  
Author(s):  
Ping Nie ◽  
Laifa Shen ◽  
Gang Pang ◽  
Yaoyao Zhu ◽  
Guiyin Xu ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Prussian Blue ◽  
Metal Organic Frameworks ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Prussian Blue Analogues ◽  
Ion Storage ◽  
Metal Organic ◽  
Flexible Metal ◽  
Sodium Ion Storage

Flexible metal–organic frameworks composed of Prussian blue analogues on a highly conductive carbonfiber paper have been synthesized and utilized as attractive hosts for sodium ion storage at ambient temperature.

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