We showed that the development of recommendations for a reasonable choice of linear block copolyurethanes that would be optimal for given operating conditions is still intuitive and does not consider the features of the molecular structure and the nature of initial components. We suggested a new scientifically grounded approach to the creation of linear block-copolyurethanes with increased wear resistance in relation to strength, deformation, thermophysical and tribotechnical characteristics. To simplify analysis of the properties of the studied materials, a mathematical model was developed, which describes the relationship between all considered properties of materials and their structure. We proposed to assess the relationship between structure and properties of the investigated materials by using quality indexes. Maximum values of quality indexes, depending on the operating conditions, correspond to different contents of hard blocks (Pc), and, consequently, to different molecular structure of the studied polyurethanes. Thus, it is reasonable to use block-copolyurethanes based on OBGA500 with a maximum content of hard blocks (Рс>60%) for operating conditions where it is necessary to provide high strength characteristics. Polyurethanes synthesized with the formation of clusters of hard blocks in the range of 45–55% are recommended for the use as wear-resistant materials.
Structural studies of sodium and potassium ion-activated adenosine triphosphatase. The relationship between molecular structure and the mechanism of active transport.
