In Situ-Generated Halogen-Bonding Complex Enables Atom Transfer Radical Addition (ATRA) Reactions of Olefins

2020 ◽  
Vol 85 (16) ◽  
pp. 10574-10583 ◽  
Author(s):  
Kazuki Matsuo ◽  
Eiji Yamaguchi ◽  
Akichika Itoh
Keyword(s):  
Halogen Bonding ◽  
Radical Addition ◽  
Atom Transfer ◽  
Atom Transfer Radical Addition

Atom-transfer radical addition of fluoroalkyl bromides to alkenes via a photoredox/copper catalytic system

2021 ◽  
Author(s):  
Vladislav S. Kostromitin ◽  
Artem A. Zemtsov ◽  
Vladimir A. Kokorekin ◽  
Vitalij V. Levin ◽  
Alexander D. Dilman
Keyword(s):  
Catalytic System ◽  
Radical Addition ◽  
Atom Transfer ◽  
Alkyl Bromides ◽  
System P ◽  
Atom Transfer Radical Addition

A method for the addition of fluorinated alkyl bromides to alkenes is described.

ChemInform Abstract: Regioisomerized Atom Transfer Radical Addition (ATRA) of Olefins with Dichlorofluorocarbons.

ChemInform ◽  
2016 ◽  
Vol 47 (16) ◽  
Author(s):  
Bo Zhao ◽  
Ju-You Lu ◽  
Yang Li ◽  
Dong-Huai Tu ◽  
Zhao-Tie Liu ◽  
...  
Keyword(s):  
Radical Addition ◽  
Atom Transfer ◽  
Atom Transfer Radical Addition

N-Chloroamines as substrates for metal-free photochemical atom-transfer radical addition reactions in continuous flow

2021 ◽  
Author(s):  
Alexander Steiner ◽  
Oscar de Frutos ◽  
Juan A. Rincón ◽  
Carlos Mateos ◽  
Jason Williams ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Radical Addition ◽  
Addition Reactions ◽  
Atom Transfer ◽  
Metal Free ◽  
Atom Transfer Radical Addition

N-Chloroamines have recently seen interest as substrates for atom-transfer radical addition (ATRA) reactions with olefins, to form β-chloroamine products, with complete atom incorporation. We report the development of a fully...

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