Preparation and Electron-Transfer Properties of Self-Assembled Monolayers of Ferrocene on Carbon Electrodes

2021 ◽  
Vol 125 (15) ◽  
pp. 8177-8184
Author(s):  
Rajendra P. Gautam ◽  
Christopher J. Barile
Keyword(s):  
Electron Transfer ◽  
Self Assembled Monolayers ◽  
Carbon Electrodes ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Electron Transfer Properties ◽  
Transfer Properties

scholarly journals Electron-Transfer Properties of Phenyleneethynylene Linkers Bound to Gold via a Self-Assembled Monolayer of Molecular Tripod

Molecules ◽  
2018 ◽  
Vol 23 (11) ◽  
pp. 2893 ◽  
Author(s):  
Toshikazu Kitagawa ◽  
Takashi Kawano ◽  
Takahiro Hase ◽  
Ikuma Hayakawa ◽  
Katsuyuki Hirai ◽  
...  
Keyword(s):  
Electron Transfer ◽  
High Surface ◽  
Gold Surface ◽  
Solid Surfaces ◽  
Self Assembled Monolayers ◽  
Self Assembled Monolayer ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Electron Transfer Properties ◽  
Transfer Properties

The three-point adsorption of tripod-shaped molecules enables the formation of robust self-assembled monolayers (SAMs) on solid surfaces, where the component molecules are fixed in a strictly upright orientation. In the present study, SAMs of a rigid molecular tripod consisting of an adamantane core and three CH2SH groups were employed to arrange ferrocene on a gold surface through oligo(p-phenyleneethynylene) linkers. Cyclic voltammetry of the monolayers demonstrated high surface coverage of ferrocene, yet the molecular interaction among adjacent ferrocene units was negligible. This was because of the extended intermolecular distance caused by the bulky tripod framework. The rates of electron transfer from the ferrocene to the gold surface through different linker lengths were determined by electrochemical measurements, from which the decay factor for oligo(p-phenyleneethynylene) wire was evaluated.

Evaluation of the Tunneling Constant for Long Range Electron Transfer in Azobenzene Self-Assembled Monolayers on Gold

Langmuir ◽  
1997 ◽  
Vol 13 (21) ◽  
pp. 5774-5778 ◽  
Author(s):  
H. Z. Yu ◽  
H. B. Shao ◽  
Y. Luo ◽  
H. L. Zhang ◽  
Z. F. Liu
Keyword(s):  
Electron Transfer ◽  
Long Range ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Donor/Acceptor Interactions in Self-Assembled Monolayers and Their Consequences on Interfacial Electron Transfer

2004 ◽  
Vol 108 (50) ◽  
pp. 19307-19313 ◽  
Author(s):  
Eden J. Pacsial ◽  
Daniel Alexander ◽  
Robert J. Alvarado ◽  
Massimiliano Tomasulo ◽  
Françisco M. Raymo
Keyword(s):  
Electron Transfer ◽  
Self Assembled Monolayers ◽  
Interfacial Electron Transfer ◽  
Assembled Monolayers ◽  
Donor Acceptor ◽  
Self Assembled

Pyridine as a Resonantly Addressable Group to Study Electron-Transfer Dynamics in Self-Assembled Monolayers

2018 ◽  
Vol 122 (23) ◽  
pp. 12534-12544 ◽  
Author(s):  
Tobias Wächter ◽  
Lothar Weinhardt ◽  
Andreas Terfort ◽  
Michael Zharnikov
Keyword(s):  
Electron Transfer ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Structure-Dependent Electron Transfer Kinetics of Azobenzene Self-Assembled Monolayers on Gold

1997 ◽  
Vol 13 (01) ◽  
pp. 42-47
Author(s):  
Zhao Jian-Wei ◽  
◽  
Yu Hua-Zhong ◽  
Wang Yong-Qiang ◽  
Zhang Hao-Li ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Self Assembled Monolayers ◽  
Electron Transfer Kinetics ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Kinetics Of

The influence of 2D nanomaterials on electron transfer across molecular thin films

2019 ◽  
Vol 4 (2) ◽  
pp. 431-436
Author(s):  
Na Kong ◽  
Shuang Zhang ◽  
Jing Liu ◽  
Jianmei Wang ◽  
Zhen Liu ◽  
...  
Keyword(s):  
Thin Films ◽  
Electron Transfer ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
2D Nanomaterials ◽  
Electron Transfer Pathways ◽  
Molecular Thin Films ◽  
Self Assembled

Design and formation of electron transfer pathways across self-assembled monolayers by the hydrophobic attachment of BN-NH2 and MoS2 nanosheets.

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