Kinetic-Model-Free Analysis of Transient Absorption Spectra Enabled by 2D Correlation Analysis

2021 ◽  
pp. 4148-4153
Author(s):  
Julian Hniopek ◽  
Carolin Müller ◽  
Thomas Bocklitz ◽  
Michael Schmitt ◽  
Benjamin Dietzek ◽  
...  
Keyword(s):  
Kinetic Model ◽  
Correlation Analysis ◽  
Absorption Spectra ◽  
Transient Absorption ◽  
Transient Absorption Spectra ◽  
Model Free ◽  
2D Correlation Analysis

scholarly journals Model-free decomposition of transient absorption spectra into components with time-dependent shape

2019 ◽  
Vol 205 ◽  
pp. 09011
Author(s):  
Lang B. ◽  
Rosspeintner A. ◽  
Angulo G. ◽  
Vauthey E.
Keyword(s):  
Absorption Spectra ◽  
Transient Absorption ◽  
Time Dependent ◽  
Absorption Data ◽  
Spectral Signatures ◽  
Additional Information ◽  
Transient Absorption Spectra ◽  
Model Free ◽  
Ultrafast Transient Absorption ◽  
Free Decomposition

Disentangling overlapping spectral signatures with time-dependent shape is performed using additional information contained in ultrafast transient absorption data, without applying any assumption on the underlying kinetics.

Graphical analysis of transient absorption spectra using the phasor approach

2015 ◽  
Vol 32 (8) ◽  
pp. 1693
Author(s):  
Hong Liu ◽  
Yulei Bai ◽  
Yun Zhang ◽  
Shuangli Ye ◽  
Weichao Xu ◽  
...  
Keyword(s):  
Absorption Spectra ◽  
Transient Absorption ◽  
Graphical Analysis ◽  
Transient Absorption Spectra

Electron attachment in irradiated solutions

1964 ◽  
Vol 277 (1371) ◽  
pp. 549-561 ◽  
Keyword(s):  
Absorption Spectra ◽  
Transient Absorption ◽  
Electron Attachment ◽  
Alkaline Solutions ◽  
Neutral Solution ◽  
Anaerobic Conditions ◽  
Ketyl Radical ◽  
Neutral Radical ◽  
Transient Absorption Spectra ◽  
Flash Spectroscopy

Transient absorption spectra have been obtained by pulsed radiolysis and flash spectroscopy of neutral and alkaline solutions of benzophenone under anaerobic conditions. These spectra demonstrate the formation of the ketyl radical ion (C 6 H 5 ) 2 Ċ—O - as a primary product resulting from electron attachment to benzophenone. In neutral solution, the rapid neutralization of the ketyl ion produces the neutral radical (C 6 H 5 ) 2 Ċ—OH, and this is shown by a change in the optical absorption spectrum. Neither of the absorption spectra due to these species is observed in acid solutions. These observations show that in neutral and alkaline solution, the hydrated electron reacts directly with the solute, whereas in acid solution it is converted to the hydrogen atom before reacting with the solute.

PICOSECOND TRANSIENT ABSORPTION SPECTRA OF HEMOGLOBIN

1978 ◽  
pp. 1075-1083
Author(s):  
B.I. Greene ◽  
R.M. Hochstrasser ◽  
R.B. Weisman ◽  
W.A. Eaton
Keyword(s):  
Absorption Spectra ◽  
Transient Absorption ◽  
Transient Absorption Spectra
Sign in / Sign up

Export Citation Format

Share Document