Amine-Cured Glycidyl Esters as Dual Dynamic Epoxy Vitrimers

2022 ◽  
Author(s):  
Yingchun Sun ◽  
Miaomiao Wang ◽  
Zhen Wang ◽  
Yifan Mao ◽  
Ling Jin ◽  
...  
Keyword(s):  
Molecules ◽  
2021 ◽  
Vol 26 (9) ◽  
pp. 2449
Author(s):  
Lauren Girard ◽  
Kithsiri Herath ◽  
Hernando Escobar ◽  
Renate Reimschuessel ◽  
Olgica Ceric ◽  
...  

The U.S. Food and Drug Administration’s (FDA′s) Center for Veterinary Medicine (CVM) has been investigating reports of pets becoming ill after consuming jerky pet treats since 2007. Renal failure accounted for 30% of reported cases. Jerky pet treats contain glycerin, which can be made from vegetable oil or as a byproduct of biodiesel production. Glycidyl esters (GEs) and 3-monochloropropanediol esters (3-MCPDEs) are food contaminants that can form in glycerin during the refining process. 3-MCPDEs and GEs pose food safety concerns, as they can release free 3-MCPD and glycidol in vivo. Evidence from studies in animals shows that 3-MCPDEs are potential toxins with kidneys as their main target. As renal failure accounted for 30% of reported pet illnesses after the consumption of jerky pet treats containing glycerin, there is a need to develop a screening method to detect 3-MCPDEs and GEs in glycerin. We describe the development of an ultra-high-pressure liquid chromatography/quadrupole time-of-flight (UHPLC/Q-TOF) method for screening glycerin for MCPDEs and GEs. Glycerin was extracted and directly analyzed without a solid-phase extraction procedure. An exact mass database, developed in-house, of MCPDEs and GEs formed with common fatty acids was used in the screening.


2019 ◽  
Vol 73 (S1) ◽  
Author(s):  
J. Rousova ◽  
J. Konschnik ◽  
H. Majer ◽  
A. Pavkovich ◽  
C. English
Keyword(s):  

2017 ◽  
Vol 94 (6) ◽  
pp. 759-765 ◽  
Author(s):  
Yu Hua Wong ◽  
Oi Ming Lai ◽  
Faridah Abas ◽  
Kar Lin Nyam ◽  
Imededdine Arbi Nehdi ◽  
...  

1966 ◽  
Vol 11 (3) ◽  
pp. 447-448 ◽  
Author(s):  
S. R. Sandler ◽  
F. R. Berg
Keyword(s):  

Author(s):  
Willian Cruzeiro Silva ◽  
Roseli Aparecida Ferrari ◽  
Eduardo Vicente ◽  
Klicia Araujo Sampaio ◽  
Adriana Pavesi Arisseto
Keyword(s):  

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Yu Hua Wong ◽  
Kok Ming Goh ◽  
Kar Lin Nyam ◽  
Ling Zhi Cheong ◽  
Yong Wang ◽  
...  

Abstract 3-Monochloropropane-1,2-diol (3-MCPD) esters and glycidyl esters (GE) are heat-induced contaminants which form during oil refining process, particularly at the high temperature deodorization stage. It is worth to investigate the content of 3-MCPD and GE in fries which also involved high temperature. The content of 3-MCPD esters and GE were monitored in fries. The factors that been chosen were temperature and duration of frying, and different concentration of salt (NaCl). The results in our study showed that the effect was in the order of concentration of sodium chloride < frying duration < frying temperature. The content of 3-MCPD esters was significantly increased whereas GE was significantly decreased, when prolong the frying duration. A high temperature results in a high 3-MCPD ester level but a low GE level in fries. The present of salt had contributed significant influence to the generation of 3-MCPD. The soaking of potato chips in salt showed no significant effect on the level of GE during the frying. The oil oxidation tests showed that all the fries were below the safety limit. Hence, the frying cycle, temperature and the added salt to carbohydrate-based food during frying should be monitored.


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