scholarly journals Monitoring of heat-induced carcinogenic compounds (3-monochloropropane-1,2-diol esters and glycidyl esters) in fries

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Yu Hua Wong ◽  
Kok Ming Goh ◽  
Kar Lin Nyam ◽  
Ling Zhi Cheong ◽  
Yong Wang ◽  
...  

Abstract 3-Monochloropropane-1,2-diol (3-MCPD) esters and glycidyl esters (GE) are heat-induced contaminants which form during oil refining process, particularly at the high temperature deodorization stage. It is worth to investigate the content of 3-MCPD and GE in fries which also involved high temperature. The content of 3-MCPD esters and GE were monitored in fries. The factors that been chosen were temperature and duration of frying, and different concentration of salt (NaCl). The results in our study showed that the effect was in the order of concentration of sodium chloride < frying duration < frying temperature. The content of 3-MCPD esters was significantly increased whereas GE was significantly decreased, when prolong the frying duration. A high temperature results in a high 3-MCPD ester level but a low GE level in fries. The present of salt had contributed significant influence to the generation of 3-MCPD. The soaking of potato chips in salt showed no significant effect on the level of GE during the frying. The oil oxidation tests showed that all the fries were below the safety limit. Hence, the frying cycle, temperature and the added salt to carbohydrate-based food during frying should be monitored.

2019 ◽  
Vol 102 (3) ◽  
pp. 903-914 ◽  
Author(s):  
Mathieu Dubois ◽  
Anna-Maria Empl ◽  
Greg Jaudzems ◽  
Quentin Basle ◽  
Erik Konings

Abstract Background: Monochloropropanediol (MCPD) and its fatty acid esters as well as glycidyl fatty acid esters are substances generated during oil refining or food processing. The free form released during digestion, 3-MCPD and glycidol, have shown adverse effects in animal studies. Objective: So far, the available analytical methods have not been validated in a collaborative study for infant and adult nutritional formulas. This manuscript describes a single-laboratory validation method in view of a future multilaboratory validation trial. Methods: The method described is for the direct determination of 2- and 3-MCPD and indirect determination of 2- and 3-MCPD esters and glycidyl esters in infant and adult/pediatric nutritional formulas by GC coupled to MS. Results: The analytical range was found to be 4–2000 μg/kg powder formula and 0.7–333 μg/kg liquid formula for fatty acid esters of MCPD and glycidol, and 2.5–750 μg/kg samples for free MCPD. The recovery rates were within 91–124% for all samples. Repeatability precision was &lt;20% at levels close to the LOQ. Conclusions: The results met the Standard Method Performance Requirements® (SMPR) set by the AOAC Stakeholder Panel on Infant Formula and Adult Nutritionals. Highlights: The AOAC Expert Review Panel approved the present method as AOAC Official First Action 2018.03.


Alloy Digest ◽  
1970 ◽  
Vol 19 (4) ◽  

Abstract FIRTH VICKERS FI (A1) is a chromium type heat and corrosion resistant alloy steel recommended for oil refining and chemical plant equipment. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: SS-236. Producer or source: Firth-Vickers Stainless Steels Ltd.


2017 ◽  
Vol 94 (6) ◽  
pp. 759-765 ◽  
Author(s):  
Yu Hua Wong ◽  
Oi Ming Lai ◽  
Faridah Abas ◽  
Kar Lin Nyam ◽  
Imededdine Arbi Nehdi ◽  
...  

2019 ◽  
Vol 36 (11) ◽  
pp. 1626-1636 ◽  
Author(s):  
Raznim Arni Abd. Razak ◽  
Azmil Haizam Ahmad Tarmizi ◽  
Abdul Niefaizal Abdul Hammid ◽  
Ainie Kuntom ◽  
Intan Safinar Ismail ◽  
...  

Author(s):  
Kirk Hanawa

In many LNG receiving terminals worldwide, the cryogenic heat of imported LNG which was liquefied by using 10% energy of natural gas supply1), 2), has been wasted into the sea water mainly through heat exchangers like ORVs (Open Rack Vaporizer)3). This cryogenic heat of 110 K (-256 F) class is considered, however, as an excellent energy source to apply thermodynamic cycles. Several literature, accordingly, are found to improve such high-grade energy potential of LNG regasification process as a low temperature sink, combining with fired heater at 1,100 K (1520 F) class or GT main exhaust gas at 700 K (800 F) class as a high temperature source, through Brayton and Rankine cycles5),6),7),8),9). This paper presents a typical example of closed “Ericsson” cycle which has the minimum cycle temperature of 157 K (-176 F) from LNG cryogenic heat and the maximum of 550 K (531 F) from the partial HRSG exit heat mixed with the partial GT exit gas. This closed gas turbine, from viewpoints of minor modification to existing power plants and no energy impacts for high temperature source, which would be better than the above-described idea, is able to offer 35% thermal efficiency. And it is recognized that this system would be superior to existing cryogenic generation systems of 20% class operated by Rankine Cycle.


Fuel ◽  
2015 ◽  
Vol 139 ◽  
pp. 411-424 ◽  
Author(s):  
Tyler Stephenson ◽  
Mike Hazelton ◽  
Martin Kupsta ◽  
Justin Lepore ◽  
Einar Johan Andreassen ◽  
...  

2011 ◽  
Vol 59 (11) ◽  
pp. 6263-6270 ◽  
Author(s):  
Markus Küsters ◽  
Ute Bimber ◽  
Sebastian Reeser ◽  
Rainer Gallitzendörfer ◽  
Michael Gerhartz

Sign in / Sign up

Export Citation Format

Share Document