Analysis of Small-Angle Neutron Scattering Spectra from Deformed Polymers with the Spherical Harmonic Expansion Method and a Network Model

2018 ◽  
Vol 51 (21) ◽  
pp. 9011-9018 ◽  
Author(s):  
Zhi-Yuan Wang ◽  
Dejia Kong ◽  
Lincan Yang ◽  
Hongwei Ma ◽  
Fengmei Su ◽  
...  
2011 ◽  
Vol 110 (10) ◽  
pp. 102217 ◽  
Author(s):  
Andrey V. Ilatovskiy ◽  
Dmitry V. Lebedev ◽  
Michael V. Filatov ◽  
Mikhail Grigoriev ◽  
Michael G. Petukhov ◽  
...  

1991 ◽  
Vol 248 ◽  
Author(s):  
J. Bastide ◽  
F. Boue ◽  
R. Oeser ◽  
E. Mendes ◽  
F. Zielinski ◽  
...  

AbstractA totally unexpected phenomenon has been observed for the first time a few years ago when studying, by small angle neutron scattering, rubbery networks containing a small proportion of uncrosslinked labelled (deuterated) chains [1].When such a system is elongated, the scattered intensity strongly increases with the extension ratio λ for q vectors parallel to the stretching direction (and for low q values). Conversely, in the direction perpendicular to the elongation axis, the scattered intensity slightly decreases at low q for small extension ratios and then remains approximately constant when λ is further increased. The changes which are observed occur therefore in a direction opposite to the “conventional” one, i.e. that corresponding to chains effectively linked by at least two chemical junctions to the network and thus oriented on an average along the direction of stretching.


1997 ◽  
Vol 506 ◽  
Author(s):  
L.P. Aldridge ◽  
W.K. Bertram ◽  
T.M. Sabine ◽  
A Ioffe

ABSTRACTSmall angle neutron scattering from hydrating cement paste was compared to that from a paste made of a blend of cement and ground granulated blast furnace slag. The scattering measurements were used to determine the average size of the scattering particles during hydration. Their rate of growth was monitored in-situ over the first 40 hours of hydration. There was little difference in the scattering spectra, showing that the scattering particles in paste containing slag blend or cement were of similar size. At the beginning of hydration the particle radii were about 250 nn and after 14 days they had grown to over 600nm.Estimates of particle sizes are critically dependent on the amount of multiple scattering. Therefore the amount of multiple scattering of the sample must be taken into account before making comparisons between the sizes of particles of different matrices.


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