Visible-Light Photocatalytic Tri- and Difluoroalkylation Cyclizations: Access to a Series of Indole[2,1-a]isoquinoline Derivatives in Continuous Flow

2021 ◽  
Vol 23 (5) ◽  
pp. 1950-1954
Author(s):  
Xin Yuan ◽  
Xiu Duan ◽  
Yu-Sheng Cui ◽  
Qi Sun ◽  
Long-Zhou Qin ◽  
...  
2021 ◽  
Vol 23 (3) ◽  
pp. 1280-1285
Author(s):  
Hao-Xing Xu ◽  
Ze-Run Zhao ◽  
Yeersen Patehebieke ◽  
Qian-Qian Chen ◽  
Shun-Guo Fu ◽  
...  

A continuous-flow photocatalytic synthesis of the industrially important thiuram disulfides has been developed, utilizing O2 as the oxidant and Eosin Y as the photoredox catalyst.


2015 ◽  
Vol 4 (1) ◽  
pp. 12-17 ◽  
Author(s):  
Natan Straathof ◽  
Dannie Osch ◽  
Arian Schouten ◽  
Xiao Wang ◽  
Jaap Schouten ◽  
...  

2020 ◽  
Author(s):  
Cristian Cavedon ◽  
Eric T. Sletten ◽  
Amiera Madani ◽  
Olaf Niemeyer ◽  
Peter H. Seeberger ◽  
...  

Protecting groups are key in the synthesis of complex molecules such as carbohydrates to distinguish functional groups of similar reactivity. The harsh conditions required to cleave stable benzyl ether protective groups are not compatible with many other protective and functional groups. The mild, visible light-mediated debenzylation disclosed here renders benzyl ethers orthogonal protective groups. Key to success is the use of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as stoichiometric or catalytic photooxidant such that benzyl ethers can be cleaved in the presence of azides, alkenes, and alkynes. The reaction time for this transformation can be reduced from hours to minutes in continuous flow. <br>


2020 ◽  
Vol 10 (9) ◽  
pp. 3238
Author(s):  
Min Liu ◽  
Guangxin Wang ◽  
Panpan Xu ◽  
Yanfeng Zhu ◽  
Wuhui Li

In this study, the Ag3PO4/SnO2 heterojunction on carbon cloth (Ag3PO4/SnO2/CC) was successfully fabricated via a facile two-step process. The results showed that the Ag3PO4/SnO2/CC heterojunction exhibited a remarkable photocatalytic performance for the degradation of Rhodamine B (RhB) and methylene blue (MB), under visible light irradiation. The calculated k values for the degradation of RhB and MB over Ag3PO4/SnO2/CC are 0.04716 min−1 and 0.04916 min−1, which are higher than those calculated for the reactions over Ag3PO4/SnO2, Ag3PO4/CC and SnO2/CC, respectively. The enhanced photocatalytic activity could mainly be attributed to the improved separation efficiency of photogenerated electron-hole pairs, after the formation of the Ag3PO4/SnO2/CC heterojunction. Moreover, carbon cloth with a large specific surface area and excellent conductivity was used as the substrate, which helped to increase the contact area of dye solution with photocatalysts and the rapid transfer of photogenerated electrons. Notably, when compared with the powder catalyst, the catalysts supported on carbon cloth are easier to quickly recycle from the pollutant solution, thereby reducing the probability of recontamination.


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