Kinetic Resolution Driven Diastereo- and Enantioselective Synthesis of cis-β-Heteroaryl Amino Cycloalkanols by Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation

2016 ◽  
Vol 18 (24) ◽  
pp. 6436-6439 ◽  
Author(s):  
Vijyesh K. Vyas ◽  
Bhalchandra M. Bhanage
Keyword(s):  
Kinetic Resolution ◽  
Enantioselective Synthesis ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation

Enantioselective synthesis of chiral multicyclic γ-lactones via dynamic kinetic resolution of racemic γ-keto carboxylic acids

2020 ◽  
Vol 7 (1) ◽  
pp. 104-108 ◽  
Author(s):  
Zhichao Xiong ◽  
Jiangyan Tian ◽  
Peng Xue ◽  
Xumu Zhang ◽  
Hui Lv
Keyword(s):  
Carboxylic Acids ◽  
Kinetic Resolution ◽  
Enantioselective Synthesis ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution ◽  
High Yields

Ru-Catalyzed asymmetric transfer hydrogenation of γ-keto carboxylic acids has been achieved, affording chiral multicyclic γ-lactones in high yields with excellent diastereo- and enantioselectivities.

Enantioselective Synthesis of 1-Aryl-Substituted Tetrahydroisoquinolines Through Ru-Catalyzed Asymmetric Transfer Hydrogenation

2015 ◽  
Vol 2015 (29) ◽  
pp. 6503-6514 ◽  
Author(s):  
Marc Perez ◽  
Zi Wu ◽  
Michelangelo Scalone ◽  
Tahar Ayad ◽  
Virginie Ratovelomanana-Vidal
Keyword(s):  
Enantioselective Synthesis ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation
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