Chemical Route to Yb14MgSb11 Composites with Nanosized Iron Inclusions for the Reduction of Thermal Conductivity

2021 ◽  
Vol 4 (4) ◽  
pp. 3748-3756
Author(s):  
Christopher J. Perez ◽  
Zhijie Chen ◽  
Willie B. Beeson ◽  
Sevan Chanakian ◽  
Kai Liu ◽  
...  
2011 ◽  
Vol 31 (2-3) ◽  
Author(s):  
Mahesh Baboo ◽  
Manasvi Dixit ◽  
Dinesh Patidar ◽  
Kananbala Sharma ◽  
Narendra Sahai Saxena

Abstract This paper focuses on the comparative evaluation of the glass transition temperature (Tg), storage modulus and thermal conductivity of trans-polyisoprene (TPI) and CdS-TPI nanocomposite. The CdS nanoparticles synthesized by chemical route are dispersed into TPI using ultrasonic vibrations. Particle size of nanocrystals is obtained from X-ray diffraction and found to be 1.84 nm. Thermo-mechanical properties (Tg and storage modulus) are measured by dynamic mechanical analyzer (DMA), while thermal conductivity is a measured using the transient plane source (TPS) technique. It is observed that glass transition temperature and thermal conductivity are higher while storage modulus and mechanical properties are lower for CdS-TPI nanocomposites than for pure TPI. This has been explained on the basis of structural changes occurring due to introduction of CdS as filler into the TPI.


Author(s):  
Pratibha L. Gai ◽  
M. A. Saltzberg ◽  
L.G. Hanna ◽  
S.C. Winchester

Silica based ceramics are some of the most fundamental in crystal chemistry. The cristobalite form of silica has two modifications, α (low temperature, tetragonal form) and β (high temperature, cubic form). This paper describes our structural studies of unusual chemically stabilized cristobalite (CSC) material, a room temperature silica-based ceramic containing small amounts of dopants, prepared by a wet chemical route. It displays many of the structural charatcteristics of the high temperature β-cristobalite (∼270°C), but does not undergo phase inversion to α-cristobalite upon cooling. The Structure of α-cristobalite is well established, but that of β is not yet fully understood.Compositions with varying Ca/Al ratio and substitutions in cristobalite were prepared in the series, CaO:Al2O3:SiO2 : 3-x: x : 40, with x= 0-3. For CSC, a clear sol was prepared from Du Pont colloidal silica, Ludox AS-40®, aluminium nitrate nonahydrate, and calcium nitrate hexahydrate in proportions to form a final composition 1:2:40 composition.


1981 ◽  
Vol 42 (C4) ◽  
pp. C4-931-C4-934 ◽  
Author(s):  
M. F. Kotkata ◽  
M.B. El-den

1981 ◽  
Vol 42 (C6) ◽  
pp. C6-893-C6-895
Author(s):  
M. Locatelli ◽  
R. Suchail ◽  
E. Zecchi
Keyword(s):  

1981 ◽  
Vol 42 (C6) ◽  
pp. C6-247-C6-249 ◽  
Author(s):  
W. Bauernfeind ◽  
J. Keller ◽  
U. Schröder

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