Transparent Supercapacitor Display with Redox-Active Metallo-Supramolecular Polymer Films

2020 ◽  
Vol 12 (14) ◽  
pp. 16342-16349 ◽  
Author(s):  
Sanjoy Mondal ◽  
Takefumi Yoshida ◽  
Subrata Maji ◽  
Katsuhiko Ariga ◽  
Masayoshi Higuchi
Keyword(s):  
Polymer Films ◽  
Supramolecular Polymer ◽  
Redox Active

Stimuli-responsive metallo-supramolecular polymer films: design, synthesis and device fabrication

2014 ◽  
Vol 2 (44) ◽  
pp. 9331-9341 ◽  
Author(s):  
Masayoshi Higuchi
Keyword(s):  
Polymer Films ◽  
Chemical Properties ◽  
Device Fabrication ◽  
Supramolecular Polymer ◽  
Stimuli Responsive ◽  
Design Synthesis ◽  
Metal Interactions ◽  
Metal Metal ◽  
Metal Ligand

Based on the metal–ligand or metal–metal interactions, metallo-supramolecular polymer films showed stimuli-responsive electro- and photo-chemical properties such as electrochromism.

scholarly journals Aqueous-Processable Redox-Active Supramolecular Polymer Binders for Advanced Lithium/Sulfur Cells

2018 ◽  
Vol 30 (3) ◽  
pp. 685-691 ◽  
Author(s):  
Yoon Hwa ◽  
Peter D. Frischmann ◽  
Brett A. Helms ◽  
Elton J. Cairns
Keyword(s):  
Supramolecular Polymer ◽  
Polymer Binders ◽  
Redox Active ◽  
Lithium Sulfur

Electrochemically controlled release of chemicals from redox-active polymer films

1994 ◽  
Vol 375 (1-2) ◽  
pp. 233-241 ◽  
Author(s):  
S. Cosnier ◽  
C. Innocent ◽  
J.-C. Moutet ◽  
F. Tennah
Keyword(s):  
Controlled Release ◽  
Polymer Films ◽  
Redox Active

The electrochemical fabrication of electroactive polymer films from diamide- or diimide-cored N-phenylcarbazole dendrons for electrochromic applications

2016 ◽  
Vol 4 (6) ◽  
pp. 1271-1280 ◽  
Author(s):  
Sheng-Huei Hsiao ◽  
Shu-Wei Lin
Keyword(s):  
Polymer Films ◽  
Oxidative Coupling ◽  
Electroactive Polymer ◽  
Redox Active ◽  
Electrochemical Fabrication ◽  
Poly Imide

Redox-active and electrochromic poly(amide-carbazole) and poly(imide-carbazole) films were directly prepared on electrodes from N-phenylcarbazole dendrons by carbazole-based electrochemical oxidative coupling.

Nucleobase-functionalized supramolecular polymer films with tailorable properties and tunable biodegradation rates

2017 ◽  
Vol 8 (9) ◽  
pp. 1454-1459 ◽  
Author(s):  
Chih-Chia Cheng ◽  
Jyun-Jie Huang ◽  
Zhi-Sheng Liao ◽  
Shan-You Huang ◽  
Duu-Jong Lee ◽  
...  
Keyword(s):  
Physical Properties ◽  
Network Structure ◽  
Polymer Films ◽  
Three Dimensional ◽  
Supramolecular Polymer ◽  
Dimensional Network

Nucleobase-functionalized supramolecular films can directly self-assemble into a non-covalently cross-linked three-dimensional network structure with tuned physical properties and biodegradation rates.

Controlled Grafting of Tetrathiafulvalene (TTF) Containing Diacetylenic Units on Hydrogen-Terminated Silicon Surfaces: From Redox-Active TTF Monolayer to Polymer Films

2012 ◽  
Vol 116 (22) ◽  
pp. 12093-12102 ◽  
Author(s):  
Gilles Yzambart ◽  
Bruno Fabre ◽  
Franck Camerel ◽  
Thierry Roisnel ◽  
Dominique Lorcy
Keyword(s):  
Polymer Films ◽  
Silicon Surfaces ◽  
Redox Active

scholarly journals A Terpyridine-Fe2+-Based Coordination Polymer Film for On-Chip Micro-Supercapacitor with AC Line-Filtering Performance

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1002
Author(s):  
Hongxing Wang ◽  
Feng Qiu ◽  
Chenbao Lu ◽  
Jinhui Zhu ◽  
Changchun Ke ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Polymer Films ◽  
Flexible Electronics ◽  
Electrode Materials ◽  
Interfacial Polymerization ◽  
Energy Storage Devices ◽  
Storage Devices ◽  
Redox Active ◽  
Ultrathin Polymer Films ◽  
On Chip

The preparation of redox-active, ultrathin polymer films as the electrode materials represents a major challenge for miniaturized flexible electronics. Herein, we demonstrated a liquid–liquid interfacial polymerization approach to a coordination polymer films with ultrathin thickness from tri(terpyridine)-based building block and iron atoms. The as-synthesized polymer films exhibit flexible properties, good redox-active and narrow bandgap. After directly transferred to silicon wafers, the on-chip micro-supercapacitors of TpPB-Fe-MSC achieved the high specific capacitances of 1.25 mF cm−2 at 50 mV s−1 and volumetric energy density of 5.8 mWh cm−3, which are superior to most of semiconductive polymer-based micro-supercapacitor (MSC) devices. In addition, as-fabricated on-chip MSCs exhibit typical alternating current (AC) line-filtering performance (−71.3° at 120 Hz) and a short resistance–capacitance (RC) time (0.06 ms) with the electrolytes of PVA/LiCl. This study provides a simple interfacial approach to redox-active polymer films for microsized energy storage devices.

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