Printed Zinc Tin Oxide Diodes: From Combustion Synthesis to Large-Scale Manufacturing

Printed metal oxide devices have been widely desired in flexible electronic applications to allow direct integration on foils and to reduce electronic waste and associated costs. Especially, semiconductor devices made from non-critical raw materials, such as Zn, Sn (and not, for example, In), have gained much interest. Despite considerable progress in the field, the upscale requirements from lab to fab scale to produce these materials and devices remain a challenge. In this work, we report the importance of solution combustion synthesis (SCS) when compared with sol-gel in the production of zinc tin oxide (ZTO) thin films using a solvent (1-methoxypropanol) that has lower environmental impact than the widely used and toxic 2-methoxyethanol. To assure the compatibility with low-cost flexible substrates in high-throughput printing techniques, a low annealing temperature of 140 ºC was achieved for these thin films by combining SCS and infrared (IR) annealing in a short processing time. These conditions allowed the transition from spin-coating (lab scale) to flexographic printing (fab scale) at a printing speed of 10 m/min in a roll-to-roll (R2R) pilot line. The ZTO (1:1 Zn:Sn-ratio) diodes show a rectification ratio of 103, a low operation voltage (≤ 3 V), promising reproducibility and low variability. The results provide the basis for further optimization (device size, encapsulation) to meet the requirements of diodes in flexible electronics applications such as passive-matrix addressing, energy harvesting and rectification.

Selective detection of microcracks under the surface of glass substrates by non-contact stress-induced light-scattering method with temperature variations

Demand for flexible electronics is increasing due to recent global movements related to IoT. In particular, the ultra-thin glass substrate can be bent, its use is expanding for various applications such as thin liquid crystal panels. On the other hand, fine-polishing techniques such as chemical mechanical polishing treatments, are important techniques in glass substrate manufacturing. However, these techniques may cause microcracks under the surface of glass substrates because they use mechanical friction. We propose a novel non-contact thermal stress-induced light-scattering method (N-SILSM) using a heating device for inspecting surfaces to detect polishing-induced microcracks. In this report, we carry out the selective detection of microcracks and tiny particles using a N-SILSM with temperature variation. Our results show that microcracks and tiny particles can be distinguished and measured by a N-SILSM utilizing temperature change, and that microcrack size can be estimated based on the change in light-scattering intensity.

A novel scalable electrode array and system for non-invasively assessing gastric function using flexible electronics

Disorders of gastric function are highly prevalent, but diagnosis often remains symptom-based and inconclusive. Body surface gastric mapping is an emerging diagnostic solution, but current approaches lack scalability and are cumbersome and clinically impractical. We present a novel scalable system for non-invasively mapping gastric electrophysiology in high-resolution (HR) at the body-surface. The system comprises a custom-designed flexible HR sensor array and portable data-logger synchronized to an App, with automated analysis and visualization algorithms. The novel system underwent performance testing then validation in 24 healthy subjects. In all subjects, gastric electrophysiology and meal responses were successfully captured and mapped non-invasively (mean frequency 2.9 ± 0.3 cycles per minute; peak amplitude at mean 60 m postprandially with return to baseline in <4 h). Spatiotemporal mapping showed regular and consistent wave activity of mean direction 182.7°±73 (74.7% antegrade, 7.8% retrograde, 17.5% indeterminate). The presented system is a new diagnostic tool for assessing gastric function that is scalable, validated, and ready for clinical applications, offering several biomarkers that are new to gastroenterology practice.

Flexible carbonized cotton/thermoplastic polyurethane composites with outstanding electric heating and pressure sensing performance

Although flexible wearable conductive textiles for various applications have attracted great attention from researchers in recent years, it is still a great challenge to fabricate conductive textiles with the advantages of a simple fabrication process, excellent flexibility, environmental friendliness, and superior performance. Carbonized cellulose materials are gradually emerging in flexible electronics due to their flexibility, low cost, abundant raw materials, and electrical conductivity. Herein, carbonized cotton fabrics were fabricated from cotton fabrics via a simple carbonization process. Then carbonized cotton/thermoplastic polyurethane composites, with excellent electric heating performance and pressure sensing performance, were fabricated through a dip-and-dry method. Carbonized cotton/thermoplastic polyurethane composites show satisfactory electrical conductivity, electric heating temperature rising performance, heating stability, and resistance stability. The surface temperature of carbonized cotton/thermoplastic polyurethane composites can reach ≈53°C within 1.5 min at 5 V. Besides this, the fabricated flexible pressure sensor based on carbonized cotton/thermoplastic polyurethane composites exhibits the combined superiority of a wide working range (0–16 kPa), high sensitivity (98.77 kPa−1), and excellent durability (>4000 cycles). Moreover, the finger motions and wrist pulse can be monitored in real time. These results demonstrate the potential application value and broad developmental prospects of carbonized cotton/thermoplastic polyurethane composites in flexible wearable electronics.

Flexible Capacitive Pressure Sensors with Micro-Patterned Porous Dielectric Layer for Wearable Electronics

Highly sensitive soft sensors play key roles in flexible electronics, which therefore have attracted much attention in recent years. Herein, we report a flexible capacitive pressure sensor with high sensitivity by using engineered micro-patterned porous polydimethylsiloxane (PDMS) dielectric layer through an environmental-friendly fabrication procedure. The porous structure is formed by evaporation of emulsified water droplets during PDMS curing process, while the micro-patterned structure is obtained via molding on sandpaper. Impressively, this structure renders the capacitive sensor with a high sensitivity up to 143.5 MPa-1 at the pressure range of 0.068~150 kPa and excellent anti-fatigue performance over 20,000 cycles. Meanwhile, the sensor can distinguish different motions of the same person or different people doing the same action. Our work illustrates the promising application prospects of this flexible pressure sensor for the security field or human motion monitoring area.

Recent Progress in Flexible Multiferroics

A great deal of interest has grown in both academia and industry toward flexible multiferroics in the recent years. The coupling of ferromagnetic properties with ferroelectric properties in multiferroic materials opens up many opportunities in applications such as magnetoelectric random access memories, magnetic field sensors, and energy harvesters. Multiferroic materials on a flexible platform bring an exciting opportunity for the next generation of consumer electronics owing to their unique characteristics of wearability, portability, and weight reduction. However, the fabrication of flexible multiferroic devices is still a great challenge due to various technical difficulties, including the requirement of high growth temperature of the oxide-based multiferroic materials, their lattice mismatch with the flexible substrates, and the brittleness of the functional layers. In this review article, we will discuss different methods of fabricating flexible or even freestanding oxide films to achieve flexible electronics. This article will address the benefits and challenges of each synthesis method in terms of interlayer interactions and growth parameters. Furthermore, the article will include an account of the possible bending limits of different flexible substrates without degrading the properties of the functional layer. Finally, we will address the challenges, opportunities, and future research directions in flexible multiferroics.

High-conductivity flexible Ag films formed by low-temperature and short-time sintering of PVP-modified silver oxalate composite ink

Attaining low-temperature sintering and high electrical conductivity is vital in the field of flexible electronics. Inks with silver oxalate as the precursor have recently received significant attention in this field; however, the high sintering temperature and long sintering time limit commercial applicability. High sintering temperature can shorten the sintering timereducing the conductivity. but lead to porous and uneven filmOn the other hand, morphology;low sintering temperature prolongthus,s thesintering time; thus, reducing the production efficiency. To solve the abovementionedproblems, a silver composite conductive ink modified by polyvinylpyrrolidone (PVP)was prepared in this study. The ink used silver oxalate as the precursor, methanol and acetone as the solvent, and 1, 2-diaminopropane as the complexing agent, and could reduce the sintering temperature and time to 160℃ and 20 min, respectively. After sintering, the silver film showed good electrical conductivity, and low resistivity (4.56 μΩ·cm). Furthermore, the impact of sintering temperature on the surface morphology and electrical conductivity were also studied, and the results showed that PVP had a positive influence on the nucleation of silver and the microstructure of the sintered silver film.