Enhanced Selective Oxidation of Benzyl Alcohol via In Situ H2O2 Production over Supported Pd-Based Catalysts

Highly selective oxidation of benzyl alcohol for simultaneous hydrogen production promotion with solar-driven dual photoelectrode photoelectrochemical cell.

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In Situ Hydrogen Peroxide Production for Selective Oxidation of Benzyl Alcohol over a Pd@Hierarchical Titanium Silicalite Catalyst

ACS Omega ◽

10.1021/acsomega.0c02065 ◽

2020 ◽

Vol 5 (27) ◽

pp. 16865-16874

Author(s):

Jinghui Lyu ◽

Lei Niu ◽

Fanglie Shen ◽

Jun Wei ◽

Yizhi Xiang ◽

...

Keyword(s):

Hydrogen Peroxide ◽

Benzyl Alcohol ◽

Selective Oxidation ◽

Titanium Silicalite ◽

Hydrogen Peroxide Production ◽

Oxidation Of Benzyl Alcohol

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One-step solvothermal synthesis of Al-promoted Fe3O4 magnetic catalysts for the selective oxidation of benzyl alcohol to benzaldehyde with H2O2 in water

RSC Advances ◽

10.1039/c6ra23019a ◽

2016 ◽

Vol 6 (103) ◽

pp. 101048-101060 ◽

Cited By ~ 20

Author(s):

Leisha Xiong ◽

Rong Chen ◽

Fengxi Chen

Keyword(s):

Catalytic Activity ◽

Synergistic Effect ◽

Benzyl Alcohol ◽

Selective Oxidation ◽

Solvothermal Synthesis ◽

Active Sites ◽

Title Reaction ◽

Oxidation Of Benzyl Alcohol ◽

One Step

The in situ modification of Fe3O4 by aluminium introduced new active sites besides the primary iron sites. Their synergistic effect contributes to much better catalytic activity of Al-promoted Fe3O4 in the title reaction.

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Surface functionalized TiO2 supported Pd catalysts for solvent-free selective oxidation of benzyl alcohol

Catalysis Today ◽

10.1016/j.cattod.2014.06.005 ◽

2015 ◽

Vol 250 ◽

pp. 218-225 ◽

Cited By ~ 31

Author(s):

Patcharaporn Weerachawanasak ◽

Graham. J. Hutchings ◽

Jennifer K. Edwards ◽

Simon A. Kondrat ◽

Peter J. Miedziak ◽

...

Keyword(s):

Benzyl Alcohol ◽

Selective Oxidation ◽

Solvent Free ◽

Pd Catalysts ◽

Oxidation Of Benzyl Alcohol ◽

Supported Pd Catalysts ◽

Supported Pd

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Selective Oxidation of Benzyl Alcohol Catalyzed by Pd/PMO-SBA-15 Catalyst

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) ◽

10.3724/sp.j.1088.2010.00447 ◽

2011 ◽

Vol 31 (11) ◽

pp. 1369-1373

Author(s):

Cheng LIU ◽

Rong TAN ◽

Donghong YIN ◽

Ningya YU ◽

Yuxu ZHOU

Keyword(s):

Benzyl Alcohol ◽

Selective Oxidation ◽

Oxidation Of Benzyl Alcohol

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Cobalt Single Atoms Embedded in Nitrogen‐Doped Graphene for Selective Oxidation of Benzyl Alcohol by Activated Peroxymonosulfate

Small ◽

10.1002/smll.202004579 ◽

2021 ◽

pp. 2004579

Author(s):

Jiaquan Li ◽

Shiyong Zhao ◽

Lianji Zhang ◽

San Ping Jiang ◽

Shi‐Ze Yang ◽

...

Keyword(s):

Benzyl Alcohol ◽

Selective Oxidation ◽

Nitrogen Doped ◽

Single Atoms ◽

Oxidation Of Benzyl Alcohol ◽

Nitrogen Doped Graphene ◽

Doped Graphene

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On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow

Nanotechnology Reviews ◽

10.1515/ntrev-2012-0085 ◽

2014 ◽

Vol 3 (1) ◽

pp. 99-110 ◽

Cited By ~ 2

Author(s):

Hannes Alex ◽

Norbert Steinfeldt ◽

Klaus Jähnisch ◽

Matthias Bauer ◽

Sandra Hübner

Keyword(s):

Catalytic Activity ◽

Benzyl Alcohol ◽

Aerobic Oxidation ◽

X Ray ◽

X Ray Scattering ◽

Oxidation Of Benzyl Alcohol ◽

Transmission Electron ◽

Vis Spectroscopy ◽

Selective Aerobic Oxidation

AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.

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