Metal-Catalyzed Switching Degradation of Vinyl Polymers via Introduction of an “In-Chain” Carbon–Halogen Bond as the Trigger

2021 ◽  
pp. 1535-1539
Author(s):  
Taichi Kimura ◽  
Keita Kuroda ◽  
Hiroyuki Kubota ◽  
Makoto Ouchi
Keyword(s):  
Halogen Bond ◽  
Vinyl Polymers ◽  
Metal Catalyzed

End-Functionalization with Alcohols in Metal-Catalyzed Living Radical Polymerization through Umpolung of Growing Carbon−Halogen Bond

2010 ◽  
Vol 43 (21) ◽  
pp. 8910-8916 ◽  
Author(s):  
Kazuhiro Nakatani ◽  
Takaya Terashima ◽  
Makoto Ouchi ◽  
Mitsuo Sawamoto
Keyword(s):  
Radical Polymerization ◽  
Halogen Bond ◽  
Living Radical Polymerization ◽  
Metal Catalyzed

Modern Transition-Metal-Catalyzed Carbon–Halogen Bond Formation

2016 ◽  
Vol 116 (14) ◽  
pp. 8003-8104 ◽  
Author(s):  
David A. Petrone ◽  
Juntao Ye ◽  
Mark Lautens
Keyword(s):  
Transition Metal ◽  
Halogen Bond ◽  
Bond Formation ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Sequence-Controlled Vinyl Polymers by Transition Metal-Catalyzed Step-Growth and Living Radical Polymerizations

2014 ◽  
Vol 1613 ◽  
pp. 17-21
Author(s):  
Kotaro Satoh ◽  
Masami Kamigaito
Keyword(s):  
Radical Polymerization ◽  
Building Blocks ◽  
Vinyl Monomers ◽  
Vinyl Polymers ◽  
Living Radical Polymerizations ◽  
Step Growth ◽  
Novel Strategy ◽  
Metal Catalyzed ◽  
Polymeric Structures ◽  
Step Polymerization

ABSTRACTThe metal-catalyzed step-growth radical polymerization was achieved to enable two systems for preparing tailored polymeric structures, i.e., sequence-regulated vinyl copolymer and periodically-functionalized polymer. The former is a novel strategy for preparing sequence-regulated vinyl copolymers by step-polymerization of sequence-regulated vinyl oligomers prepared from common vinyl monomers as building blocks. The later deals the simultaneous chain- and step-growth radical polymerization, which resulted in the polymers with periodic functional groups.

Chelation-assisted transition metal-catalysed C–H chalcogenylations

2020 ◽  
Vol 7 (8) ◽  
pp. 1022-1060 ◽  
Author(s):  
Wenbo Ma ◽  
Nikolaos Kaplaneris ◽  
Xinyue Fang ◽  
Linghui Gu ◽  
Ruhuai Mei ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Site Selectivity ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review summarizes recent advances in C–S and C–Se formations via transition metal-catalyzed C–H functionalization utilizing directing groups to control the site-selectivity.

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