Rapid Sodium-Ion Storage in Hard Carbon Anode Material Derived from Ganoderma lucidum Residue with Inherent Open Channels

2019 ◽  
Vol 7 (17) ◽  
pp. 14841-14847 ◽  
Author(s):  
Peng-Rong Lu ◽  
Ji-Li Xia ◽  
Xiao-Ling Dong
2021 ◽  
Vol 13 (40) ◽  
pp. 47728-47739
Author(s):  
Wentao Deng ◽  
Yongjie Cao ◽  
Guangming Yuan ◽  
Gonggang Liu ◽  
Xiang Zhang ◽  
...  

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Jinlin Yang ◽  
Xiaowei Wang ◽  
Wenrui Dai ◽  
Xu Lian ◽  
Xinhang Cui ◽  
...  

Highlights Hard-carbon anode dominated with ultra-micropores (< 0.5 nm) was synthesized for sodium-ion batteries via a molten diffusion–carbonization method. The ultra-micropores dominated carbon anode displays an enhanced capacity, which originates from the extra sodium-ion storage sites of the designed ultra-micropores. The thick electrode (~ 19 mg cm−2) with a high areal capacity of 6.14 mAh cm−2 displays an ultrahigh cycling stability and an outstanding low-temperature performance. Abstract Pore structure of hard carbon has a fundamental influence on the electrochemical properties in sodium-ion batteries (SIBs). Ultra-micropores (< 0.5 nm) of hard carbon can function as ionic sieves to reduce the diffusion of slovated Na+ but allow the entrance of naked Na+ into the pores, which can reduce the interficial contact between the electrolyte and the inner pores without sacrificing the fast diffusion kinetics. Herein, a molten diffusion–carbonization method is proposed to transform the micropores (> 1 nm) inside carbon into ultra-micropores (< 0.5 nm). Consequently, the designed carbon anode displays an enhanced capacity of 346 mAh g−1 at 30 mA g−1 with a high ICE value of ~ 80.6% and most of the capacity (~ 90%) is below 1 V. Moreover, the high-loading electrode (~ 19 mg cm−2) exhibits a good temperature endurance with a high areal capacity of 6.14 mAh cm−2 at 25 °C and 5.32 mAh cm−2 at − 20 °C. Based on the in situ X-ray diffraction and ex situ solid-state nuclear magnetic resonance results, the designed ultra-micropores provide the extra Na+ storage sites, which mainly contributes to the enhanced capacity. This proposed strategy shows a good potential for the development of high-performance SIBs.


2021 ◽  
Author(s):  
Mathew J Thompson ◽  
Qingbing Xia ◽  
Zhe Hu ◽  
Xiu Song Zhao

This paper presents a review of research progress for biomass-derived hard carbon materials for sodium-ion storage. It provides an in-depth analysis of hard carbon anode materials obtained from biomass with...


Author(s):  
Xiaoyang Chen ◽  
Youlong Fang ◽  
Jiyu Tian ◽  
Haiyan Lu ◽  
Xinping Ai ◽  
...  

2019 ◽  
Vol 321 ◽  
pp. 134624 ◽  
Author(s):  
Huijun Li ◽  
Siyue Hao ◽  
Zhen Tian ◽  
Zhenxin Zhao ◽  
Xiaomin Wang

2019 ◽  
Vol 7 (22) ◽  
pp. 18554-18565 ◽  
Author(s):  
Hua Wang ◽  
Fei Sun ◽  
Zhibin Qu ◽  
Kunfang Wang ◽  
Lijie Wang ◽  
...  

2020 ◽  
Vol 55 (14) ◽  
pp. 5994-6004
Author(s):  
Yujie Zou ◽  
Hang Li ◽  
Kaiyan Qin ◽  
Yang Xia ◽  
Lin Lin ◽  
...  

Carbon ◽  
2013 ◽  
Vol 55 ◽  
pp. 328-334 ◽  
Author(s):  
Zhaohui Wang ◽  
Long Qie ◽  
Lixia Yuan ◽  
Wuxing Zhang ◽  
Xianluo Hu ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (50) ◽  
pp. 28953-28960 ◽  
Author(s):  
Hongliang Li ◽  
Mingxiang Deng ◽  
Hongshuai Hou ◽  
Xiaobo Ji

The natural stibnite mineral modified with graphite provides a reference for the development of natural mineral as first-hand materials in energy storage and a new approach to improve natural stibnite mineral composites as anode in SIBs.


2020 ◽  
Vol 32 (21) ◽  
pp. 2000447 ◽  
Author(s):  
Ji‐Li Xia ◽  
Dong Yan ◽  
Li‐Ping Guo ◽  
Xiao‐Ling Dong ◽  
Wen‐Cui Li ◽  
...  

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