Electrochemical Capacitance of Ni-Doped Metal Organic Framework and Reduced Graphene Oxide Composites: More than the Sum of Its Parts

2015 ◽  
Vol 7 (6) ◽  
pp. 3655-3664 ◽  
Author(s):  
Parama Chakraborty Banerjee ◽  
Derrek E. Lobo ◽  
Rick Middag ◽  
Woo Kan Ng ◽  
Mahdokht E. Shaibani ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Metal Organic Framework ◽  
Electrochemical Capacitance ◽  
Reduced Graphene ◽  
Metal Organic ◽  
Oxide Composites ◽  
Organic Framework

scholarly journals Poly(3,4-ethylenedioxythiophene)-reduced graphene oxide/copper-based metal-organic frameworks as a high-performance symmetrical supercapacitor device

2021 ◽  
Author(s):  
Dharshini Mohanadas ◽  
Muhammad Amirul Aizat Mohd Abdah ◽  
Nur Hawa Nabilah Azman ◽  
Thahira B.S.A. Ravoof ◽  
Yusran Sulaiman
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
High Performance ◽  
Metal Organic Framework ◽  
Specific Power ◽  
X Ray Diffraction ◽  
Reduced Graphene ◽  
Metal Organic ◽  
Energy Storage Material ◽  
Organic Framework

Abstract A novel poly(3,4-ethylenedioxythiophene)-reduced graphene oxide/copper-based metal-organic framework (PrGO/HKUST-1) has been successfully fabricated by incorporating electrochemically synthesized poly(3,4-ethylenedioxythiophene)-reduced graphene oxide (PrGO) and hydrothermally synthesized copper-based metal-organic framework (HKUST-1). The field emission scanning microscopy (FESEM) and elemental mapping analysis revealed an even distribution of poly(3,4-ethylenedioxythiophene) (PEDOT), reduced graphene oxide (rGO) and HKUST-1. The crystalline structure and vibration modes of PrGO/HKUST-1 was validated utilizing X-ray diffraction (XRD) as well as Raman spectroscopy, respectively. A remarkable specific capacitance (360.5 F/g) was obtained for PrGO/HKUST-1 compared to HKUST-1 (103.1 F/g), PrGO (98.5 F/g) and PEDOT (50.8 F/g) using KCl/PVA as a gel electrolyte. Moreover, PrGO/HKUST-1 composite with the longest charge/discharge time displayed excellent specific energy (21.0 Wh/kg), specific power (479.7 W/kg) and outstanding cycle life (95.5%) over 4000 cycles. Thus, the PrGO/HKUST-1 can be recognized as a promising energy storage material.

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