1D Tube, 2D Layer, and 3D Framework Derived from a New Series of Metal(II)−5-Aminodiacetic Isophthalate Coordination Polymers

Reactions of Zn(NO3)2·6H2O with 1,2,4-triazole (Htrz) and 1,3,5-benzenetricarboxylic acid (H3BTC) or 5-sulfoisophthalic acid (5-H3SIP) afforded two coordination polymers, {[Zn5(μ3-OH)2(trz)2(BTC)2(DMF)2]·x(solvent)}n (1) and {[Zn7(trz)8(5-SIP)2(H2O)4]·4(H2O)}n (2). Compound 1 has pentanuclear [Zn5(μ3-OH)2] clusters, which are linked by the triazolate ligands to give a 2D layer. The 2D layer is further bridged by BTC3− ligands to form a 3D framework. The 3D framework of 1 has 1D channels filled by solvent molecules. Desolvated 1 shows a moderate CO2 uptake and high CO2/CH4 and CO2/N2 adsorption selectivities due to its carboxylate oxygen decorated pore environment. Compound 2 contains a rare 3D zinc-triazolate framework constructed from a pentanuclear [Zn5(trz)8] cluster wherein the five zinc atoms are arranged linearly. The 3D zinc-triazolate substructure has 1D open channels filled by 5-SIP3− ligands, which interact with the zinc-triazolate framework through Zn–O bonds, leading to a non-porous 3D structure of 2. Introduction of BTC3− into the zinc-triazolate system gave the porous structure of 1. While a variation of BTC3−, 5-SIP3− was introduced into the zinc-triazolate system yielding a non-porous structure of 2, demonstrating that the secondary ligands play an important role in the formation of the final structures.

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Hydrothermal Syntheses, Crystal Structures, and Luminescent Properties of Two MnII Coordination Polymers: From Two-Fold Interpenetrated pcu Topological Net to Polycatenated 2D+2D→3D Framework

Australian Journal of Chemistry ◽

10.1071/ch14092 ◽

2015 ◽

Vol 68 (2) ◽

pp. 322 ◽

Cited By ~ 2

Author(s):

Wenlong Liu ◽

Mengqiang Wu ◽

Xueying Wang ◽

Wei Wang ◽

Dayu Liu ◽

...

Keyword(s):

Dicarboxylic Acid ◽

Coordination Polymers ◽

Self Assembly ◽

Room Temperature ◽

Luminescent Properties ◽

The Self ◽

X Ray Diffraction ◽

X Ray ◽

3D Framework ◽

Dimethyl Benzene

Using a hydrothermal synthesis, the self-assembly of MnII ions and 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene with two dicarboxylate ligands, 2-nitrobenzene-1,4-dicarboxylic acid (2-H2ata) and 5-methylbenzene-1,3-dicarboxylic acid (5-CH3-H2ip) constructed two interesting coordination polymers: [Mn(2-ata)(bimb)]n (1) and {[Mn(5-CH3-ip)(bimb)1.5]·2H2O}n (2), where bimb refers to 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene. Their structures were determined by single-crystal X-ray diffraction, elemental analysis, and infrared spectroscopy. Complex 1 exhibits a 2-fold interpenetrated pcu net. Complex 2 shows an unusual polycatenated 2D+2D→3D framework. In addition, the solid-state photoluminescent properties of 1 and 2 were investigated at room temperature.

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Coordination polymers of the bis(imidazole) ligand modulated by dicarboxylate ligands: From 2D layer to 3D framework

Polyhedron ◽

10.1016/j.poly.2015.05.046 ◽

2015 ◽

Vol 98 ◽

pp. 40-46 ◽

Cited By ~ 6

Author(s):

Fei-Fei Yang ◽

Xiao-Fang Wang ◽

Xiao-Yang Yu ◽

Yu-Hui Luo ◽

Hong Zhang

Keyword(s):

Coordination Polymers ◽

Imidazole Ligand ◽

3D Framework

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Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework

Crystal Growth & Design ◽

10.1021/acs.cgd.6b00429 ◽

2016 ◽

Vol 16 (9) ◽

pp. 4886-4896 ◽

Cited By ~ 17

Author(s):

Kong-Qiu Hu ◽

Liu-Zheng Zhu ◽

Cong-Zhi Wang ◽

Lei Mei ◽

Yun-Hai Liu ◽

...

Keyword(s):

Coordination Polymers ◽

1D Chain ◽

3D Framework

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Organic carboxylate ligands tuned structural variations of two new Cd(II) coordination polymers: From 2D layer to 3D framework

Journal of Molecular Structure ◽

10.1016/j.molstruc.2015.07.013 ◽

2015 ◽

Vol 1100 ◽

pp. 1-5 ◽

Cited By ~ 2

Author(s):

Chang-Wei Lv ◽

Jing Li ◽

Yan-Wu Liu ◽

Xia Li ◽

Zhi Yuan

Keyword(s):

Coordination Polymers ◽

Structural Variations ◽

Carboxylate Ligands ◽

3D Framework

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Assembly of [CunIn]-based coordination polymers from cracking the 3D framework of bulk CuI via flexible N-heterocyclic ligands

Dalton Transactions ◽

10.1039/b908697h ◽

2009 ◽

pp. 8567 ◽

Cited By ~ 89

Author(s):

Ling-Ling Li ◽

Hong-Xi Li ◽

Zhi-Gang Ren ◽

Dong Liu ◽

Yang Chen ◽

...

Keyword(s):

Coordination Polymers ◽

Heterocyclic Ligands ◽

3D Framework

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New coordination polymers from 1D chain, 2D layer to 3D framework constructed from 1,2-phenylenediacetic acid and 1,3-bis(4-pyridyl)propane flexible ligands

Journal of Solid State Chemistry ◽

10.1016/j.jssc.2011.04.002 ◽

2011 ◽

Vol 184 (6) ◽

pp. 1387-1392 ◽

Cited By ~ 27

Author(s):

Ling-Yun Xin ◽

Guang-Zhen Liu ◽

Li-Ya Wang

Keyword(s):

Coordination Polymers ◽

1D Chain ◽

Flexible Ligands ◽

3D Framework

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Effect of Charge on the Structures of Zn(II) Coordination Polymers with Triazole-carboxylate Ligands: Syntheses, Structures, and Luminescent Properties

Crystals ◽

10.3390/cryst8080312 ◽

2018 ◽

Vol 8 (8) ◽

pp. 312 ◽

Cited By ~ 2

Author(s):

Shaobin Miao ◽

Xiaojuan Sun ◽

Kexin Wang ◽

Chunying Xu ◽

Zhaohao Li ◽

...

Keyword(s):

Coordination Polymers ◽

Positive Charge ◽

Luminescent Properties ◽

Chain Structure ◽

Double Layers ◽

Carboxylate Ligands ◽

Benzenedicarboxylic Acid ◽

1D Chain ◽

3D Framework ◽

State Luminescence

Three new Zn(II) coordination polymers, {[Zn(L1)2(H2O)2]·4H2O}n (1), {[Zn(L2)(H2O)2]·0.5H2O}n (2), and {[Zn1.5(L1)(o-bdc)(H2O)]·0.5H2O}n (3) (HL1 = 3,5-di(1,2,4-triazol-1-yl)benzoic acid, H2L2 = 5-(triazol-1-yl)isophthalic acid, o-H2bdc = 1,2-benzenedicarboxylic acid), were successfully synthesized and characterized. Compound 1 exhibits 1D chain structure containing [Zn(L1)2] unit. Compound 2 shows a 2D plane with the ratio of Zn:L2 was 1:1 since L2 can match the positive charge of Zn(II). When L1 and o-bdc2– were presented together, Zn(II) centers are linked by L1 to form 2D double layers, then o-bdc2– further connected the adjacent layers to generate final 3D framework of 3. The ligand charges may play key roles in tuning the frameworks of compounds 1–3. The solid state luminescence of compounds 1–3 and all ligands have been investigated here.

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