An experiment on the molar solubility and solubility product of barium nitrate

1989 ◽  
Vol 66 (6) ◽  
pp. 515 ◽  
Author(s):  
Betty Wruck ◽  
Jesse Reinstein
Keyword(s):  
Solubility Product ◽  
Barium Nitrate ◽  
Molar Solubility

Solubility and Complex-Ion Equilibria

2021 ◽  
pp. 313-324
Author(s):  
Christopher O. Oriakhi
Keyword(s):  
Metal Complexes ◽  
Solubility Product ◽  
Formation Constants ◽  
Aqueous Systems ◽  
Complex Ions ◽  
Ionic Compounds ◽  
Molar Solubility ◽  
Solubility Product Constant ◽  
Complex Ion

Solubility and Complex-Ion Equilibria broadens the previous chapter’s coverage of equilibria to include aqueous systems containing two or more solutes of slightly soluble ionic compounds and the formation of metal complexes in solution. Solubility equilibria which allow quantitative predictions of how much of a compound will dissolve under given conditions are covered. The meaning of the solubility product constant (K sp) and how to calculate it from molar solubility values is presented. Also discussed is determination of molar solubility from K sp. Calculations demonstrate how to predict the formation of a precipitate by comparing the ion product or solubility quotient (Q) with K sp. Formation constants of complex ions and calculations involving complex ion equilibria are explained.

Revised aqueous solubility product constants and a simple laboratory synthesis of the Pb(II) hydroxycarbonates: Plumbonacrite and hydrocerussite

2017 ◽  
Vol 51 (4) ◽  
pp. 315-328
Author(s):  
Arturo Mendoza-Flores ◽  
Mario Villalobos ◽  
Teresa Pi-Puig ◽  
Nadia Valentina Martínez-Villegas
Keyword(s):  
Solubility Product ◽  
Aqueous Solubility ◽  
Laboratory Synthesis

scholarly journals Solubility Product of Vanadinite Pb5(VO4)3Cl at 25 °C—A Comprehensive Approach to Incongruent Dissolution Modeling

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 135
Author(s):  
Justyna Topolska ◽  
Bartosz Puzio ◽  
Olaf Borkiewicz ◽  
Julia Sordyl ◽  
Maciej Manecki
Keyword(s):  
Nuclear Waste ◽  
Solubility Product ◽  
Geochemical Modeling ◽  
Incongruent Dissolution ◽  
Mineral Solubility ◽  
Actual Application ◽  
Universal Approach ◽  
Solubility Constant ◽  
First Time

Although vanadinite (Pb5(VO4)3Cl) occurs in abundance in various terrestrial geochemical systems of natural and anthropogenic origin and is seriously considered as a potential nuclear waste sequestering agent, its actual application is severely limited by a lack of understanding of its basic thermodynamic parameters. In this regard, the greatest challenge is posed by its incongruent dissolution, which is a pivotal hurdle for effective geochemical modeling. Our paper presents an universal approach for geochemical computing of systems undergoing incongruent dissolution which, along with unique, long-term experiments on vanadinites’ stability, allowed us to determine the mineral solubility constant. The dissolution experiments were carried out at pH = 3.5 for 12 years. Vanadinite has dissolved incongruently, continuously re-precipitating into chervetite (Pb2V2O7) with the two minerals remaining in mutual equilibrium until termination of the experiments. The empirically derived solubility constant Ksp,V,298 = 10–91.89 ± 0.05 of vanadinite was determined for the first time. The proposed modeling method is versatile and can be adopted to other mineral systems undergoing incongruent dissolution.

Solubility product and the silver-ammonia halides.

1947 ◽  
Vol 24 (5) ◽  
pp. 236 ◽  
Author(s):  
Kelso B. Morris
Keyword(s):  
Solubility Product

Solubility of barium nitrate in highly active raffinates under evaporation conditions

Atomic Energy ◽  
1996 ◽  
Vol 81 (4) ◽  
pp. 751-753 ◽  
Author(s):  
Yu. P. Zhirnov ◽  
L. V. Moiseenko
Keyword(s):  
Barium Nitrate ◽  
Highly Active

Solution Properties of Tetraalkylammonium Halide and Alkali-Metal Halide Ion Pairs. The Relationship Between Dissociation Constants and Solubility Products

1987 ◽  
Vol 40 (7) ◽  
pp. 1201 ◽  
Author(s):  
W Mizerski ◽  
MK Kalinowski
Keyword(s):  
Alkali Metal ◽  
Solubility Product ◽  
Dissociation Constants ◽  
Ion Pairs ◽  
Empirical Relation ◽  
Alkali Metal Halide ◽  
Alkali Metal Cations ◽  
Solubility Products ◽  
The Relationship ◽  
Dissociation Constant Kd

An empirical relation describing the effect of solvent on the dissociation constant ( Kd ) of ion pairs is described. An equation of the form pKd = apKso + bD-1 + c ( Kso and D stand for the solubility product of a given salt and for the electric permittivity of a solvent, respectively) has been tested with 13 sets of experimental data for salts containing tetraalkylammonium and alkali-metal cations. A successful correlation was obtained in 100% of the cases considered.

The Solubility Product of Barium Chromate at Various Ionic Strengths

1943 ◽  
Vol 65 (5) ◽  
pp. 971-973 ◽  
Author(s):  
George L. Beyer ◽  
William Rieman
Keyword(s):  
Solubility Product ◽  
Barium Chromate

The Solubility of Nitrogen and Nitrides in Ternary Liquid Iron Alloys. The Limits of the 'Solubility Product' Concept

2003 ◽  
Vol 414-415 ◽  
pp. 491-0 ◽  
Author(s):  
Maziar Sahba Yaghmaee ◽  
György Kaptay
Keyword(s):  
Liquid Iron ◽  
Solubility Product ◽  
Iron Alloys ◽  
Product Concept
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