Solution Properties of Tetraalkylammonium Halide and Alkali-Metal Halide Ion Pairs. The Relationship Between Dissociation Constants and Solubility Products
Keyword(s):
An empirical relation describing the effect of solvent on the dissociation constant ( Kd ) of ion pairs is described. An equation of the form pKd = apKso + bD-1 + c ( Kso and D stand for the solubility product of a given salt and for the electric permittivity of a solvent, respectively) has been tested with 13 sets of experimental data for salts containing tetraalkylammonium and alkali-metal cations. A successful correlation was obtained in 100% of the cases considered.
1974 ◽
Vol 52
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pp. 3259-3268
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1967 ◽
Vol 45
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pp. 2411-2418
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1967 ◽
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pp. 1325-1332
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1970 ◽
Vol 43
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pp. 3689-3694
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1972 ◽
Vol 12
(4)
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pp. 596-598
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1980 ◽
Vol 73
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pp. 75-79
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2016 ◽
Vol 28
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pp. 608-615
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