Cation Effects on the Layer Structure of Biogenic Mn-Oxides

2010 ◽  
Vol 44 (12) ◽  
pp. 4465-4471 ◽  
Author(s):  
Mengqiang Zhu ◽  
Matthew Ginder-Vogel ◽  
Sanjai J. Parikh ◽  
Xiong-Han Feng ◽  
Donald L. Sparks
2010 ◽  
Vol 44 (12) ◽  
pp. 4472-4478 ◽  
Author(s):  
Mengqiang Zhu ◽  
Matthew Ginder-Vogel ◽  
Donald L. Sparks

Biomolecules ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 941
Author(s):  
Van Khanh Nguyen ◽  
Myung-Gyu Ha ◽  
Ho Young Kang ◽  
Dinh Duc Nguyen

Manganese-oxidizing bacteria have been widely investigated for bioremediation of Mn-contaminated water sources and for production of biogenic Mn oxides that have extensive applications in environmental remediation. In this study, a total of 5 Mn-resistant bacteria were isolated from river water and investigated for Mn removal. Among them, Ochrobactrum sp. NDMn-6 exhibited the highest Mn removal efficiency (99.1%). The final precipitates produced by this strain were defined as a mixture of Mn2O3, MnO2, and MnCO3. Optimal Mn-removal performance by strain NDMn-6 was obtained at a temperature range of 25–30 °C and the salinity of 0.1–0.5%. More interestingly, strain NDMn-6 could be resistant to salinities of up to 5%, revealing that this strain could be possibly applied for Mn remediation of high salinity regions or industrial saline wastewaters. This study also revealed the potential of self-detoxification mechanisms, wherein river water contaminated with Mn could be cleaned by indigenous bacteria through an appropriate biostimulation scheme.


2020 ◽  
Vol 710 ◽  
pp. 136386 ◽  
Author(s):  
Sandeepraja Dangeti ◽  
Joyce M. McBeth ◽  
Babak Roshani ◽  
Jonathan M. Vyskocil ◽  
Brian Rindall ◽  
...  

2007 ◽  
Vol 20-21 ◽  
pp. 607-610
Author(s):  
Keiko Sasaki ◽  
M. Matsuda ◽  
T. Urata ◽  
Tsuyoshi Hirajima ◽  
H. Konno

Sorption of Co(II) on the biogenic Mn oxide produced by a Paraconiothyrium sp.-like strain was investigated. The biogenic Mn oxide, which was characterized to be poorly crystalline birnessite (Na4Mn(III) 6Mn(IV) 8O27 ·9H2O) bearing Mn(III) and Mn(IV) in the structure, showed approximately 6.0-fold higher efficiency for Co(II) sorption than a synthetic Mn oxide. XP-spectra of Co 2p for the biogenic and synthetic Mn oxides after Co(II) sorption indicate that Co was immobilized as Co(III) on the surface of Mn oxides, clearly suggesting that redox reaction occurs between Co(II) ions and each Mn oxides. The Co(II) ions would be initially sorbed on the vacant sites of the surface of biogenic Mn oxide, and then oxidized to Co(III) by neighbor Mn(III/IV) atoms to release Mn(II). For the synthetic Mn oxide, release of Mn(II) was negligibly small because the oxidant is only Mn(IV) in ramsdellite (γ-MnO2). The Mn(II) release from the biogenic Mn oxide during Co(II) adsorption would be not only from weakly bounded Mn(II), but also from redox reaction between Mn(III/IV) and Co(II) ions.


PLoS ONE ◽  
2015 ◽  
Vol 10 (6) ◽  
pp. e0128863 ◽  
Author(s):  
Magnus Ivarsson ◽  
Curt Broman ◽  
Håkan Gustafsson ◽  
Nils G. Holm
Keyword(s):  

2010 ◽  
Vol 74 (11) ◽  
pp. 3232-3245 ◽  
Author(s):  
Xiong Han Feng ◽  
Mengqiang Zhu ◽  
Matthew Ginder-Vogel ◽  
Chaoying Ni ◽  
Sanjai J. Parikh ◽  
...  

2014 ◽  
Vol 11 (5) ◽  
pp. 7273-7290 ◽  
Author(s):  
H. Wang ◽  
X. Pan

Abstract. Microbially mediated oxidation of Mn(II) to Mn oxides have been demonstrated in previous studies, however, the mechanisms of bacteria how to dissolve and oxidize using a solid Mn(II) origin are poorly understood. In this study, we examined the role of extracellular polymeric substances (EPS) from P. putida strain MnB1 in enhancing dissolution of natural rhodochrosite. The results showed that P. putida strain MnB1 cell can effectively dissolve and oxidize natural rhodochrosite to generate Mn oxides, and EPS were found to play an important role in increasing dissolution of natural rhodochrosite. Compared with EPS-free treatment, dissolution rate of natural rhodochrosite in the presence of bacterial EPS was significantly increased with decreasing initial pH and increasing EPS concentration, ionic strength and rhodochrosite dosage (p < 0.05). The fourier-transform infrared spectroscopy (FTIR) analysis implies that the functional groups like N-H, C=O and C-H in EPS contributed to the dissolution of natural rhodochrosite. This study is helpful for understanding the mechanisms of the formation of biogenic Mn oxides using a solid Mn(II) origin.


Sign in / Sign up

Export Citation Format

Share Document