Water Oxidation Catalysis: Influence of Anionic Ligands upon the Redox Properties and Catalytic Performance of Mononuclear Ruthenium Complexes

2012 ◽  
Vol 51 (6) ◽  
pp. 3388-3398 ◽  
Author(s):  
Lianpeng Tong ◽  
Ying Wang ◽  
Lele Duan ◽  
Yunhua Xu ◽  
Xiao Cheng ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Ruthenium Complexes ◽  
Catalytic Performance ◽  
Redox Properties ◽  
Oxidation Catalysis ◽  
Anionic Ligands ◽  
Water Oxidation Catalysis

Syntheses and Redox Properties of Bis(hydroxoruthenium) Complexes with Quinone and Bipyridine Ligands. Water-Oxidation Catalysis

2001 ◽  
Vol 40 (2) ◽  
pp. 329-337 ◽  
Author(s):  
Tohru Wada ◽  
Kiyoshi Tsuge ◽  
Koji Tanaka
Keyword(s):  
Water Oxidation ◽  
Redox Properties ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis

scholarly journals Cooperative effects in homogenous water oxidation catalysis by mononuclear ruthenium complexes

2014 ◽  
Vol 43 (18) ◽  
pp. 6819-6827 ◽  
Author(s):  
Yanyan Mulyana ◽  
F. Richard Keene ◽  
Leone Spiccia
Keyword(s):  
Water Oxidation ◽  
Ruthenium Complexes ◽  
Oxidation Catalysis ◽  
Cooperative Effects ◽  
Water Oxidation Catalysis

scholarly journals Mechanisms of Photoisomerization and Water Oxidation Catalysis of Ruthenium(II) Aquo Complexes

2021 ◽  
Author(s):  
Yuta Tsubonouchi ◽  
Eman A. Mohamed ◽  
Zaki N. Zahran ◽  
Masayuki Yagi
Keyword(s):  
Physicochemical Properties ◽  
Water Oxidation ◽  
Recent Progress ◽  
Artificial Photosynthesis ◽  
Ruthenium Complexes ◽  
Oxidation Catalysis ◽  
Oxidation Catalysts ◽  
Water Oxidation Catalysis ◽  
Molecular Catalysts ◽  
Insight Into

Polypyridyl ruthenium(II) complexes have been widely researched as promising functional molecules. We have found unique photoisomerization reactions of polypyridyl ruthenium(II) aquo complexes. Recently we have attempted to provide insight into the mechanism of the photoisomerization of the complexes and distinguish between the distal−/proximal-isomers in their physicochemical properties and functions. Moreover, polypyridyl ruthenium(II) aquo complexes have been intensively studied as active water oxidation catalysts (WOCs) which are indispensable for artificial photosynthesis. The catalytic aspect and mechanism of water oxidation by the distal-/proximal-isomers of polypyridyl ruthenium(II) aquo complexes have been investigated to provide the guided thought to develop more efficient molecular catalysts for water oxidation. The recent progress on the photoisomerization and water oxidation of polypyridyl ruthenium(II) aquo complexes in our group are reviewed to understand the properties and functions of ruthenium complexes.

Proton-coupled redox properties and water oxidation catalysis of an aqua-coordinated (µ-oxo)diruthenium(III) complex

2021 ◽  
Vol 514 ◽  
pp. 120007
Author(s):  
Bo-Hong Luo ◽  
Ya-Jie Ren ◽  
Hai-Bin Cui ◽  
Qiang Fu ◽  
Hao-Dong Jiang ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Redox Properties ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis

Efficient Light-Driven Water Oxidation Catalysis by Dinuclear Ruthenium Complexes

ChemSusChem ◽  
2015 ◽  
Vol 8 (21) ◽  
pp. 3688-3696 ◽  
Author(s):  
Serena Berardi ◽  
Laia Francàs ◽  
Sven Neudeck ◽  
Somnath Maji ◽  
Jordi Benet-Buchholz ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Ruthenium Complexes ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis ◽  
Dinuclear Ruthenium ◽  
Dinuclear Ruthenium Complexes

Toward Controlling Water Oxidation Catalysis: Tunable Activity of Ruthenium Complexes with Axial Imidazole/DMSO Ligands

2012 ◽  
Vol 134 (45) ◽  
pp. 18868-18880 ◽  
Author(s):  
Lei Wang ◽  
Lele Duan ◽  
Beverly Stewart ◽  
Maoping Pu ◽  
Jianhui Liu ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Ruthenium Complexes ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis

Stoichiometric Photoisomerization of Mononuclear Ruthenium(II) Monoaquo Complexes Controlling Redox Properties and Water Oxidation Catalysis

2011 ◽  
Vol 133 (23) ◽  
pp. 8846-8849 ◽  
Author(s):  
Hirosato Yamazaki ◽  
Tomoya Hakamata ◽  
Manabu Komi ◽  
Masayuki Yagi
Keyword(s):  
Water Oxidation ◽  
Redox Properties ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis

scholarly journals Influence of chloro substituent on photoisomerization, redox reactions and water oxidation catalysis of mononuclear ruthenium complexes

2015 ◽  
Vol 313 ◽  
pp. 117-125 ◽  
Author(s):  
Kosuke Takahashi ◽  
Xiaohong Zhang ◽  
Masanari Hirahara ◽  
Taisei Sato ◽  
Kenji Saito ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Redox Reactions ◽  
Ruthenium Complexes ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis

Competitive oxygen-18 kinetic isotope effects expose O–O bond formation in water oxidation catalysis by monomeric and dimeric ruthenium complexes

2014 ◽  
Vol 5 (3) ◽  
pp. 1141-1152 ◽  
Author(s):  
Alfredo M. Angeles-Boza ◽  
Mehmed Z. Ertem ◽  
Rupam Sarma ◽  
Christian H. Ibañez ◽  
Somnath Maji ◽  
...  
Keyword(s):  
Water Oxidation ◽  
Isotope Effects ◽  
Bond Formation ◽  
Transition States ◽  
Ruthenium Complexes ◽  
Kinetic Isotope Effects ◽  
Oxidation Catalysis ◽  
Kinetic Isotope ◽  
Water Oxidation Catalysis

Competitive 18O KIEs on water oxidation catalysis provide a probe of transition states for O–O bond formation.

scholarly journals The search for intermediates formed during water-oxidation catalysis

2021 ◽  
Vol 1 (2) ◽  
pp. 248-250
Author(s):  
Rosalie K. Hocking
Keyword(s):  
Water Oxidation ◽  
Oxidation Catalysis ◽  
Water Oxidation Catalysis
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