Reactions of Some Transition Metal Cyano Complexes with Molecular Hydrogen at Elevated Temperatures

1965 ◽  
Vol 4 (3) ◽  
pp. 365-368 ◽  
Author(s):  
Jin Sun Yoo ◽  
Ernest Griswold ◽  
Jacob Kleinberg
Keyword(s):  
Transition Metal ◽  
Molecular Hydrogen ◽  
Elevated Temperatures ◽  
Cyano Complexes

Reactions of potassium hexacyanochromate(III) and some transition metal cyanonitrosyls with molecular hydrogen at elevated temperatures

1967 ◽  
Vol 6 (10) ◽  
pp. 1849-1854 ◽  
Author(s):  
David F. Banks ◽  
Jacob Kleinberg
Keyword(s):  
Transition Metal ◽  
Molecular Hydrogen ◽  
Elevated Temperatures

Activation of molecular hydrogen by transition-metal complexes

1981 ◽  
Vol 30 (3) ◽  
pp. 361-365 ◽  
Author(s):  
A. S. Berenblyum ◽  
T. V. Turkova ◽  
I. I. Moiseev
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Molecular Hydrogen

Transition metal-cyano complexes in molten potassium cyanide

1969 ◽  
Vol 8 (11) ◽  
pp. 2499-2503 ◽  
Author(s):  
Jesse G. Reinstein ◽  
Ernest Griswold ◽  
Jacob Kleinbert
Keyword(s):  
Transition Metal ◽  
Potassium Cyanide ◽  
Cyano Complexes

Carbon-13/carbon-12 isotope effects on nitrogen-15 chemical shielding in some diamagnetic cyano complexes

1982 ◽  
Vol 60 (17) ◽  
pp. 2194-2197 ◽  
Author(s):  
Roderick E. Wasylishen
Keyword(s):  
Transition Metal ◽  
High Field ◽  
Chemical Shifts ◽  
Isotope Effects ◽  
Chemical Shielding ◽  
Cyanide Ion ◽  
Theoretical Formulation ◽  
Metal Cyanides ◽  
Shielding Constants ◽  
Cyano Complexes

Carbon-13/carbon-12 isotope-induced 15N chemical shifts of 0.06 to 0.10 ppm have been observed for the cyanide ion and several transition metal cyanides. In each case, the 15N resonance of the 13C labelled isotopomers is to high field of that in the corresponding carbon-12 species. The sensitivity of the 15N and 13C shielding constants in the cyanide ion to small changes in the CN bond length are evaluated using the theoretical formulation of Jameson: (∂σ(15N)/∂r)e = −872 ± 160 ppm/Å and (∂σ(13C)/∂r)e = −473 ± 90 ppm/Å. Nitrogen-15 chemical shifts in the metal complexes exhibit basically the same behaviour as do the 13C chemical shifts in these same complexes.

ChemInform Abstract: TRANSITION METAL CYANO COMPLEXES. I. OCTACYANONIOBATES(III), -NIOBATES(IV), -MOLYBDATES(V), AND -TUNGSTATES(V)

1976 ◽  
Vol 7 (10) ◽  
pp. no-no
Author(s):  
PATRICK M. KIERNAN ◽  
WILLIAM P. GRIFFITH
Keyword(s):  
Transition Metal ◽  
Cyano Complexes

Activation and Functionalization of Dinitrogen in the Presence of Molecular Hydrogen Promoted by Transition Metal Complexes

2020 ◽  
Vol 2020 (15-16) ◽  
pp. 1383-1395
Author(s):  
Chinnappan Sivasankar ◽  
Packirisamy Kuzhalmozhi Madarasi ◽  
Masilamani Tamizmani
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Molecular Hydrogen
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