Lanthanide (Eu3+, Tb3+)/β-Diketone Modified Mesoporous SBA-15/Organic Polymer Hybrids: Chemically Bonded Construction, Physical Characterization, and Photophysical Properties

2009 ◽  
Vol 48 (17) ◽  
pp. 8276-8285 ◽  
Author(s):  
Ya-Juan Li ◽  
Bing Yan
Keyword(s):  
Photophysical Properties ◽  
Physical Characterization ◽  
Organic Polymer ◽  
Polymer Hybrids

scholarly journals The Photostability of Novel Boron Hydride Blue Emitters in Solution and Polystyrene Matrix

Materials ◽  
2021 ◽  
Vol 14 (3) ◽  
pp. 589
Author(s):  
Jakub Ševčík ◽  
Pavel Urbánek ◽  
Barbora Hanulíková ◽  
Tereza Čapková ◽  
Michal Urbánek ◽  
...  
Keyword(s):  
Thin Films ◽  
Photophysical Properties ◽  
Inorganic Compounds ◽  
Solid Polymer ◽  
Organic Polymer ◽  
Quantum Yields ◽  
Boron Hydride ◽  
Polystyrene Matrix ◽  
Blue Emitters ◽  
Solvent Blends

In recent work, the boron hydride anti-B18H22 was announced in the literature as a new laser dye, and, along with several of its derivatives, its solutions are capable of delivering blue luminescence with quantum yields of unity. However, as a dopant in solid polymer films, its luminescent efficiencies reduce dramatically. Clarification of underlying detrimental effects is crucial for any application and, thus, this contribution makes the initial steps in the use of these inorganic compounds in electrooptical devices based on organic polymer thin films. The photoluminescence behavior of the highly luminescent boron hydrides, anti-B18H22 and 3,3′,4,4′-Et4-anti-B18H18, were therefore investigated. The quantum yields of luminescence and photostabilities of both compounds were studied in different solvents and as polymer-solvent blends. The photophysical properties of both boranes are evaluated and discussed in terms of their solvent-solute interactions using photoluminescence (PL) and NMR spectroscopies. The UV degradability of prepared thin films was studied by fluorimetric measurement. The effect of the surrounding atmosphere, dopant concentration and the molecular structure were assessed.

Design on polarization distribution in all-organic polymer hybrids for high density energy storage

2020 ◽  
Vol 394 ◽  
pp. 125052 ◽  
Author(s):  
Wentian Wei ◽  
Chen Huang ◽  
Lingyu Zhang ◽  
Yao Wang ◽  
Meiyu Xu ◽  
...  
Keyword(s):  
Energy Storage ◽  
High Density ◽  
Organic Polymer ◽  
Polarization Distribution ◽  
Polymer Hybrids
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