Proton-Induced Tuning of Electrochemical and Photophysical Properties in Mononuclear and Dinuclear Ruthenium Complexes Containing 2,2‘-Bis(benzimidazol-2-yl)-4,4‘-bipyridine:  Synthesis, Molecular Structure, and Mixed-Valence State and Excited-State Properties†

Five diruthenium complexes in the mixed-valence state of Ru(ii)–Ru(iii), triply bridged by halogeno and methoxido ligands, were newly synthesized and compared.

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Ground and excited state dynamics of new dinuclear ruthenium complexes: NMR, UV–Vis, IR, electrochemical, photophysical characterization, and theoretical study of Ru(bpy)2(μ-dpp)Ru(CN–X)4n+ complexes

Inorganica Chimica Acta ◽

10.1016/j.ica.2012.01.024 ◽

2012 ◽

Vol 387 ◽

pp. 261-270

Author(s):

Margit Kovács ◽

Gábor Szalontai ◽

György Lendvay ◽

Günter Grampp ◽

Attila Horváth

Keyword(s):

Excited State ◽

Theoretical Study ◽

Ruthenium Complexes ◽

Excited State Dynamics ◽

Dinuclear Ruthenium ◽

Dinuclear Ruthenium Complexes

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Infrared Study of the Class II/Class III Boundary in Mixed-Valence Dinuclear Ruthenium Complexes

Journal of the American Chemical Society ◽

10.1021/ja002971k ◽

2001 ◽

Vol 123 (7) ◽

pp. 1396-1402 ◽

Cited By ~ 21

Author(s):

Maria C. DeRosa ◽

Christopher A. White ◽

Christopher E. B. Evans ◽

Robert J. Crutchley

Keyword(s):

Mixed Valence ◽

Ruthenium Complexes ◽

Class Ii ◽

Class Iii ◽

Infrared Study ◽

Dinuclear Ruthenium ◽

Dinuclear Ruthenium Complexes

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Mononuclear and dinuclear ruthenium complexes containing the LRu(acac) fragment. Crystal structures of [LRuIII(acac)(OH)]PF6.cntdot.H2O, [{LRuIII(acac)}2(.mu.-O2H3)](PF6)3, and [{LRuIII(acac)}2(.mu.-O)](PF6)2. Characterization of the mixed-valence species [{LRu(acac)}2(.mu.-O)](PF6)3 (L = 1,4,7-trimethyl-1,4,7-triazacyclononane)

Inorganic Chemistry ◽

10.1021/ic00074a044 ◽

1993 ◽

Vol 32 (22) ◽

pp. 4925-4934 ◽

Cited By ~ 36

Author(s):

Ralf Schneider ◽

Thomas Weyhermueller ◽

Karl Wieghardt ◽

Bernhard Nuber

Keyword(s):

Crystal Structures ◽

Mixed Valence ◽

Ruthenium Complexes ◽

Dinuclear Ruthenium ◽

Dinuclear Ruthenium Complexes

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Synthesis and Characterization of an Azido-Bridged Dinuclear Ruthenium(II) Polypyridylamine Complex Forming a Mixed-Valence State

Inorganic Chemistry ◽

10.1021/ic400412f ◽

2013 ◽

Vol 52 (9) ◽

pp. 5507-5514 ◽

Cited By ~ 13

Author(s):

Misaki Makino ◽

Tomoya Ishizuka ◽

Shingo Ohzu ◽

Jiang Hua ◽

Hiroaki Kotani ◽

...

Keyword(s):

Valence State ◽

Mixed Valence ◽

Synthesis And Characterization ◽

Mixed Valence State ◽

Dinuclear Ruthenium

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Dimeric ruthenium complexes of dicyanopyrazines: complexes with an unstable mixed-valence state

Polyhedron ◽

10.1016/s0277-5387(00)83650-5 ◽

1992 ◽

Vol 11 (24) ◽

pp. 3109-3115 ◽

Cited By ~ 2

Author(s):

Eric C. Kesslen ◽

William B. Euler

Keyword(s):

Valence State ◽

Mixed Valence ◽

Ruthenium Complexes ◽

Mixed Valence State

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Probing the Transition between the Localised (Class II) and Localised-to-Delocalised (Class II–III) Regimes by Using Intervalence Charge-Transfer Solvatochromism in a Series of Mixed-Valence Dinuclear Ruthenium Complexes

Chemistry - A European Journal ◽

10.1002/chem.200501483 ◽

2006 ◽

Vol 12 (18) ◽

pp. 4873-4884 ◽

Cited By ~ 23

Author(s):

Deanna M. D'Alessandro ◽

Amy C. Topley ◽

Murray S. Davies ◽

F. Richard Keene

Keyword(s):

Charge Transfer ◽

Mixed Valence ◽

Ruthenium Complexes ◽

Class Ii ◽

Intervalence Charge Transfer ◽

Dinuclear Ruthenium ◽

Dinuclear Ruthenium Complexes

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Dinuclear ruthenium complexes with bridging 1,4,5,8-tetraoxonaphthalene: redox properties and mixed-valence interactions

Inorganic Chemistry ◽

10.1021/ic00332a033 ◽

1990 ◽

Vol 29 (7) ◽

pp. 1442-1444 ◽

Cited By ~ 36

Author(s):

Andrea Dei ◽

Dante Gatteschi ◽

Luca Pardi

Keyword(s):

Mixed Valence ◽

Ruthenium Complexes ◽

Redox Properties ◽

Dinuclear Ruthenium ◽

Dinuclear Ruthenium Complexes

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Dendritic Mixed-Valence Dinuclear Ruthenium Complexes for Optical Attenuation at Telecommunication Wavelengths

Macromolecules ◽

10.1021/ma021018s ◽

2003 ◽

Vol 36 (9) ◽

pp. 3146-3151 ◽

Cited By ~ 54

Author(s):

Yinghua Qi ◽

Zhi Yuan Wang

Keyword(s):

Mixed Valence ◽

Ruthenium Complexes ◽

Optical Attenuation ◽

Dinuclear Ruthenium ◽

Dinuclear Ruthenium Complexes

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Theory for the mixed-valence state

Le Journal de Physique Colloques ◽

10.1051/jphyscol:19795133 ◽

1979 ◽

Vol 40 (C5) ◽

pp. C5-374-C5-374 ◽

Cited By ~ 1

Author(s):

C. M. Varma

Keyword(s):

Valence State ◽

Mixed Valence ◽

Mixed Valence State

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