AUTOCATALYSIS ANALYZED BY ANALOG COMPUTER AND BY EXPERIMENTATION

1967 ◽  
Vol 59 (6) ◽  
pp. 41-49 ◽  
Author(s):  
W. E. Walles ◽  
A. E. Platt
Keyword(s):  
SIMULATION ◽  
1964 ◽  
Vol 3 (6) ◽  
pp. 38-45 ◽  
Author(s):  
Arthur Hausner

1952 ◽  
Vol 23 (7) ◽  
pp. 382-382 ◽  
Author(s):  
Leonilda Altman
Keyword(s):  

1963 ◽  
Vol 52 (7) ◽  
pp. 668-678 ◽  
Author(s):  
Edward R. Garrett ◽  
Richard L. Johnston ◽  
Elliott J. Collins
Keyword(s):  

1978 ◽  
Vol 33 (3) ◽  
pp. 293-299 ◽  
Author(s):  
Joachim Stauff ◽  
Wolfgang Jaeschke

Abstract The reactions of diluted aqueous solutions of SO2 resp. HSO3-ions with MnO4-or Ce4+ ions in the pH range 1-4 produce chemiluminescence in the spectral region of 450-600 nm. Measurements of the time course of the light emission and their simulation on an analog computer led to a reaction scheme in which a recombination product of primarily formed HSO3 radicals -of a lifetime of about 1 second -appears as precursor of electronically excited SO2 molecules. The participation of singlet oxygen can be excluded because at least the reaction with Ce4+ ions proceeds also in the absence of oxygen.


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